Using a natural catalyst from bacteria for inspiration, researchers have now developed the fastest synthetic
catalyst for hydrogen production — producing 45 million molecules per second.
The scientists took the well - characterized nickel - based
catalyst for hydrogen production previously synthetized at PNNL and built a dozen different versions by adding either a single synthetic amino acid or a dipeptide, consisting of two molecules.
«Recipe for low - cost, biomass - derived
catalyst for hydrogen production.»
Cobalt atoms shine in an electron microscope image of a new
catalyst for hydrogen production invented at Rice University.
«The research team has provided a new perspective in designing and improving non-precious metal - based
catalysts for hydrogen production,» said Lin.
There are many start - ups and research teams out there making breakthroughs in alternative
catalysts for hydrogen production.
Not exact matches
For example, the nanoparticle
catalyst converted 99 % of dimethylphenylsilane to the corresponding silanol in just 9 min at room temperature, releasing an equimolar amount of
hydrogen gas at the same time.
White's group is working on
catalysts that can modify a wider range of amino acids, particularly those with electron - rich aromatic functionality, which compete with the carbon -
hydrogen bonds
for oxidation using the current
catalyst.
The nanoparticle
catalyst displayed the highest turnover frequency and number attained to date
for hydrogen production
catalysts from organosilanes.
UNSW Sydney chemists have invented a new, cheap
catalyst for splitting water with an electrical current to efficiently produce clean
hydrogen fuel.
Until now, however, this chemical was not considered a good
catalyst for making moly sulfide to produce
hydrogen from water through electrolysis.
Further studies will also employ another beam line, NOMAD, to characterize the exact structure of both the surface and bulk hydride in the
catalyst to reveal,
for example, if oxygen vacancies form channels in the bulk to bring in
hydrogen and spur further hydride formation.
University researchers from two continents have engineered an efficient and environmentally friendly
catalyst for the production of molecular
hydrogen (H2), a compound used extensively in modern industry to manufacture fertilizer and refine crude oil into gasoline.
«We believe that electrochemical tuning can be used to find new
catalysts for other chemical fuels beyond
hydrogen.
Graphene doped with nitrogen and augmented with cobalt atoms has proven to be an effective, durable
catalyst for the production of
hydrogen from water, according to scientists at Rice University.
An efficient, low - cost
catalyst is essential
for realizing the promise of
hydrogen as a clean, environmentally friendly fuel.
Currently, the most efficient
catalysts for the electrochemical reaction that generates
hydrogen from water are based on platinum, which is scarce and expensive.
Rice University scientists have created an efficient, simple - to - manufacture oxygen - evolution
catalyst that pairs well with semiconductors
for solar water splitting, the conversion of solar energy to chemical energy in the form of
hydrogen and oxygen.
A nanostructured composite material developed at UC Santa Cruz has shown impressive performance as a
catalyst for the electrochemical splitting of water to produce
hydrogen.
The work, which appears in the November 27, 2014, edition of Science Express, points to new avenues
for producing single - site supported gold
catalysts that could produce high - grade
hydrogen for cleaner energy use in fuel - cell powered devices, including vehicles.
For decades, researchers tinkered with light - triggered
catalysts that encourage water molecules to release
hydrogen gas — but none of the
catalysts were sufficiently cheap and stable.
«We have discovered a
catalyst that can produce ready quantities of
hydrogen without the need
for extreme cold temperatures or high pressures, which are often required in other production and storage methods,» remarks Mahdi Abu - Omar of Purdue University.
For instance, the team could show that pre-treating with
hydrogen should increase the efficiency of platinum
catalysts.
Providing
hydrogen for the process is expensive, and as oils get more sour, higher pressures and more stable
catalysts are needed to break the sulfur bonds.
This synthesis route is capable of developing alternative
catalysts of noble metals
for many eco-friendly technologies such as fuel cell vehicles,
hydrogen generation from water and CO2 reduction.
Titanium - based semiconductors are particularly popular as
catalysts for solar water - splitting reactions to produce
hydrogen, a clean renewable - energy source.
A major new discovery by scientists at the universities of Oxford, Cambridge and Cardiff in the UK, and the King Abdulaziz City
for Science and Technology (KACST) in Saudi Arabia, has shown that hydrocarbon wax rapidly releases large amounts of
hydrogen when activated with
catalysts and microwaves.
Co-author Professor Sir John Meurig Thomas, from the Department of Materials Science and Metallurgy at the University of Cambridge, said the work could be extended so that many of the liquid components of refined petroleum and inexpensive solid
catalysts can pave the way
for the generation of massive quantities of high - purity
hydrogen for other commercial uses, including CO2 - free energy production.
«New, more efficient
catalyst for water splitting: Discovery could remove hurdle to producing
hydrogen from water.»
Some of the most widely studied materials
for direct
hydrogen peroxide synthesis are palladium - based
catalysts.
«The direct growth of anchored MoSoy nanocrystals on graphene sheets may enhance the formation of strongly coupled hybrid materials with intimate, seamless electron transfer pathways, thus accelerating the electron transfer rate
for the chemical desorption of
hydrogen from the
catalyst, further reducing the energy required
for the reaction to take place,» Sasaki said.
«If we understand where and how
hydrogen peroxide primarily decomposes, we can propose some design criteria
for future iterations of palladium
catalysts.»
Understanding these effects is also important
for other applications such as splitting water molecules to produce
hydrogen at solid - liquid interfaces, electronic devices that rely on oxide - oxide interfaces, or other electrochemical processes using these materials as
catalysts, where defects serve as the sites that enable the interactions.
Perhaps some unknown mineral on Titan acts as a
catalyst to speed up the reaction of
hydrogen and carbon to form methane, and that's what accounts
for the vanishing
hydrogen.
Scientists from Forschungszentrum Jülich and Technische Universität Berlin have succeeded in developing efficient metallic
catalyst particles
for converting
hydrogen and oxygen to water using only a tenth of the typical amount of platinum that was previously required.
Many, many investigators have contributed over the years to the development of a form of artificial photosynthesis in which sunlight - activated
catalysts split water molecules to yield oxygen and
hydrogen — the latter being a valuable chemical
for a wide range of sustainable technologies.
Among the areas of research that inspire Dr. Cui are: the development of new technologies to further the development of electric transportation; creating new battery chemistry
for grid - scale storage at ultra-low cost; and harnessing low - cost technologies
for the development of
catalysts for efficient carbon dioxide reduction and conversion into highly valuable products and inert carbon -
hydrogen bond activation.
D.M. Ginosar, L.M. Petkovic, A.W. Glenn, K.C. Burch, «Stability of supported platinum sulfuric acid decomposition
catalysts for use in thermochemical water splitting cycles,» International Journal of
Hydrogen Energy, 32, 482 - 488, 2007.
The next step is to test the new
catalyst in devices incorporating electrodes and other components
for converting the protons and electrons to
hydrogen fuel — and then later, with light - absorbing compounds to provide energy to drive the whole reaction.
Researchers at the University of Erlangen - Nürnberg (Germany) report in the journal Angewandte Chemie their development of an enhanced platinum
catalyst for the steam reforming of methanol to release
hydrogen.
Direct liquefaction, by contrast, combines coal with
hydrogen over a
catalyst for the direct conversion to linear and ring - type hydrocarbons.
This particular discovery originated in prior work at Rochester that demonstrated quantum dots could be excellent
catalysts for creating
hydrogen -
hydrogen bonds
for solar fuel applications.
«This
catalyst will pave the way
for the development of high - performance, electrolysis - based
hydrogen production applications.»
The key
for energy storage via the creation of
hydrogen gas lies in finding a low - cost
catalyst whose turnover frequency and overpotential matches or exceeds that of platinum.
The team continues to uncover the basic design principles
for catalysts capable of
hydrogen oxidation and
hydrogen production.
It will focus on
catalyst development
for four applications: proton exchange membrane fuel cells to convert stored energy in non-fossil fuels into electricity; electrolysers
for splitting water into oxygen and
hydrogen — a potential clean fuel cell source; syngas, a mixture of CO and H2, which is generated from coal, gas and biomass, and widely used as a key intermediate in the chemical industry; and lithium - air batteries.
For example, on the rhodium
catalysts, the team's calculations showed that the carbon - carbon and carbon -
hydrogen bond scissions are competitive, regardless of the rhodium particle size.
A new robust and highly active bifunctional
catalyst developed by Rice University and the University of Houston splits water into
hydrogen and oxygen without the need
for expensive metals such as platinum.
The scientists correlated the various peaks observed in the NMR spectra with the
catalysts» reactivity
for an oxidation reaction that removes a
hydrogen atom from methanol.
Solar - driven water splitting has been studied intensely
for decades because it could provide a nearly limitless supply of clean - burning
hydrogen if a suitable
catalyst can be found.