Large amounts of methane are stored in seafloor sediments
as gas hydrate, and as these melt the gas is released into the water column.
Not exact matches
The U.S. Geological Survey estimates that methane locked in ice (known
as hydrates) could contain more organic carbon than all the world's coal, oil, and nonhydrate natural
gas combined.
The Arctic ocean floor hosts vast amounts of methane trapped
as hydrates, which are ice - like, solid mixtures of
gas and water.These
hydrates are stable under high pressure and cold temperatures.
Prior to the 1970s,
hydrates were thought of only
as nuisances, because they can plug oil and
gas pipelines in the field.
Similar frozen methane
hydrates occur throughout the same arctic region
as they did in the past, and warming of the ocean and release of this methane is of key concern
as methane is 20x the impact of CO2
as a greenhouse
gas.
The results indicate that, in contrast to UO2 (H2O) +, the protactinium hydroxide isomer, PaO (OH) 2 +, is produced
as a
gas - phase species close in energy to the
hydrate isomer, PaO2 (H2O) +.
«Later, the sea ice gradually expanded from the very high Arctic before reaching, for the first time, what we now see
as the boundary of the winter ice around 2.6 million years ago,» says Jochen Knies, who is also attached to CAGE, the Centre for Arctic
Gas Hydrate, Environment and Climate at the University of Tromsø, the Arctic University of Norway.
As it melts, one cubic meter of
gas hydrate will release 164 cubic meters of natural
gas.
The most likely explanation is the mass release of methane from sediments on the sea floor, where the
gas was sequestered,
as it is now, in a solid form
as methane
hydrate.
Yet governments and industry are rushing into expanded use of fossil fuels, including unconventional fossil fuels such
as tar sands, tar shale, shale
gas extracted by hydrofracking, and methane
hydrates.
The alternative pathway, which the world seems to be on now, is continued extraction of all fossil fuels, including development of unconventional fossil fuels such
as tar sands, tar shale, hydrofracking to extract oil and
gas, and exploitation of methane
hydrates.
It is made up of aluminum,
hydrated silicon compounds, and oxygen and can trap toxic
gases and odors such
as formaldehyde, ammonia, and carbon monoxide.
SeaYu Enterprises SeaYu Enterprises» Clean + Green line of odor - control products — including a product specifically made for small animals — are made from cane - sugar derivatives, a proprietary blend of botanical extracts,
hydrated cellulose (a plant - based cleaning agent), purified water, and nitrogen
gas as a natural propellant.
«Methane
hydrate seems menacing
as a source of
gas» another emotive term is «menacing».
Methane
hydrate seems menacing
as a source of
gas that can spring aggressively from the solid phase like pop rocks (carbonated candies).
The shelf (ESAS) is also characterized by the location of over 80 % of the existing submarine permafrost,
as well
as of the bulk of shallow water
gas hydrates.
There are a number of factors that control CH4 concentrations that are extermely poorly understood and are mostly ignored in the scenarios — the dependence on other
gases (such
as O3, and CO), the impact of increased temperatures and changes to precip on tropical and boreal wetland emissions, the existence (or not) of a significant methane
hydrate source from permafrost or continental shelves, the climate impact on the atmopsheric chemistry of CH4.
As such, there is a diffusion gradient of dissolved CH4 between the top of
gas hydrate and the seafloor.
A thermal pulse of more than 10 °C is still propagating down into the submerged sediment and may be decomposing
gas hydrate as well
as permafrost.
And the
gas expanding and cooling
as the
gas expands could push up a mass of ice and reformed
hydrates creating the typical «bump» in the seabed.
Those original 10 molecules of water (
gas and liquid) would have been present
as chemical
hydrates, I've depicted them
as rust above.
Schmidt & Shindell, 2003, Atmospheric composition, radiative forcing, and climate change
as a consequence of a massive methane release from
gas hydrates.
Shakhova and Semiletov have identified CH4 sources on the East Siberian Arctic Shelf (ESAS)
as comprising
hydrates (1,000 Gtonnes),
gas (700 Gtonnes) and permafrost (500 Gtonnes).
Methane can also be stored in the seabed
as methane
gas or methane
hydrates and then released
as subsea permafrost thaws.
Hydrates should be seen
as a seal blocking the flux of methane from underlying reservoirs, and not the total source of
gas in themselves.
Methane
hydrate in ocean seabed sediments is a potential source of methane (CH4) to the atmosphere, where CH4 has potential to act
as a powerful greenhouse
gas.
What is concerning is the possibility that rapid global warming could occur faster than many people believe is possible, if global warming due to atmospheric carbon dioxide causes the Earth's atmosphere to warm enough to release enormous deposits of frozen methane (CH4) that are stored in the permafrost above the Arctic Circle and in frozen methane ice, known
as methane
hydrate, underneath the floors of the oceans throughout the world (see: How Methane
Gas Releases Due To Global Warming Could Cause Human Extinction).
As it happens, the extra heat travels into shallow seas along the continental shelf and, over time, the warming also spreads to the deep seabed, destabilizing methane
hydrates and free
gas trapped over millennia in the permafrost cap.
Moreover,
as if discovering methane emissions from the deep seas of the Arctic isn't already of major concern, a recent study discovered immense amounts of methane locked under Antarctic ice: «They... calculated that the potential amount of methane
hydrate and free methane
gas beneath the Antarctic Ice Sheet could be up to 4 billion metric tons, a similar order of magnitude to some estimates made for Arctic permafrost.
However, if the temperature warms, or the pressure is reduced (for instance if local sea level decreases), the
hydrate will break up and release the methane
as gas which can bubble up through the ocean and enter the atmosphere.
The
hydrates release
gas as they warm.
The release of fossil geological methane, currently trapped
as free
gas, may therefore occur sooner than from
hydrates associated with permafrost.
It is quite possible, therefore, that some of the venting
gas observed on the ESAS could be fossil methane, previously trapped beneath the permafrost
as free
gas or
gas hydrates, finding its way to the surface through a cryosphere cap that has been degrading over the past 10,000 years.
It is not yet clear whether this
gas is present below the permafrost
as free
gas or
as methane
hydrates or both.
Warming destabilises permafrost and marine sediments of methane
gas hydrates in some regions according to some model simulations (Denman et al., 2007 Section 7.4.1.2),
as has been proposed
as an explanation for the rapid warming that occurred during the Palaeocene / Eocene thermal maximum (Dickens, 2001; Archer and Buffett, 2005).
What this exciting new research vessel will allow us to learn about seafloor spreading, earthquakes, magma flow,
gas hydrate deposits, continental drift, and more, will expand scientific knowledge about the Earth and contribute to our ability
as humans to withstand its extreme forces.
The alternative pathway, which the world seems to be on now, is continued extraction of all fossil fuels, including development of unconventional fossil fuels such
as tar sands, tar shale, hydrofracking to extract oil and
gas, and exploitation of methane
hydrates.
The research to be conducted by Georgia Tech will advance the understanding of the behavior of
gas hydrates hosted in fine - grained sediments such
as clay or silt, and will evaluate extraction methods relevant to the potential to produce
gas from such sediments.
There is some more information about permafrost and
gas hydrates as a source of methane here and here: https://earthobservatory.nasa.gov/Features/MethaneMatters/#page5 https://earthobservatory.nasa.gov/Features/MethaneMatters/#page6
In addition, deep fresh water lakes may host
gas hydrates as well, e.g. the fresh water Lake Baikal, Siberia.
The sedimentary methane
hydrate reservoir probably contains 2 — 10 times the currently known reserves of conventional natural
gas,
as of 2013 [update].
The commentary speculates methane
hydrates, ice - like substances where the
gas is stored in the East Siberian Arctic shelf (among other places), could unleash a 50 gigatonne «pulse» of methane between 2015 - 2025 (leading to an atmospheric concentration six times current levels)
as undersea permafrost thaws.
I suspect that the methane that has out -
gassed from the
hydrates changes to CO2 in the atmosphere before it returns to the Earth
as stored carbon.
The visible
hydrate was found
as thin icelike layers that released methane
gas initially upon retrieval, but stabilized for up to 4 h at atmospheric pressure conditions and subfreezing temperatures.
High methane concentrations in well - ice - bonded sediments and
gas releases suggest that pore - space
hydrate may be found at depths
as shallow
as 119 m. Geochemical and isotopic determinations suggest that the methane
hydrate observed in the core hole is biogenic (microbial) in origin.
Schmidt, G.A., and D.T. Shindell, 2003: Atmospheric composition, radiative forcing, and climate change
as a consequence of a massive methane release from
gas hydrates.
The ice sheet provides perfect conditions for subglacial
gas hydrate formation, in the past
as well
as today.