Oxidation of methane to CO2, which requires reactions with the OH radical, produces an instantaneous reduction
in radiative absorption and emission since CO2 is a weaker greenhouse gas than methane, although CO2 has a longer lifetime.
Not exact matches
The recent JCAP paper published
in Nature Communications introduces a transcendent approach to understanding PEC device performance for arbitrary material and device quality, using five representative parameters: semiconductor
absorption fraction, external
radiative efficiency, series resistance, shunt resistance and catalytic exchange current density to account for imperfect light
absorption, charge transport and catalysis.
The magnitude of the
radiative forcing per doubling is equal to the effect of band widenning, which is (BW1 + BW2) * depth of valley or height of hill, plus some additional effect
in the center of the band, which is on the order of 1/2 * (BW1 + BW2) * increase
in height or depth of hill or valley; the central contribution could be more or less than that, but it will be less than double (because the shape of the
absorption spectrum won't allow a square shape
in the graph of the spectral flux).
The effect is a continuum of different
absorption spectra that all have the same band - widenning per doubling and same effects at the center at various stages between no effect and saturation, though they are at different stages
in that process for any given amount of CO2; the
radiative forcing is a weighted average of the effects of each of those
absorption spectra; once the center of the band is saturated for all of the spectra, the band widenning effect is the same for each and thus the forcing from the band widenning is the same as it is
in the original simplified picture.
In the tugging on the temperature profile (by net radiant heating / cooling resulting from
radiative disequilibrium at single wavelengths) by the
absorption (and emission) by different bands, the larger - scale aspects of the temperature profile will tend to be shaped more by the bands with moderate amounts of
absorption, while finer - scale variations will be more influenced by bands with larger optical thicknesses per unit distance (where there can be significant emission and
absorption by a thinner layer).
But if the optical thickness
in that band is sufficiently smaller than
in another band (depending on wavelengths), adding some
absorption to the optically - thinner band would tend to result
in warming of the colder layers (as there would be less temperature variation over height
in radiative equilbrium for that band, given the same surface (+ tropospheric) temperatures.
Re my 441 — competing bands — To clarify, the
absorption of each band adds to a warming effect of the surface + troposphere; given those temperatures, there are different equilibrium profiles of the stratosphere (and different
radiative heating and cooling rates
in the troposphere, etc.) for different amounts of
absorption at different wavelengths; the bands with
absorption «pull» on the temperature profile toward their equilibria; disequilibrium at individual bands is balanced over the whole spectrum (with zero net LW cooling, or net LW cooling that balances convective and solar heating).
On the other hand, water vapor and CO2 have many strong
radiative absorption transitions
in the infrared (as do also ozone, CH4, N2O, and a variety of CFCs).
In an atmosphere open to the sky as opposed to a container in a laboratory a density change is forced by the absorption of radiative energy by the GHG molecule
In an atmosphere open to the sky as opposed to a container
in a laboratory a density change is forced by the absorption of radiative energy by the GHG molecule
in a laboratory a density change is forced by the
absorption of
radiative energy by the GHG molecules.
However the
radiative absorption capability of CO2 is also high so
in practice it has little difficulty acquiring the energy needed to initiate uplift.
Absorption in the atmosphere of solar radiation by CO2 doesn't buy you any reduction
in the
radiative forcing which is conventionally applied to the whole atmosphere and surface.
If, for instance, CO2 concentrations are doubled, then the
absorption would increase by 4 W / m2, but once the water vapor and clouds react, the
absorption increases by almost 20 W / m2 — demonstrating that (
in the GISS climate model, at least) the «feedbacks» are amplifying the effects of the initial
radiative forcing from CO2 alone.
Your hypothesis assumes that increased
absorption of energy
in the troposphere will be transmitted to the surface by convection, since
radiative transfer doesn't change if the temperature remains constant, and the
radiative imbalance at the TOA wouldn't change.
Aerosol particles infl uence
radiative forcing directly through refl ection and
absorption of solar and infrared radiation
in the atmosphere.
If that is the case and if the continuum is coming
in from all directions, then there is no net
radiative power transfer going on and
in fact, one would not observe any
absorption spectra (or emission spectra) at all.
«Because the solar - thermal energy balance of Earth [at the top of the atmosphere (TOA)-RSB- is maintained by
radiative processes only, and because all the global net advective energy transports must equal zero, it follows that the global average surface temperature must be determined
in full by the
radiative fluxes arising from the patterns of temperature and
absorption of radiation.»
depending on what I'm doing, I can do straight attenuation or do
radiative transfer where there is both
absorption and emission
in a layer.
Would it have been so difficult to terminate the smaller atmospheric
absorption arrow
in the atmosphere itself and then have a separate set of arrows (both toward the surface and into space) showing the
radiative energy from the atmosphere?
Vis.: www.garfield.library.upenn.edu/classics1981/A1981LQ21800001.pdf Even more to the point, he goes on to state that [quote] «The regions of validity of the linear, square root, and nonoverlapping approximations were considered
in this article...» [endquote] and notes that the summary of the [quote] «various models and approximations for band
absorption» [endquote] given
in that article had apparently been useful
in many later studies requiring [quote] «mathematical calculation» [endquote] of the
radiative exchange by infrared bands.
The
radiative energy inciding on our skin is absorbed by the molecules of water
in our bodies by Resonance
Absorption.
They assume a basis for all this, the
radiative heat
absorption by CO2 (this is
in their founding documents), and produce massive summaries, generally including long term ordinary linear regression
in approriately applied to a time series, and then make a statement such as «an increase of.2 deg C / decade».
Pekka, to claim that the temperature effect of CO2 absorbing IR
in the atmosphere is unmeasurable except
in the atmosphere is a good way of glossing over the fact that the claimed warming phenomenon (backradiation or insulation or IR
absorption) is: a. imprecisely described, and non-existent according to G&T b. untested
in the laboratory — probably because it hasn't been precisely described c. very small according to the precisely measured
radiative transfer data precisely modeled
in Spectralcalc d. confounded by other variables
in the real atmosphere
We need to examine the Gas Laws
in some detail to consider how the
radiative absorption capabilities of Greenhouse Gases could be dealt with given that the Gas Laws have no term for the
radiative capabilities of molecules.
In any case, yes,
radiative effects should be accounted for with a first - principles
radiative model, that is to say, insolation +
absorption (I don't think this is hard to do).
The direct
radiative effects of aerosols can be divided
in reflection and
absorption.
This study seeks to explain the effects of cloud on changes
in atmospheric
radiative absorption that largely balance changes
in global mean precipitation under climate change.
And, there is plenty of empirical data at every level: There is empirical data on the basic
absorption lines of the various atmospheric constituents, there is a wealth of empirical data backing up the basic equations of
radiative transfer that are applied
in calculating the greenhouse effect
in just the same way that engineers and scientists use these equations everyday
in other calculations, there is empirical spectra looking both up from the surface of the earth and down from satellites.
In the absence of
absorption of terrestrial radiation by the atmosphere (and with the other caveats about still having the same albedo and such), that average temperature would have to be 255 K at the surface because of
radiative balance and then the temperature would decrease with height at the lapse rate from there.
jae says: «You are making the usual EXTREMELY big jump
in saying that because there is
absorption / emission by GHGs that there is a
radiative GHE.»
If I were choosing a model to describe with as much quantitative fidelity as possible the greenhouse effect
in the earth's atmosphere, then the model I would choose would be a state - of - the - art convective -
radiative transfer code using the actual composition and empirical
absorption / emission lines for the atmospheric constituents.
You are making the usual EXTREMELY big jump
in saying that because there is
absorption / emission by GHGs that there is a
radiative GHE.
Relative integrated IR
absorption in the atmospheric window is not the same as relative
radiative efficiency
1950s: Research on military applications of radar and infrared radiation promotes advances
in radiative transfer theory and measurements = > Radiation math — Studies conducted largely for military applications give accurate values of infrared
absorption by gases = > CO2 greenhouse — Nuclear physicists and chemists develop Carbon - 14 analysis, useful for dating ancient climate changes = > Carbon dates, for detecting carbon from fossil fuels
in the atmosphere, and for measuring the rate of ocean turnover = > CO2 greenhouse — Development of digital computers affects many fields including the calculation of radiation transfer
in the atmosphere = > Radiation math, and makes it possible to model weather processes = > Models (GCMs)-- Geological studies of polar wandering help provoke Ewing - Donn model of ice ages = > Simple models — Improvements
in infrared instrumentation (mainly for industrial processes) allow very precise measurements of atmospheric CO2 = > CO2 greenhouse.
The solar shortwave
absorption is by far the largest uncertainty
in modeling the global
radiative budget.