Sentences with phrase «carbonate ion»

Ocean uptake of CO2, resulting from increasing atmospheric CO2 concentrations, reduces surface ocean pH and carbonate ion concentrations, an impact that was overlooked in the TAR.

The diminishing availability of carbonate ion -LRB--RRB-, and ensuing reduction in calcium carbonate (CaCO3) saturation states are widely reported to reduce calcification in a wide range [11,12] of, but not all, calcifying organisms [13,14].

There is little free carbonate ion in seawater.

The pH in surface open - ocean waters was regulated largely by changes in CO2 because the carbonate ion concentration (CO3 −) concentration is relatively uniform over the timescales of interest and ocean waters are mostly saturated in Ca2 + (Caldeira and Berner 1999).

These changes are resulting in a decrease in pH, carbonate ion concentrations, and dissolved oxygen in the ocean.

Under scenario IS92a, the multi-model projection shows large decreases in pH and carbonate ion concentrations throughout the world oceans (Orr et al., 2005; Figures 10.23 and 10.24).

Increasing atmospheric CO2 concentrations lower oceanic pH and carbonate ion concentrations, thereby decreasing the saturation state with respect to calcium carbonate (Feely et al., 2004).

The decrease in surface carbonate ion concentrations is found to be largest at low and mid-latitudes, although undersaturation is projected to occur at high southern latitudes first (Figure 10.24).

These reactions are fully reversible and the basic thermodynamics of these reactions in seawater are well known, such that at a pH of approximately 8.1 approximately 90 % the carbon is in the form of bicarbonate ion, 9 % in the form of carbonate ion, and only about 1 % of the carbon is in the form of dissolved CO2.

Thus, the addition of anthropogenic CO2 into the oceans lowers the pH and consumes carbonate ion.

Under normal seawater conditions, more than 99.99 % of the hydrogen ions that are produced will combine with carbonate ion (CO32 ---RRB- to produce additional HCO3 — .

Past hypotheses arguing calcification was dependent on carbonate ion concentration, or aragonite and calcite saturation levels, were most likely misled by the fact that higher carbonate ion concentrations are a daily «side effect» of photosynthesis.

Effect of carbonate ion concentration and irradiance on calcification in planktonic foraminifera

If carbonate ion concentrations are lower, calcium carbonate minerals are more likely to dissolve.

This acidification occurs in a region with a naturally low carbonate ion concentration, and studies suggest that the surface of the Southern Ocean will become undersaturated with respect to calcium carbonate minerals aragonite and calcite by the end of the century.

The decreases in calcification and PIC occur simultaneously with decreases in the observed carbonate ion concentration, suggesting a possible link between acidification and decreasing calcification in this vulnerable region.

Finds that for calcite, undersaturation occurs when carbonate ion concentration drops below 42 µmol kg - 1

Recently, laboratory experiments with live foraminifera have demonstrated that the photosynthetic activity of algal symbionts and the carbonate ion concentration -LRB-[CO32 --RSB--RRB- of seawater also affect shell d18O values.

Holds that for most open - ocean surface waters, aragonite undersaturation occurs when carbonate ion concentrations drop below approximately 66 µmol kg - 1

Local researchers and fishermen have also been raising the alarm about ocean acidification, which is when carbon dioxide goes into the ocean and creates corrosive carbonic acid, reducing the pH and the carbonate ion concentration in the sea water.

This second reaction is important because reduced seawater carbonate ion concentrations decrease the saturation levels of calcium carbonate (CaCO3), a hard mineral used by many marine microbes, plants and animals to form shells and skeletons.

«Southern Ocean acidification via anthropogenic CO2 uptake is expected to be detrimental to multiple calcifying plankton species by lowering the concentration of carbonate ion (CO32 − to levels where calcium carbonate (both aragonite and calcite) shells begin to dissolve.

Counteracting the carbonate ion formation by dissolution of lime.

Many organisms require supersaturated conditions to form sufficient calcium carbonate shells or skeletons, and biological calcification rates tend to decrease in response to lower carbonate ion concentrations, even when the ambient seawater is still supersaturated.

Natural seasonal variations in carbonate ion concentrations could either hasten or dampen the future onset of this undersaturation of calcium carbonate.

If the surface ocean PCO2 concentrations continue to increase in proportion with the atmospheric CO2 increase, a doubling of atmospheric CO2 from preindustrial levels will result in a 30 % decrease in carbonate ion concentration and a 60 % increase in hydrogen ion concentration.

Declining coral reefs due to increases in temperature and decreases in carbonate ion would have negative impacts on tourism and fisheries.

As you lose carbonate ion (as the ocean is acidified), the water's capacity to absorb more CO2 decreases.

If we raise the CO2 concentration in the atmosphere to Cretaceous levels and hold it there for 10,000 years or so, the CaCO3 cycle in the ocean will restore the carbonate ion concentration back toward CaCO3 saturation.

If the surface ocean pCO2 concentrations continue to increase in proportion with the atmospheric CO2 increase, a doubling of atmospheric CO2 from preindustrial levels will result in a 30 % decrease in carbonate ion concentration and a 60 % increase in hydrogen ion concentration.

(from 370 to 470 ppm) would decrease carbonate ion concentration by 40 % more than would have been the case if carbon dioxide concentrations were raised from the pre-industrial 280 to 380 ppm.

«Addition of carbon dioxide to the ocean reduces the carbonate ion concentration and thereby reduces the solubility of carbon dioxide in seawater.

(from 370 to 470 ppm) would decrease carbonate ion concentration by 40 % more than would have been the case if carbon dioxide concentrations were raised from the pre-industrial 280 to 380 ppm.

Acidification increases the corrosiveness of the water and is also driving a decline in the amount of carbonate ion, needed to make aragonite and calcite, two forms of calcium carbonate that many marine organisms use to build their shells and skeletons.

This task can be achieved by providing proxy - based reconstructions of seawater pH, carbonate ion concentrations, and pCO2 along with the response of the marine calcifiers during key intervals of the Late Quaternary.

In turn, this could indicate that the carbonate ion concentration of the (western) Pacific at depths shallower than the sill to the SCS (ca. 2,400 m) has not changed appreciably between the last glacial period and the present interglacial.

Changes in the carbonate ion concentration in seawater can affect the saturation state (and hence biological availability) of several types of calcium carbonate (e.g., calcite, aragonite, or high - magnesian calcite.

Atmospheric CO2 is absorbed by the ocean and results in a decrease in carbonate ion concentration, making carbonate ions unavailable to corals and other marine calcifiers.

Since reef - building corals need carbonate to build their skeletons, decreasing carbonate ion concentrations will likely lead to weaker, more brittle coral skeletons and slower coral growth rates.

Ocean acidification reduces carbonate ion saturation, making it harder for marine organisms to produce the CaCO3 that they need to form their shells and frameworks.

«Periods of very intense North Atlantic circulation and higher Northern Hemisphere temperatures increased the preservation of microfossils in the sediment cores, whereas those with slower circulation, when the study site was primarily influenced from the south, were linked with decreased carbonate ion concentrations at our core site which led to partial dissolution,» said co-author Dr Luke Skinner, also from Cambridge's Department of Earth Sciences.

The uptake of fossil fuel carbon dioxide (CO2) by the ocean increases seawater acidity and causes a decline in carbonate ion concentrations.

Excess carbon dioxide enters the ocean, reacts with water, decreases ocean pH and lowers carbonate ion concentrations, making waters more corrosive to marine species that need carbonate ions and dissolved calcium to build and maintain healthy shells and skeletons.

About 35 % of added calcium ions are bound at pH = 9.00 (∼ 4 % carbonate ions in the buffer equilibrium), whereas ∼ 75 % of added calcium ions are bound at pH = 10.0 (∼ 25 % carbonate ions in the buffer equilibrium).

When CO2 from the atmosphere combines with water, it produces carbonic acid (the ingredient that gives soft drinks their fizz) and decreases carbonate ions, a key building block of marine animals» shells.

Huge amounts of carbon dioxide are retained as carbonate ions, and calcium ions represent a major contribution to water hardness.

The increasing fraction of carbonate ions in the buffer at higher pH promotes cluster formation and in this way increases calcium binding (principle of LeChatelier).

Indeed, the binding of carbonate ions in the clusters can be quantitatively evaluated by constant pH titration.

In waters depleted of carbonate ions, young oysters must expend more energy to build their shell and may not survive.

When seawater gets more acid, he explains, it holds fewer free carbonate ions.