Not so much by direct
photolysis of water vapor (not generally a lot of that in the stratosphere), but from CH4, which could build up in a nearly oxygen - free atmosphere, and being largerly of biotic origin, with the H coming from photosynthesis (releasing O); O2 buildup itself was delayed because of geologic O2 sinks (in particular, the conversion of ferrous Fe (naturally present in the crust and mantle and which can dissolve in the oceans) to ferric Fe (precipitates out of the water, the source of banded - iron formations, which humans have used to get Fe).
Photolysis of DM - nitrophen increased [Ca2 +] i from resting concentrations of 20 - 50 nM to values above microM, as measured with the fluorescent indicator Fluo - 3.
Synergy Between Cell - Penetrating Peptides and Singlet Oxygen Generators Leads to Efficient
Photolysis of Membranes.
Not exact matches
Steven Reiken, a research fellow in the department
of surgery at the Massachusetts General Hospital in Boston, believes that antibody - targeted
photolysis (ATPL), a technique based on a procedure used to treat some cancerous tumours, could cure infections caused by P. aeruginosa.
Quentin H. Gibson, who is best known for his pioneering work on the kinetics
of ligand binding to hemoglobins and the development
of stopped flow and flash
photolysis instruments, passed away on March 16, 2011 in Hanover, N.H., at the age
of 92.
So far we have only been able to detect the presence
of some
of the simpler amino acids in our
photolysis residues.
This water
photolysis must have happened to the primordial Earth, with loss
of Hydrogen to space but it was stopped, as it is today, by the presence
of ozone (O3) which requires high oxygen tension to form and it quickly reoxidises hydrogen via OH hydroxyls back to water.
The extent
of the discrepancy became apparent only when he incorporated the new
photolysis rate into a chemical model
of ozone depletion.
Well, yes Robert if «all
of the O3 is destroyed by UV «
photolysis» (whatever that may be) every few minutes, leading to the formation
of free O atoms, — etcetera», — then it seems reasonable, for me to assume that UV radiation is responsible for the making as well as for the breaking
of the «ozone hole»
According to one reference, in the normal atmosphere, all
of the O3 is destroyed by UV
photolysis every few minutes, leading to the formation
of free O atoms, and all
of the O atoms are immediately consumed in reactions with O2 to reform O3 in a fraction
of a second.
CO2
photolysis in both cases provides a low level
of free O2, but in this case there is no overall effect.
Topics that I work on or plan to work in the future include studies
of: + missing aerosol species and sources, such as the primary oceanic aerosols and their importance on the remote marine atmosphere, the in - cloud and aerosol water aqueous formation
of organic aerosols that can lead to brown carbon formation, the primary terrestrial biological particles, and the organic nitrogen + missing aerosol parameterizations, such as the effect
of aerosol mixing on cloud condensation nuclei and aerosol absorption, the semi-volatility
of primary organic aerosols, the importance
of in - canopy processes on natural terrestrial aerosol and aerosol precursor sources, and the mineral dust iron solubility and bioavailability + the change
of aerosol burden and its spatiotemporal distribution, especially with regard to its role and importance on gas - phase chemistry via
photolysis rates changes and heterogeneous reactions in the atmosphere, as well as their effect on key gas - phase species like ozone + the physical and optical properties
of aerosols, which affect aerosol transport, lifetime, and light scattering and absorption, with the latter being very sensitive to the vertical distribution
of absorbing aerosols + aerosol - cloud interactions, which include cloud activation, the aerosol indirect effect and the impact
of clouds on aerosol removal + changes on climate and feedbacks related with all these topics In order to understand the climate system as a whole, improve the aerosol representation in the GISS ModelE2 and contribute to future IPCC climate change assessments and CMIP activities, I am also interested in understanding the importance
of natural and anthropogenic aerosol changes in the atmosphere on the terrestrial biosphere, the ocean and climate.