To infer the atmospheric record of GEM from
firn air concentrations presented in Fig. 1, we determined a site specific, diffusivity - depth relationship.
Not exact matches
please read Z. Jaworowski's (with Segalstad and Ono) many papers on this subject of trapped gases in glaciers, where he discusses the over 20 mechanical and chemical processes that make accurate measurements impossible; even in shallow cores above the point where co2 is supposedly permanently trap in ice cavities in the
firn, co2
concentrations are already 20 - 40 % lower than those measured in
air at mauna loa.
Atmospheric gas
concentrations over the past century measured in
air from
firn at the South Pole
However, both sediment records of atmospheric deposition of Hg2 + species at high northern latitudes and atmospheric GEM
concentrations inferred from Greenland
firn air support the conclusion that transfer of anthropogenic inorganic mercury through the atmosphere to terrestrial and marine reservoirs occurs on a large scale.
(A) Envelope of modeled
concentrations for atmospheric GEM inferred from Summit
firn air, central Greenland, during the last 66 years (gray area).
Thus, we conclude the
firn air is a reliable archive to investigate historical changes of GEM atmospheric
concentrations during the last ≈ 70 years.
We next applied a one - dimensional
firn diffusion model (24) to reconstruct GEM
concentrations at all depths in the
firn air from different atmospheric histories.
Gaseous elemental mercury (GEM; Hg °)
concentrations measured in
firn air at Summit Station from 15 to 79.5 m depth.
Atmospheric GEM
concentrations inferred from Greenland
firn air reproduce the scarce GEM measurements reported from 1977 to 1980 across the Atlantic Ocean at mid-northern latitudes (7)(see Fig.
Hence, atmospheric GEM
concentrations inferred from Greenland
firn air and global anthropogenic Hg emissions have exhibited consistently similar trends during the most recent decades (Fig. 2), suggesting that the atmospheric reservoir of mercury at mid - and high - northern latitudes has been driven mainly by anthropogenic emissions during the last decades.
Atmospheric GEM
concentrations, reconstructed from Greenland
firn air and the worldwide production of mercury, peak at roughly the same time during the 1970s (Fig. 2).
While atmospheric GEM
concentrations reconstructed from Summit
firn air are higher than mean hemispheric values, they reproduce GEM levels observed shipboard between 40 ° and 50 ° N (see Fig.
Processes taken into account included (i)
air mixing by pressure and temperature gradients down to a few meters below the surface (i.e., the so - called convection zone); (ii) molecular diffusion in the open pore space and gravitational fractionation (entrainment toward the deeper
firn depends on
concentration gradients, diffusivities, and molar mass); and (iii) a downward
air flux in the open porosity zone due to bubble closure removing
air from the open pores.
[71][72] Because of the way
air is trapped in ice (pores in the ice close off slowly to form bubbles deep within the
firn) and the time period represented in each ice sample analyzed, these figures represent averages of atmospheric
concentrations of up to a few centuries rather than annual or decadal levels.