Although grain - boundary density has previously been correlated with catalytic activity for some reactions, direct evidence that
grain boundaries create surfaces with enhanced activity is lacking.
Grain boundaries create strained regions in polycrystalline materials by stabilizing dislocations and may provide a way to create high - energy surfaces for catalysis that are kinetically trapped.
Not exact matches
Bulk defects in a metal, such as
grain boundaries, can
create regions of increased strain at its surface that could affect its catalytic activity.
By annealing the films to
create larger
grains, they could change the types and distribution of
grain boundaries at the surface.
Salehi - Khojin said it should be possible to «tune» the electronic properties of graphene
grain -
boundary arrays using controlled doping to obtain a fingerprint response — thus
creating a reliable and stable «electronic nose.»
They
created a micron - sized, individual graphene
grain boundary in order to probe its electronic properties and study its role in gas sensing.
Those defects, the research showed,
create more heat than would be expected from the
grain boundaries.