It is known that
larger hydrocarbon molecules like ethane and propane can also form hydrates, although longer molecules (butanes, pentanes) can not fit into the water cage structure and tend to destabilise the formation of hydrates.
Mango believes he has now found the missing ingredient: transition metals such as nickel and vanadium, which catalyse the breakdown of
large hydrocarbon molecules into methane.
The geologist started to investigate the idea three years ago, and last year produced gas containing a greater proportion of methane by heating a mixture of
large hydrocarbon molecules, hydrogen and carbon - rich rocks to 190 °C for several days.
Not exact matches
Some of those
large molecules are like small sheets of graphite with hydrogen attached to them: we call these polycyclic aromatic
hydrocarbons and they can be found in terrestrial counterparts like mothballs, for example.
There is also evidence for much
larger molecules such as polycyclic aromatic
hydrocarbons, which resemble the soot from automobile emission.