The lab irradiated neptunium - 237, and these juiced - up atoms decayed into plutonium - 238, which the engineers isolated and shipped off to be turned into pellets.
They use the High Flux Isotope Reactor, a DOE Office of Science User Facility at ORNL, to irradiate the pellets, creating neptunium - 238, which quickly decays and becomes plutonium - 238.