Carbon dioxide combines with water to form carbonic acid, which then dissociates to
form bicarbonate ions and hydrogen ions (H +), so that increasing concentrations of CO2 in the atmosphere have been decreasing the pH (acidifying) of the surface ocean (NRC, 2010c).
In the absence of that ion supply, abiotic CO2 uptake in the ocean as a function of CO2 in air is at least somewhat limited by ions already present; acification can (over time) dissolve carbonate minerals that supply cations and carbonate ions, buffering pH and reacting with CO2 to
form bicarbonate ions; new cations from chemical weathering have to be supplied to actually remove C from the oceans while keeping pH from dropping and without releasing as much CO2 from bicarbonate ions).
Not exact matches
When carbon dioxide dissolves in water, carbonic acid
forms, which has a very short lifetime — typically around 30 picoseconds — before dissociating into protons and
bicarbonate ions.
Crocodiles use a waste product of metabolism — the
bicarbonate ions formed when carbon dioxide dissolves in water — as the trigger for haemoglobin to unload the oxygen it carries.
Carbonic acid dissociated to
form hydrogen
ions, which found their way into the structures of weathering minerals, and
bicarbonate, which was carried down rivers and streams to be deposited as limestone and other minerals in ocean sediments.
When hydrogen
ions are released in seawater, they combine with carbonate
ions to
form bicarbonate.
One has to wonder, though, why all the calcium
ions and
bicarbonate ions don't
form calcium carbonate and precipitate out.
This dissociates to
form bicarbonate (HCO3) and carbonate (CO3)
ions.
At any rate, when «normal» rain containing natural carbonic acid falls upon silicon - containing sedimentary rocks
formed over eons from the shells of tiny marine creatures — radiolarians, diatoms and some sponges — this «siliceous» rock combines with the carbonic acid to
form ions of
bicarbonate.
If we assume that the
bicarbonate ion is the predominant specie at pH 7, then we only get one proton per CO2 molecule in
forming carbonic acid.
With a higher internal pH,
bicarbonate sheds an H + and converts into carbonate
ions and when concentrated in the presence of concentrated Ca + +, calcium carbonate minerals readily
form.
Likewise when ocean concentrations of H +
ions increase, they more readily bond to the
bicarbonate and carbonate
ions to minimize the drop in pH and
form more CO2, which can be quickly utilized during photosynthesis.
In the
form of carbonic acid, water's 2 H +
ions can more easily detach to
form bicarbonate and carbonate
ions when pH rises.
In seawater, CO2 interacts with water molecules to
form carbonic acid, which reacts very quickly with the large reservoir of dissolved inorganic carbon —
bicarbonate and carbonate
ions — in the ocean.
These reactions are fully reversible and the basic thermodynamics of these reactions in seawater are well known, such that at a pH of approximately 8.1 approximately 90 % the carbon is in the
form of
bicarbonate ion, 9 % in the
form of carbonate
ion, and only about 1 % of the carbon is in the
form of dissolved CO2.
Additional CO2 reacts with water to
form carbonic acid (H2CO3), which quickly disassociates to
form H +
ions and
bicarbonate (HCO3 −)
ions.