Not exact matches
Each higher and cooler layer in turn emits thermal radiation corresponding to its temperature; and much of that also escapes directly to space
around the
absorption bands of the higher atmosphere layers; and so on; so that the total LWIR emission from the earth should then be a composite of roughly BB spectra but with source temepratures ranging ove the entire surface Temeprature range, as well as the range of atmospheric emitting Temperatures.
Also, I would very much like someone knowledgeable to tackle Norm Kalmanovitch's posts from
around 2.30 pm — in particular his assertions regarding saturation of the
absorption band and measurements of OLR.
That big dip
around 15 microns is due to the
absorption / emission
band of CO2.
Carbon dioxide (CO2) is mostly transparent to radiation, but it has a few
absorption bands, the most important of which is
around 12μ to 17μ, in the range where the Earth outputs longwave radiation.
Water vapour causes most
absorption in the near infrared from 0.7 um to 6 um (but with C0 2
bands at 2.7 um and 4.3 um), there is strong C02
absorption around 15 um, then intense water vapour
absorption takes over right through to about 1 mm wavelength
This method has been tested in a 250 - cm − 1 region
around 15 µm where the CO2
absorption overlaps the tail of the water vapor rotation
band.