Carrying out
atmospheric measurements often entails having to consider how representative measurements taken in a single location are, and whether local conditions, such as landforms, affect observations.
The statement that only 55 % of human CO2 emissions have been removed by the biosphere / biosphere is something you'll have to prove, which is hard because as far as I'm aware human CO2 does not posses an isotopic signature that can be easily differentiated from natural sources — the arguments you
often hear on Skeptical Science are
measurements in changes of the C12 / C13 / C14
atmospheric mass, not individual CO2 molecules, which can be misleading.