They are known
as organic aerosols, or OA.
Not exact matches
Photo credit: DRIChakrabarty and colleagues found to their surprise that funeral pyre emissions contain sunlight - absorbing
organic carbon
aerosols known
as brown carbon.
Yet, the factors that influence the formation of these
aerosols, known
as secondary
organic aerosol or SOA, are often assumed.
Even though open windows bring in more ozone from outside, the reduction in the indoor limonene concentration and SOA formation strength more than make up for it,
as less secondary
organic aerosol is formed inside.
This includes the role of oxidized volatile
organic compounds, such
as limonene and alpha - pinene, the typical scents of the citrus fruits and coniferous forests, in
aerosol formation.
In research recently published in Environmental Science & Technology, Waring describes the role of limonene, the
organic compound that gives cleaners and air fresheners an orange scent and acts
as a solvent, in the formation of secondary
organic aerosols.
By adjusting elements of the test, such
as the air exchange rate, which is the number of times per hour indoor air is replaced by outdoor air,
as well
as the concentrations of terpene and ozone in the chamber, the group was able to ascertain how those variables each affected the formation of secondary
organic aerosols.
, Kilcoyne, A.L.D., Moffet, R.C., Weigand, M., Martin, S.T., Pöschl, U., and Andreae, M.O.: Biogenic potassium salt particles
as seeds for secondary
organic aerosol in the Amazon, Science, 337, 1075 - 1078, 2012.
Further investigation showed that Titan's atmosphere has
organic aerosols, called tholins, that likely formed from molecules such
as methane and nitrogen.
The specialized instruments onboard the aircraft sampled the plume for
aerosol particle size distribution and composition
as well
as concentrations of pollutant gases such
as sulfur dioxide, nitric oxide, nitrogen dioxide, ozone, and volatile
organic compounds (VOCs).
These oligomers are also the starting materials for troubling atmospheric
aerosols, known
as secondary
organic aerosols.
The team evaluated simulated cloud fields from the multi-scale
aerosol - climate model and examined how specific human - caused
aerosols, such
as sulfate, black carbon (soot), and
organic carbon affect those clouds and, in turn, the climate.
The team injected citric, adipic, and fulvic acid into the chamber
as seed
aerosols, and then introduced a secondary
organic aerosol from α - pinene, a carbon - containing compound derived from pine trees.
The largest portion of these submicron
aerosols is
organic, or carbon - containing, and is classified
as two kinds: primary and secondary.
Results: Today's climate models regard
organic aerosols as static carbon - based molecules, but scientists at Pacific Northwest National Laboratory and the University of California, Irvine showed that the particles are very dynamic.
Her research experience includes modeling of
organic aerosol oxidation at LBNL, fabrication and optimization of high performance semiconductor nanoparticle - based image sensors
as Manager of Materials Development at InVisage Technologies, Inc., and foundational and applied research
as a Research Staff Member at IBM's Almaden Research Center on transformations in dielectrics, semiconductors, metals, and polymer films.
Aside from
aerosol solutions, and ocean clouds a la Latham and Salter, I think an essential will be capturing waste
organics (mostly farm debris, corn stalks etc.) and sequestering them in the deep ocean (not
as CO2; just drop bales; much cheaper and efficient).
Importantly, RCP4.5 considers the influence of sulfur
aerosols,
as well
as black and
organic carbon.
Brown clouds contain dark
aerosols such
as soot that are released into the atmosphere by burning
organic matter.
The brownish color of the cloud (which is visible when looking at the horizon) is due to absorption of solar radiation at short wavelengths (green, blue, and UV) by
organic and black carbon
aerosols as well
as by NOx.
New evidence shows that the ocean also acts
as a source of
organic matter from biogenic origin -LSB-...] Surface - active
organic matter of biogenic origin -LSB-...] enriched in the oceanic surface layer and transferred to the atmosphere by bubble - bursting processes, are the most likely candidates to contribute to the observed
organic fraction in marine
aerosol.
It delves into the impacts of
aerosols, which are tiny pollutants of mineral dust, soot and
organic matter emitted by sources such
as power plants, factories and quarries.
Increased biomass can lead to increased emissions of biogases such
as dimethyl sulfide and isoprene, which when oxidized in the atmospheric form sulphate and
organic aerosols that can nucleate clouds, increasing cloud cover and planetary albedo — the CLAW Hypothesis.
These NCA emissions directly affect particle concentrations and human exposure to nanosized
aerosol in urban areas, and potentially may act
as nanosized condensation nuclei for the condensation of atmospheric low - volatile
organic compounds.
Aerosol «blue haze»,
as seen here in the Great Smoky Mountains in North Carolina, is formed by the oxidation of volatile
organic compounds emitted by trees.
Organic aerosols that are directly injected in the atmosphere in the particulate phase are called primary
organic aerosols (POA), while those that are created by the oxidation of volatile
organic compounds are known
as secondary
organic aerosols (SOA).
At left, the composite annual mean
organic aerosol surface air concentrations of the models, defined
as the median of the model fields on a 5 ° × 5 ° grid.
In densely populated areas however, anthropogenically generated and released hydrocarbons play an important role
as precursor of the development of secondary
organic aerosols.
PNNL scientists found that secondary
organic aerosols formed in the presence of the toxic pollutant known
as polycyclic aromatic hydrocarbons (PAHs) trapped the PAH molecules inside, shielding them from degradation.
This thinning, which can decrease the ozone concentration by
as much
as 70 percent, was caused by the rampant use of human - made chlorofluorocarbons (CFCs),
organic compounds that were once widely used in cooling systems and
aerosols.
First, we have to consider the effect of
aerosols, which start off
as urban haze or rural smoke and ultimately become transcontinental and transoceanic plumes o ABCs consisting of sulfate, nitrate, hundreds of
organics, black carbon, soil dust, fly ash, and other
aerosols.
The climate feedbacks involved with these changes, which are key in understanding the climate system
as a whole, include: + the importance of
aerosol absorption on climate + the impact of
aerosol deposition which affects biology and, hence, emissions of
aerosols and
aerosol precursors via
organic nitrogen,
organic phosphorus and iron fertilization + the importance of land use and land use changes on natural and anthropogenic
aerosol sources + the SOA sources and impact on climate, with special attention on the impact human activities have on natural SOA formation In order to quantitatively answer such questions I perform simulations of the past, present and future atmospheres, and make comparisons with measurements and remote sensing data, all of which help understand, evaluate and improve the model's parameterizations and performance, and our understanding of the Earth system.
My studies range from detailed
aerosol processes such
as the formation of secondary
organic aerosols (SOA), to centennial time scale climate variability related to natural variability and external forcings.
Topics that I work on or plan to work in the future include studies of: + missing
aerosol species and sources, such
as the primary oceanic
aerosols and their importance on the remote marine atmosphere, the in - cloud and
aerosol water aqueous formation of
organic aerosols that can lead to brown carbon formation, the primary terrestrial biological particles, and the
organic nitrogen + missing
aerosol parameterizations, such
as the effect of
aerosol mixing on cloud condensation nuclei and
aerosol absorption, the semi-volatility of primary
organic aerosols, the importance of in - canopy processes on natural terrestrial
aerosol and
aerosol precursor sources, and the mineral dust iron solubility and bioavailability + the change of
aerosol burden and its spatiotemporal distribution, especially with regard to its role and importance on gas - phase chemistry via photolysis rates changes and heterogeneous reactions in the atmosphere,
as well
as their effect on key gas - phase species like ozone + the physical and optical properties of
aerosols, which affect
aerosol transport, lifetime, and light scattering and absorption, with the latter being very sensitive to the vertical distribution of absorbing
aerosols +
aerosol - cloud interactions, which include cloud activation, the
aerosol indirect effect and the impact of clouds on
aerosol removal + changes on climate and feedbacks related with all these topics In order to understand the climate system
as a whole, improve the
aerosol representation in the GISS ModelE2 and contribute to future IPCC climate change assessments and CMIP activities, I am also interested in understanding the importance of natural and anthropogenic
aerosol changes in the atmosphere on the terrestrial biosphere, the ocean and climate.
For a comprehensive GCM I can count oceans, land, atmosphere, ice, biological processes,
organic and inorganic chemical processes, human - made sources and other effects, radiative energy transport, conduction and convective heat transfer, phase change, clouds and
aerosols,
as some of the important system components, phenomena, and processes.
However, coatings of
organic carbon
aerosol on hygroscopic
aerosol such
as sulphate may lead to suppression of the rate of water uptake during cloud activation (Xiong et al., 1998; Chuang, 2003).
Theoretically, coatings of essentially non-absorbing components such
as organic carbon or sulphate on strongly absorbing core components such
as black carbon can increase the absorption of the composite
aerosol (e.g., Fuller et al., 1999; Jacobson, 2001a; Stier et al., 2006a), with results backed up by laboratory studies (e.g., Schnaiter et al., 2003).
Observational evidence suggests that some
organic aerosol compounds from fossil fuels are relatively weakly absorbing but do absorb solar radiation at some ultraviolet and visible wavelengths (e.g., Bond et al., 1999; Jacobson, 1999; Bond, 2001) although
organic aerosol from high - temperature combustion such
as fossil fuel burning (Dubovik et al., 1998; Kirchstetter et al., 2004) appears less absorbing than from low - temperature combustion such
as open biomass burning.
Organic aerosols are emitted
as primary
aerosol particles or formed
as secondary
aerosol particles from condensation of
organic gases considered semi-volatile or having low volatility.
However, sulphate is invariably internally and externally mixed to varying degrees with other compounds such
as biomass burning
aerosol (e.g., Formenti et al., 2003), fossil fuel black carbon (e.g., Russell and Heintzenberg, 2000),
organic carbon (Novakov et al., 1997; Brock et al., 2004), mineral dust (e.g., Huebert et al., 2003) and nitrate
aerosol (e.g., Schaap et al., 2004).