Not exact matches
Hydrogen atoms contained in water readily
bond with the heavy isotope to
form hydrochloric acid gas, which then leaks into space — leaving more of the lighter isotope behind.
«Previous research used reversible
hydrogen bonds to connect polymers to
form a rubber but reversible
bonds are intrinsically weaker than covalent
bonds,» said Li - Heng Cai, a postdoctoral fellow at SEAS and corresponding author of the paper.
About four billion years ago, the strength of those
hydrogen - carbon
bonds allowed increasingly complex molecules — amino acids, DNA, and proteins — to
form from the primordial soup, making life possible.
These groups readily
form hydrogen bonds that helped the fibers make tight contacts with one another, further strengthening the material.
Water molecules are linked together by
hydrogen bonds that break and
form several thousands of billions of times per second.
«That's what his advance is pointing towards,» he says, «finding an alternative catalyst that will allow us to do oxygen evolution (breaking the
bonds of water or H2O and
forming oxygen) in concert with
hydrogen» on a grand scale.
In recent years researchers have achieved better performance with compounds such as lithium borohydride, in which the metal atoms
form weaker, ionic
bonds with groups containing several
hydrogen atoms.
Water molecules in the solid state, such as in ice and snow,
form weak
bonds (called
hydrogen bonds) to one another.
Individually they are weak, together they
form the cement that holds together a whole new family of designer materials sings the praises of
hydrogen bonds
Atoms of most elements, such as
hydrogen, oxygen and carbon,
form tight chemical
bonds by sharing electrons with their neighbours in order to give each atom a stable configuration of electrons.
Of the two types of atom, oxygen has more pull on the electrons that they share to
form the
bonds between them, so the oxygen becomes slightly negatively charged and the
hydrogens slightly positive.
The researchers discovered that these catalysts — copper in the
form of a white salt and the ligand as an oil — can oxidize C - H
bonds in a very efficient way in combination with
hydrogen peroxide, a reduced
form of oxygen that nature uses.
The amalgamation of these techniques provided a fully characterized structure, one in which the dissolved carbon dioxide acts as a hydrophobe, having
formed only very weak
hydrogen bonds to the surrounding water molecules.
Scientists from Tomsk Polytechnic University together with their colleagues from USA and Japan have proposed a novel way to address the most important and fundamental challenge of organic chemistry, i.e. breaking a
bond between carbon and
hydrogen atoms to
form new organic substances.
In order to obtain new compounds, it is necessary to break the
bond of carbon and
hydrogen to
form carbon - carbon
bond,» explains the researcher.
When the water is drained away Berglund found that the fibres join together into networks held by
hydrogen bonds,
forming flat sheets of «nanopaper».
When ethanol dissolves in water, the ethanol molecules remain intact but
form new
hydrogen bonds with the water.
Intramolecular insertion of metal nitrenes into carbon -
hydrogen bonds to
form γ - lactam rings has traditionally been hindered by competing isocyanate formation.
The amino acid proline is special among the natural amino acids because it can not
form hydrogen bonds to other structural parts of the peptide when integrated in a peptide.
The structures and properties of these T - shaped intermediates are broadly similar to
hydrogen -
bonded complexes such as that
formed between ethene and
hydrogen chloride.
First, they occurred quickly and the resulting nucleotides spontaneously paired with each other in water,
forming hydrogen bonds like the Watson - Crick base pairs that create the «ladder - rung» pattern inside RNA and DNA helixes.
«Most self - healing polymers
form hydrogen bonds or metal - ligand coordination, but these aren't suitable for ionic conductors,» Wang says.
Again, the first one stripped off
hydrogens from adjacent carbon atoms in both the long polyethylene chains and short alkanes to
form double
bonds; the second split the molecules and randomly stitched split molecules back together.
Both materials were then sprayed with
hydrogen gas in which the
bonds were broken to
form single
hydrogen atoms.
«The Ru catalyst precisely distinguishes butadiene and substituted acetylene molecules and new carbon - carbon
bonds are
formed among a butadiene with two acetylenes just by migration of the terminal
hydrogen atoms in butadiene.
Water, for example, with one oxygen and two
hydrogen atoms, can
form two
hydrogen bonds per molecule.
Aspirin, for example, contains just 21 atoms (nine carbons, eight
hydrogens and four oxygens)
bonded together to
form a particular shape.
«Melanie Sanford's insightful studies on the details as well as applications in the field of carbon -
hydrogen bond activation have led to new methods to efficiently modify existing pharmaceuticals to arrive at new and better
forms in a more efficient and rapid way than was previously possible.
After careful analysis, the research team determined that an ammonia molecule
forms a nearly linear
hydrogen bond with another ammonia molecule and that additional
hydrogen bonds with another ammonia molecules do not perturb this pattern.
Why it matters:
Hydrogen bonds and the networks they
form play an important role in understanding and controlling processes from refining crude oil to metabolizing proteins.
High concentrations result in acid
forming hydrogen bonds and more structure, reducing dissociation
They also found that each water molecule
formed four
hydrogen bonds — three with other molecules in the same layer, and one with water in the other layer.
Wiedner and Bullock focused on a cobalt catalyst and how it
forms bonds with
hydrogen atoms and shuffles electrons.
The
hydrogen bonds with carbon to
form methane.
They
form transient
bonds with the carbon in CO2, making it more willing to
bond with
hydrogen ions, eventually resulting in the production of methanol.
The polymer and the agent
form hydrogen bonds, weak electrostatic connections between polymer's
hydrogen and an agent's oxygen atom.
To solve the mystery, Wiedner and Bullock used newer techniques to show how the actors
form bonds, trade electrons, and free
hydrogen.
This figure also shows that all of the compounds identified possible
form hydrogen bonds between the Glu66 residue and the carboxamide group.
An unsaturated fatty acid is missing
hydrogens, and as a result the carbons
bond to each other twice,
forming what is called a double
bond.
In nature, the polyunsaturated fatty acids are usually found in the cis
form, which means that both
hydrogen atoms at the double
bond are on the same side.
Monounsaturated: Monounsaturated fatty acids have one double
bond in the
form of two carbon atoms double -
bonded to each other and, therefore, lack two
hydrogen atoms.
For instance, Schoenmann explains, microscopic particulates in the air will
form hydrogen bonds with a painting's surface so that «no amount of water or scrubbing will be able to remove that dirt.
Meanwhile, Christner says, unraveling the chemistry of ice - binding proteins (which tend to
form a
hydrogen bond with water molecules) could have important biotech applications.
And so it goes, the bigger the
hydrogen bonded water cluster, the easier it is to
form a bigger cluster.
But when their temperature is lowered and they
form a water molecule, the symmetry of the individual atoms is broken as they
form a molecule with 105 degrees between the
hydrogen - oxygen
bonds.
The structure of the «nanoglue» and the clay nanosheets allowed the layers to
form cooperative
hydrogen bonds, which gives rise to what Kotov called «the Velcro effect.»
The polymer can readily
form hydrogen bonds with water.