The imperfections have unique electronic properties that the researchers were able to exploit to increase sensitivity to
absorbed gas molecules by 300 times.
Not exact matches
Producing methamphetamine gives off toxic fumes, and Bridger's laser technology, which is still in development, detects these
gases by measuring the amount of light
absorbed by the
gas molecules.
These
molecules initially comprise just a small fraction of the
gas, but they can
absorb heat from the surrounding
gas and get rid of it by emitting light, thereby cooling the cloud enough for stars to form.
Molecules in the intervening gas clouds absorb radio waves at specific frequencies determined by the type of m
Molecules in the intervening
gas clouds
absorb radio waves at specific frequencies determined by the type of
moleculesmolecules.
They are not like the oxygen
molecules or the nitrogen
molecules in the atmosphere, which do not
absorb infrared, but the greenhouse
gases do.
Kirchhoff's law doesn't apply to
gases, because the greenhouse
molecules can
absorb more energy that they emit.
Whether being lesser than CO2 in number of
molecules in the atmosphere, methane is a potent greenhouse
gas absorbing more infra - red radiation per
molecule than CO2.
If EM is passing through the
gas molecules, they may
absorb photons.
Briefly put, the process can be defined as a CO2
molecule absorbing a ~ 650 cm - 1 photon (equivalent to a thermal energy of about 900 K), and losing that energy to the surrounding bath of atmospheric
gases.
Diatomic
molecules like O2 and N2 are transparent to that radiation and will never fit the definition of a greenhouse
gas, no matter that they
absorb heat via other means.
What I'm saying is that TOA, as far as radiative energy is concerned, for CO2 or other IR
absorbing gas, is effectively the altitude where the chance that a photon will be
absorbed, and emitted back in a direction that will lead it to being
absorbed again by a
molecule in the atmosphere, becomes negligible.
Only greenhouse
gases like CO2
absorb IR, and they collide with other
molecules like oxygen, and so everything heats up.
Only
molecules made of at least three atoms
absorb heat radiation and thus only such trace
gases makes the greenhouse effect, and among these CO2 is the second most important after water vapor.
Greenhouse
gases such as CO2 cause a restriction in the flow of energy out from the Earth to space for reasons associated with the Quantum Mechanics of how these
molecules absorb and radiate energy.
He found that
gases and vapors whose
molecules had three or more atoms, such as water vapor and CO2,
absorbed much more of the thermal radiation passing through the tube than did two - atom
molecules such as oxygen and nitrogen.
All
gases that have
molecules with at least three atoms
absorb infrared light in some bands.
The point you raise is any
molecule [including
gas molecules] can
absorb [at certain wavelengths] and re-radiate energy [at same or different wavelengths depending on
molecule] and not heat up a body of
gas, liquid, or solid.
Doesn't Kirchhoff's radiation law require that in a mixture of
gasses in thermal equilibrium with the walls of an enclosing container, that each
molecule must reradiate a quantum for each quantum
absorbed?
LadyGray — A calculation which I have looked for, and been unable to find, is a calculation of the efficiency of
gas molecules absorbing and then emitting radiation.
-- For the photons of interest, it is only the GHGs that are
absorbing / emitting: if
gas molecules don't have quantum transitions with the right energy differences, they can't interact with the photons.
A calculation which I have looked for, and been unable to find, is a calculation of the efficiency of
gas molecules absorbing and then emitting radiation.
Traditional anthropogenic theory of currently observed global warming states that release of carbon dioxide into atmosphere (partially as a result of utilization of fossil fuels) leads to an increase in atmospheric temperature because the
molecules of CO2 (and other greenhouse
gases)
absorb the infrared radiation from the Earth's surface.
However, mixtures of
gases (even poor
absorbers) are better, not only because of different absorption spectra, but also because of the inter-species collisions (which to the radiation look like asymmetrical
molecules).
To review the process please see here and note the in picture caption «Some of the infra - red radiation is
absorbed and re-emitted by the greenhouse
gas molecules».
[click, Image 2] Much of this heat is
absorbed by greenhouse
gases, which then send the heat back to the surface, to other greenhouse
gas molecules, or out to space.
Since the
gas molecule absorbs and the re-radiates the wave equally in all directions it must radiate half away and half back.
But if we add a smallish number of IR - active
molecules (CO2 in this case), then the amount of IR
absorbed from the IR emitted at the surface will increase, and raise the
gas temperature a smallish amount.
Since the infrared - inactive
gases don't emit infrared light, if enough
absorbed energy is transferred to the nitrogen and oxygen
molecules through collisions, that could theoretically increase the average energy of the air
molecules, i.e., it could «heat up» the air.
Greenhouse
gas molecules absorb infrared radiation.
Instead, because there are greenhouse
gases in our atmosphere, that radiation gets
absorbed by those
molecules and when they
absorb it, the IR radiation gets converted to heat.
Or can you just accept that
molecules of
gas which have
absorbed energy at a greater rate than the surrounding
molecules of
gas with which they are intimately mixed and thus risen in temperature, will re emit that energy until they are in thermal equilibrium with the rest of the
gas?
... with the replacement of CO2
molecules absorbed by the vegetation by
molecules out -
gassed from soils by the oxidation of the organic material of plants grown years to centuries before: the delta13C of the air was then slightly less negative.
Both GH
gas molecules and
molecules in liquid emit and
absorb IR, but an excited
molecule in free space may live rather long before it emits radiation.
Note that the non-anthropic (or natural) delta13C becomes very slowly more negative (from -6.5 per mil preindustrial to about -7 per mil now) with the replacement of CO2
molecules absorbed by the vegetation by
molecules out -
gassed from soils by the oxidation of the organic material of plants grown years to centuries before: the delta13C of the air was then slightly less negative.
I agree that the 2nd Law has been misapplied, all you've got is
gas molecules and photons milling about randomly, they don't stop and think what «The 2nd Law» expects them to do, some photons from the atmosphere DO get
absorbed by the surface, making it warmer than it would otherwise be.
Moreover, since
gas molecules don't
absorb IR across the spectrum but only on molecular lines, cutting off the radiative heat flow would not be nearly as effective as simply silvering the walls and pulling a vacuum in the void between the walls.
That implies that an excited electron in a greenhouse
gas molecule in the atmosphere can not radiate toward the ground unless it can «find» another electron on the surface in a ground state which is capable of
absorbing the photon which is to be radiated.
Describe Global Warming The sun is emitting heat rays that is
absorbed by the green house
gas molecules once it reflects.
«
Gas molecules that
absorb thermal infrared radiation, and are in significant enough quantity, can force the climate system.
It does
absorb infrared radiation and trap heat in the atmosphere, which is the definition of a greenhouse
gas, but carbon monoxide is very reactive and soluble, so its
molecules do not remain in the atmosphere for any significant time.
Carbon dioxide
absorbs solar electromagnetic radiation which makes it warm, That warmth gets passed to neighboring
gas molecules and global temperature goes up.
The problem of tracking rays layer by layer as
gas molecules scattered or
absorbed them was called «radiative transfer,» an elegant and difficult branch of theoretical physics.
The
molecule will first use the heat energy in expansion and on cooling will again condense and sink because heavier, and it will cool when its heat expanded volume flows to colder air which
absorbs the heat, the internal kinetic energy of vibration, which if strong enough will pass that heat to another colder (which is why visible light is not a thermal energy, it is not powerful enough to move a
molecule of matter into vibration, it takes the bigger heat wave, longwave infrared, aka thermal infrared called that because it is the wavelength of heat)-- that is how convective heating warms the fluid
gas air in a room, by circulation, in the rise and fall of
molecules as they expand and condense, not by heat energy propelling
molecules to hit other
molecules..
It's about the ability of certain
molecules to both
absorb and re-radiate infra red radiation and only certain
gases do this like CO2.
The heated
gas molecules would bump into other air
molecules and warm them, and like any material above absolute zero, the Atmosphere would emit radiation at a variety of long - wave wavelengths in random directions, some of which would be
absorbed by the surface of the planet, warming it further.
Re-absorption by other greenhouse
gas molecules complicates the path and destination of an individual unit of IR, but what it all boils down to is that something less than half of the IR
absorbed by greenhouse
gases eventually finds its way back to the surface, with the remainder escaping into space.
You had to elaborate your answer by saying that
gases with non polar
molecule symmetry do not
absorb or emit energy within the temperature parameters with any application in engineering, e.g. O2, N2, H2..., while
gases with polar
molecule symmetries are significant
absorbers and emitters of radiative energy, e.g. H2O, CO2, SO3... for engineering applications, depending of their density, temperature and pressure in a given environment.
The current models have the greenhouse
gases radiating in their bands with the same intensity that they
absorb, but the greenhouse
gases lose most of that excitation by collisions to other air
molecules.
In fact,
molecule - for -
molecule some
gases containing lots of fluorine are 10,000 times stronger at
absorbing radiation than carbon dioxide.