Loh et al. developed a light - promoted protocol to install these labels on
alkyl carbons adjacent to nitrogen.
They prepared a complex with fluoride, tosyl - substituted nitrogen (NHTs), and aryl as well as
alkyl carbon ligands, and then measured a ratio of alkyl C - F, C - C, and alkyl C - N bonded products of roughly 5:3:1.
Not exact matches
Recently, this group succeeded to develop the synthetic method of branched terminal olefins from butadiene and
alkyl halides through selective introduction of
alkyl group into the internal
carbon of butadiene by the aid of Cu catalyst.
Nobuaki Kambe, Professor, and Takanori Iwasaki, Assistant Professor, at the Graduate School of Engineering, Osaka University developed a synthetic method by constructing
carbon frameworks of 8
carbons through the formation of a bond of two butadiene molecules by using a cheap nickel catalyst and introducing an
alkyl group and a benzene ring to an internal and terminal
carbons of 1,6 - octadiene, respectively.