Not exact matches
White's
group is working on catalysts that can modify a wider range of amino acids, particularly those with electron - rich aromatic functionality, which compete with the carbon -
hydrogen bonds for oxidation using the current catalyst.
The rays do this by causing molecules in the ring known as amide
groups to shuffle from opposite sides of the carbon
bond to the same side, loosening
hydrogen bonds in the process.
These
groups readily form
hydrogen bonds that helped the fibers make tight contacts with one another, further strengthening the material.
In recent years researchers have achieved better performance with compounds such as lithium borohydride, in which the metal atoms form weaker, ionic
bonds with
groups containing several
hydrogen atoms.
Instead of a hydrophilic alcohol
group (an oxygen -
hydrogen molecule bound to a
hydrogen - saturated carbon atom), the final lignin polymer contained a hydrophobic aldehyde
group (a carbon atom double -
bonded to an oxygen atom).
It turns out that the answer lies in the interaction between the
bonds that hold the atoms in the water molecule together and the much weaker
bonds, known as
hydrogen bonds, that are the glue holding
groups of water molecules together.
Melanie Sanford, a chemist the University of Michigan, Ann Arbor, who focuses on using metal - based agents, primarily palladium, to catalyze reactions that substitute
hydrogen in carbon -
hydrogen bonds with other atoms or functional
groups.
P1 behavior was first investigated by STM at the liquid / solid interface: as an exemple, an arrangement of the molecules on HOPG presenting a quasi-square lattice (a = 2.1 nm, b = 2.2 nm, α = 94 °) self - assembled by
hydrogen bonds between the pyridine unit and the methyl
groups borne by the p - xylene core will be described, indicating strong intermolecular interactions between the molecules P1 leading to a supramolecular self - assembly independent of the underlying HOPG structure.
The results suggested that the tertiary amine
groups bind to D97 on TM2 and E32 in the amino terminus of CXCR4 through
hydrogen bonds while aromatic residues Y45, W94, H113 and Y255 establish hydrophobic interactions with the aromatic counterpart of identified compounds.
We report on the use of the
hydrogen bond acceptor properties of some phosphorus - containing functional
groups for the assembly of a series of [2] rotaxanes.
Antiparallel beta - sheet structure of the enzyme catalase: The antiparallel
hydrogen bonds (dotted) are between peptide NH and CO
groups on adjacent strands.
This figure also shows that all of the compounds identified possible form
hydrogen bonds between the Glu66 residue and the carboxamide
group.
X-ray crystallography revealed that the isothiourea moiety was making an extended network of
hydrogen bonds with functional
groups that were key to BACE1's catalytic activity.
For example, the
hydrogen bonding interaction between the phenolic — OH and the o - methoxy
groups in curcumin influences the O - H
bond energy and H atom abstraction by free radicals, thus making it a better scavenger of free radicals compared to other curcuminoids such as BDMC.
The K'NEX Model DNA, Replication and Transcription Kit includes phosphate
groups, deoxy and ribose sugars and
hydrogen bonds, allowing students to model the processes of replication and transcription with sturdy, colour - coded pieces.