Optimized selective aerobic oxidations
in ionic liquids convert various activated primary alcohols into their corresponding acids or aldehydes in good to excellent yields.
A Study of Acid - Catalyzed Hydrolysis of Cellulose Dissolved
in Ionic Liquids and the Factors Influencing the Dehydration of Glucose and the Formation of Humins, Sean Dee, Alex Bell, Chemistry and Sustainability Energy and Materials, doi: 10.1002 / cssc.201000426, August 2, 2011.
e.g. to determine the dynamics of water in porous media, polymer melts, diffusion processes
in ionic liquids as well as magnetic fluctuations in single crystals, powder samples and thin films
Green Fluorescent Protein as a Screen for Enzymatic Activity
in Ionic Liquid - aqueous Systems for in situ Hydrolysis of Lignocellulose, Paul Wolski, Douglas Clark, Harvey Blanch, Green Chemistry, doi: 10.1039 / C1GC15691H, October 5, 2011.
Entropy of Cellulose Dissolution in Water and
in the Ionic Liquid 1 - Butyl -3-Methylimidazolim Chloride, Adam Gross, Alexis T. Bell, Jhih - Wei Chu, Physical Chemistry Chemical Physics, doi: 10.1039 / C2CP40417F, March 27, 2012.
Not exact matches
She says that,
in general, deep eutectic solvents are easier to prepare and more biodegradable than potentially toxic
ionic liquids.
Fermentation
in the presence of the carboxylate - type
liquid zwitterion produced 1.4 g / L ethanol, while no ethanol was obtained with the
ionic liquid due to its high toxicity.
Working with Brian Rosen, a chemical engineering graduate student; Wei Zhu, a recent chemical engineering Ph.D.; Amin Salehi - Khojin, a postdoctoral researcher; and other scientists at Illinois, Masel used
ionic liquids to stabilize intermediates
in the dioxide - monoxide conversion.
«We demonstrated that these
ionic liquids are excellent
in pre-treating biomass and compare well with imidazolium - based
ionic liquids,» Singh explains.
The second uses various forms of chemistry —
in the form of amine or ammonia scrubbers, special membranes or
ionic liquids — to pull carbon dioxide out of a more mixed set of exhaust gases.
The paper, «Lignin Extraction from Biomass with Protic
Ionic Liquids,» is published online
in the journal Green Chemistry.
Similarly, the water - soluble blue trityl dye commonly used
in the textile industry was also removed as a result of the lipophilic character of the
ionic liquid.
An
ionic liquid is a salt that is melted at room temperature, making it
liquid without being dissolved
in a solvent.
They then combined a room - temperature
ionic liquid and lithium salt and mixed them into the clay
in an oxygen - free glove box.
In early 2015, KU Leuven chemists developed
ionic liquid technology to recycle europium and yttrium from collected fluorescent lamps and low - energy light bulbs.
In 2012, JBEI researchers, including Blake Simmons, a co-author on this new study, had discovered a suite of saccharification enzymes that were tolerant to
ionic liquids.
Because the salt solvent, known as
ionic liquids, interferes with later stages
in biofuels production, it needs to be removed before proceeding, a process that takes time and money.
But what makes
ionic liquids great for deconstruction also makes it harmful for the downstream enzymes and bacteria used
in biofuel production.
«E. coli remains the workhorse microbial host
in synthetic biology, and
in our study, using the
ionic -
liquid - tolerant E. coli strain, we can combine many earlier discoveries to create an advanced biofuel
in a single pot.»
But Graetzel and his colleagues recently discovered that by substituting
ionic liquids —
liquids made up of charged particles, imidazolium iodide
in this case — they could maintain the efficiency and pose no risk of evaporation.
They discovered that by adding
ionic liquid — a kind of
liquid salt — they can modify the optical transparency of single - walled carbon nanotube films
in a controlled pattern.
JBEI has established world - class and differentiated expertise
in the use of
ionic liquids (ILs) as a viable biomass pretreatment solvent and potential game changing conversion technology, but there remain several significant scientific challenges that must be addressed before an affordable IL - based process is commercially viable.
Under the supervision of Ling Liang, a process engineer, she worked on figuring out how effective lignin - derived
ionic liquids, solvents used
in a variety of renewable energy applications, would be for biomass pretreatment.
I would like to add that the marriage of stir bar dispersive
liquid microextraction and magnetic
ionic liquids came about after I heard Prof. Alberto Chisvert's talk at Extech 2016
in Poland.
Researchers
in China have generated gasoline fuel with a research octane number of 95.4 from biomass - derived γ - valerolactone (GVL)-- the highest octane number reported for biomass - derived gasoline fuel — using an
ionic liquid catalyst.
At the conclusion of his talk, he mentioned his interest
in pursuing other magnetic sorbents, such as magnetic
ionic liquids.
«A Thermophilic
Ionic liquid - tolerant Cellulase Cocktail for the Production of Cellulosic Biofuels» published
in 2012 has already been viewed 8,871 times and cited 50 times as of today.
«This solvent, or
ionic liquid, is like dissolving the catalyst
in pure substrate, but the catalyst won't work
in this
liquid without adding water which is necessary to move the substrate very quickly to the catalyst,» said O'Hagan.
Metal chlorides belong to a class of
ionic -
liquid - soluble materials called halides, which «
in general work well for converting fructose to HMF,» Zhang said — but not so well when glucose is the initial stock.
Ionic liquids provide an additional benefit: It is reusable, thus produces none of the wastewater
in other methods that convert fructose to HMF.
For example, the research provided a theoretical foundation for understanding and engineering the electronic properties of
liquid electrolytes
in PEC cells for hydrogen production and
ionic liquid for batteries.
Inert - Gas - Stripping Method for Measuring Solubilities of Sparingly Soluble Gases
in Liquids; Solubilities of Some Gases
in Protic
Ionic Liquid 1 - Butyl, 3 - Hydrogen - Imidazolium Acetate, Waheed Afzal, Brian Yoo, John H. Prausnitz, Industrial and Engineering Chemistry Research, 51 (11), pp. 4433 - 4439, doi: 10.1021 / ie20228 - y, March 21, 2012.
The pupils can choose between seven topics of nanotechnology: the creation of artificial muscles, microbiological fuel elements, manipulation of nanoparticles, nanoparticles and
ionic liquids as oil additives, materials used
in regenerative medicine, deposition and 3D - characterisation of atomically designed structures and a topic covered
in English, «Artificial robotic fish with EAP elements».
Lei Liang, a postdoc
in Ye's research group and first author of the paper, built a device
in which he could induce ferromagnetism
in non-magnetic platinum, using a field effect generated by gating through an
ionic medium called
ionic liquid.
There are several different ways to get Magnesium:
In powder form with a product like Natural Calm so that you can vary your dose and work up slowly,
ionic liquid form can be added to food and drinks and dose can be worked up slowly, or transdermal form by using Magnesium oil applied to the skin (this is my favorite method).
If do need to take magnesium and your doctor okays it, the most absorbable forms of magnesium are
ionic magnesium which comes
in a
liquid form, magnesium citrate, and magnesium taurate.
99.9999 % pure
liquid ionic silver
in the form of silver hydroxide.
«I next tried
liquid ionic magnesium, which included trace minerals as found
in the Great Salt Lake
in Utah.
Researchers from the University of California, Berkeley, and the University of Maryland School of Medicine have characterized a new cellulase (cellulose - digesting enzyme) that has optimal activity at 109 °C, a half - life of 5 h at 100 °C, and resists denaturation
in strong detergents, high - salt concentrations, and
ionic liquids.
The team has published some of its results
in the Proceedings of the National Academy of Sciences, under the title «High Coulombic efficiency aluminum - ion battery using an AlCl3 - urea
ionic liquid analog electrolyte.»
Water, which is produced by combustion, so is contained
in exhaust gases, cuts down the efficiency of various nitrogen
ionic liquids, but Dr Davis says it is more prone to interact with CO2 rather than water.