BPL (84) you say that most of the energy leaving the system via IR emission (from CO2 in your example) is sourced from insolation, which would mean that only a small portion of the escaping
CO2 radiation energy originates from earth's IR.
... you say that most of the energy leaving the system via IR emission (from CO2 in your example) is sourced from insolation, which would mean that only a small portion of the escaping
CO2 radiation energy originates from earth's IR.
Not exact matches
Water (H2O) plus carbon dioxide (
CO2) plus light
energy (solar
radiation) produces carbohydrates plus oxygen.
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They don't have to be scientists to understand that the higher
energy waves of visible light from the Sun can penetrate through
CO2, H2O, CH4, NOZ etal in the atmosphere, but the lower
energy radiation of infra - red waves, from Earth's surface, have problems getting back out through these molecules, and a new
energy balance has to be established in the form of rising temperature.
The
CO2 molecule has a unique way to absorb
energy at a particular frequency, but that
energy gets transferred very quickly to its neighboring molecules, most of which have no way to emit
radiation at that frequency.]
So to maintain
energy balance the stratosphere must be losing
energy via long wavelength
radiation which means long wavelength emitters like
CO2 must be radiating more than they are absorbing.
Vibrational modes in molecules with three or more atoms (H2O,
CO2, O3, N2O, CH4, CFCs, HFCs...) include bending motions that are easier to excite and so will absorb and emit lower
energy photons which co-incide with the infrared
radiation that the Earth emits.
CO2 reduces the rate at which the atmosphere loses its
energy to space via infrared
radiation, which in turn reduces the flow of
energy from the Earth's surface to the atmosphere.
(mostly by faster transport of
radiation, which compensates for the
CO2 slowdown, since tha amount of
energy is fixed by what comes in from the sun) The failure to return to equilibrium means that the Laws Of Physics ie the Stefan - Boltzmann Law (SBL) is NOT allowed to function.
ie does a slightly lower density of air mean a slightly lower ground level temperature (temperature normally decreases with height at the lower air density), so that in reality adding
CO2 and subtracting more O2 actually causes miniscule or trivial global COOLING, and the (unused) ability of the changed atmosphere to absorb
radiation energy and transmit it to the rest of the air is overruled or limited by the ideal gas law?
Of course this is a global average but in principle I see no reason not to consider that some large percentage of the
energy warming the tropical Pacific will be from «back
radiation» (for which
CO2 will be partly responsible) and thus not «direct from the sun.»
I think the central point is that of the scale of
energy imbalance and the timescale for response: our addition of
CO2 reduces outgoing thermal
radiation, so incoming
energy from the sun is greater than outgoing
energy to space.
idlex asked:» Am I right in saying that
CO2 has 4
energy levels that correspond to IR
radiation absorption?
The molecules of
CO2 become excited, and can lose this excitation
energy via
radiation of slightly longer wavelength IR in all directions, or by colliding with other molecules.
The general argument however is being discussed by rasmus in the context of planetary
energy balance: the impact of additional
CO2 is to reduce the outgoing longwave
radiation term and force the system to accumulate excess
energy; the imbalance is currently on the order of 1.45 * (10 ^ 22) Joules / year over the globe, and the temperature must rise allowing the outgoing
radiation term to increase until it once again matches the absorbed incoming stellar flux.
What will the
energy of the
radiation emitted by a
CO2 molecules in the atmosphere at NTP, and does it depend on the temperature of the air?
It does seem at first glance that a warm troposphere would warm the stratosphere, but the explanation that more of the earth - sourced infrared
radiation is absorbed lower in the the troposphere by higher levels of
CO2 makes sense if one thinks about the thermodynamic losses involved in the
CO2 re-
radiation processes; some of the earth - sourced infrared is transformed into kinetic
energy and only a fraction is reradiated as more infrared
radiation (if I'm understanding correctly).
Pekka Pirilä: Where the effect of increase in
CO2 is important for the
energy balance is in the upper troposphere, because a significant part of the
radiation emitted upwards by
CO2 of the upper troposphere goes trough the tropopause to stratosphere or through it to open space.
What I'm thinking is that the primary way that the
energy captured by
CO2 gets dissipated is not
radiation, partly back to the surface, but primarily upwards convention as the kinetic transfer between gas molecules moves the heat rapidly throughout the atmosphere.
Where the effect of increase in
CO2 is important for the
energy balance is in the upper troposphere, because a significant part of the
radiation emitted upwards by
CO2 of the upper troposphere goes trough the tropopause to stratosphere or through it to open space.
What they found was a drop in Escaping Infra Red
radiation at the PRECISE wavelength bands that greenhouse gases such as
CO2 with H2O, CFC's, Ozone, Nitrous Oxides, & methane (CH4) absorb
energy.
The latest modelling experiments take this into account, but it is easier to understand causes and effects in an equilibrium - response experiment.The first thing that happens when
CO2 is doubled is that less
energy in the form of
radiation escapes to space.
But this pure IR
energy blocking by
CO2 versus compensating temperature rise for
radiation equilibrium is unrealistic for the long - period and slow
CO2 rises that are occurring.
The evolving
radiation balance of the earth as seen in the satellite data shows that the
energy added by the
CO2 and feedbacks is more than sufficient to explain the observed warming surface temperatures.
Add to that the plausibility of some human - caused warming (
CO2 does interact with photons of outgoing LW
radiation, and all else being equal this should lead to some increase of
energy within the lower atmosphere).
At face value it requires that no
energy can be transfered via collisions, i.e. no thermal conductivity, no viscosity, no diffusion... Even for
CO2, there is no mechanism for the transfer of
energy from rotational / vibrational degrees of freedom to translational motion which has no coupling with a
radiation field.
Bob, the mechanism is that
CO2 converts 15 micron
radiation into kinetic
energy.
It may be pure coincidence that the two things are happening at the same time; but it is undisputed that
CO2 absorbs the heat
energy in infrared
radiation and, as it warms up, becomes an emitter of infrared itself.
I can feel thermal
radiation, I believe
CO2 has a measured IR absorption spectrum, I believe a
CO2 molecule is not a bottomless pit of
energy that can be filled without ever spilling over, and this predictable spilling over is measured from spectrometers on satellites and the ground, therefore there is a
CO2 greenhouse effect whose net effect on the climate is of some small and as yet imprecisely known size.
There more
CO2 leads to a change in the altitude of the level whose
energy balance is controlled by
radiation without a significant convective component.
One last note, the
energy budget framework can also be used to understand the consequences of geo - engineering scenarios that block incoming solar
radiation to compensate the warming by
CO2:
Alarmists are obsessed with the additional
energy that they believe to come from back -
radiation from manmade
CO2 in the atmosphere.
If the upper troposphere cools only by
radiation (with probably some convection across the tropopause), but the surface transfers
energy to the upper troposphere via
radiation, convection, and evapotranspiration, why would the concurrent
CO2 - induced warming be uniform?
When heat
energy gets released from Earth's surface, some of that
radiation is trapped by greenhouse gases like
CO2; the effect is what makes our planet comfy temperature-wise, but too much and you get global warming.
The no - feedback climate senstiivity of about 1 C for a doubling of
CO2 is based on the assumption that this imbalance can only be countered by a change in the
radiation component of how
energy is transmitted through the atmopshere.
If an object (for example, an N2 molecule) is going to collide with a
CO2 molecule and excite it with to an excited state that N2 molecule has to have translational
energy equivalent to at least 15 um
radiation and the impact must occur with exactly the right impact parameter for the reaction to occur.
Once
energy from
CO2 and H2O begins to leak into outer space, LTE is violated, temperatures * must * fall until a more global thermal equilibrium is established with incoming thermal
radiation and convection.
Tom Vonk is correct when he says that the following statements are over-simplifications and need corrections (in caps): «
CO2 absorbs AND EMITS the outgoing infrared
energy and warms the atmosphere TO A HIGHER TEMPERATURE THAN IT WOULD HAVE WITHOUT
CO2» — or — «
CO2 traps part of the infrared
radiation between ground and the upper part of the atmosphere» AND IS THE MAJOR SOURCE OF INFRARED RADIATION FROM THE UPPER ATMOSPHERE
radiation between ground and the upper part of the atmosphere» AND IS THE MAJOR SOURCE OF INFRARED
RADIATION FROM THE UPPER ATMOSPHERE
RADIATION FROM THE UPPER ATMOSPHERE TO SPACE.
However, climate models forced with
CO2 reveal that global
energy accumulation is, instead, primarily caused by an increase in absorbed solar
radiation (ASR).
If
CO2 and H2O molecules now are cooled below the previous equilibrium point by having their
radiation allowed to escape to outer space, then I believe these molecules must then tend to absorb more
energy than yield
energy with each interaction with the other components of the atmosphere until that atmosphere as a whole reaches a new thermal equilibrium where the net
radiation going out and the net
radiation coming in (primarily from the sun and the surrounding atmosphere) is the same.
What they found was a drop in outgoing
radiation at the wavelength bands that greenhouse gases such as carbon dioxide (
CO2) and methane (CH4) absorb
energy.
A consequence of the model you have proposed would seem to be that the «back
radiation» due to
CO2 interception of surface emitted (from solid or liquid continuum thermal
radiation can consist only of the specific wavelengths that the
CO2 absorbed in the first place; since you say no net
energy is exchanged between the
CO2 and the Atmosphere.
Increased concentrations of greenhouse gases, such as
CO2, reduce the amount of outgoing longwave
radiation (OLR) to space; thus,
energy accumulates in the climate system, and the planet warms.
Also, the
co2 must be in radiative equilibrium, giving off as much
radiation energy as it receives.
With
CO2 in the hohlraum at least some of the molecules, everyone seems to agree, spend a fraction of there time with
energy from the
radiation field bound up in internal excitations of one or more forms.
For instance a believable narrative about
CO2 absorbing or emitting 15um
radiation can be matched with thermal
energy changes.
We know with absolute certainty that a doubling of
CO2 can produce no more than half a degree C (actually the number is a lot closer to 0.3 °C) because the 14.77 micron band of the Earth's
radiation is already so close to saturation that there is not enough
energy left in this band to have any further significant effect regardless of how much the
CO2 concentration increases.
CO2 molecules outnumber water molecules in the upper atmosphere, where water vapor is limited by the low saturation vapor pressure, and this is where
radiation to space matters, so
CO2 plays a big role in how much
energy is radiated to space.
If Earth's mean
energy imbalance today is +0.5 W / m2,
CO2 must be reduced from the current level of 395 ppm (global - mean annual - mean in mid-2013) to about 360 ppm to increase Earth's heat
radiation to space by 0.5 W / m2 and restore
energy balance.