Not exact matches
For example, when physicists explain the electrical conductivity of
metals in terms of the «band structure» of the energy levels of the electrons
in a crystal lattice of
atoms, to which of the four causes does that correspond?
Clay minerals consist of crystals
in which
atoms of silicon, oxygen and a number of
metals, such as aluminum, iron and various rarer and less frequent ones, are arranged
in a three - dimensional lattice.
For example, the presence of hydrogen and methane are clues that the chemical environment of the fluid
in which the diamond crystallized was one
in which the
metal atoms could easily gain electrons and disengage from carbon
atoms.
Ti (3) SiC (2) was the first MAX phase Drexel researchers tried to selectively etch
in 2011, but synthesis failed using hydrofluoric acid alone because the silicon
atoms are strongly bound to the adjacent transition
metal atoms.
Seeking such a strategy, researchers at Northwestern University
in Evanston, Illinois, created an organic ring - shaped molecule with four
metal atoms: two zincs and two rhodiums.
This technique, described
in the Feb. 2 Physical Review Letters, showed that 2 - D semiconductors arranged
in single -
atom - thick sheets expand more like plastics than
metals when heated.
In fact, the heat response of the single -
atom - thick semiconductors is «more like [that] of a plastic than a
metal,» Mecklenburg says.
The arrangement of
atoms in an alloy changes the chemical properties of its constituent
metals and makes it potentially useful to catalyse reactions.
However, the so called «displacements - per -
atom» (dpa) number obtained from this equation does not
in common
metals usually correspond to any physically measurable quantity.
Carefully tuned
in the laboratory, these coatings can produce a bright, solid pink — or, say, a vivid blue — using the same two
metals, applied with only a few
atoms» difference
in thickness.
This latest study looked at how the soft element arsenic interacts with thorium, because arsenic could
in principle be used
in organic molecules that bond to
metal atoms and improve extraction processes.
When the
metal is bent or stressed, planes of
atoms in the grains slide past one another, sometimes causing crystalline defects to connect with each other — producing fractures.
The cathode material
in lithium batteries is typically «ordered,» meaning the lithium and transition
metal atoms are arranged
in neat layers, allowing lithium to move
in and out of the layers.
But
in our process the
atoms driving catalysis have no
metal atoms next to them.
But on an atomic scale, it has remarkable properties: on magnetite, single
metal atoms are held
in place, or they can be made to move across the surface.
Among other things, they can now better predict the behavior of electrons
in graphene, a flat sheet of carbon just a single
atom thick, which acts like a strange
metal under certain conditions.
As long as the gold
atoms, or cations, are stabilized
in a single - site form configuration, irrespective of the type of support, the precious
metal will be stable and operate for many hours at a range of practical temperatures.
This innovative land mine detector can find explosives that are not encased
in metal by detecting the hydrogen
atoms that comprise the devious war devices.
That calculation requires measuring the x-rays» intensity and determining their phase, the relative timing — a harder problem traditionally solved by comparing the diffraction pattern from a pure crystal with one from a similar crystal
in which heavy
metal atoms substitute for some components of the crystal.
In recent years researchers have achieved better performance with compounds such as lithium borohydride, in which the metal atoms form weaker, ionic bonds with groups containing several hydrogen atom
In recent years researchers have achieved better performance with compounds such as lithium borohydride,
in which the metal atoms form weaker, ionic bonds with groups containing several hydrogen atom
in which the
metal atoms form weaker, ionic bonds with groups containing several hydrogen
atoms.
Specifically, computer simulations suggested which amino - acid building blocks should comprise the future transporter, so that it would carry ionic
atoms of
metal zinc
in one direction across membranes, while pumping protons
in the other.
Surprisingly, it is unclear what happens when an X-ray is absorbed, for example,
in biological tissue consisting of water, biomolecules and some
metal atoms.
The lens manufacturer Nion Co.
in Kirkland, Washington, has found a way to tighten the beam so that
atoms situated behind other
atoms are clearly visible, as are heavy -
metal atoms that were previously undetectable.
I knew that heme, the oxygen - carrying molecule
in hemoglobin, contained an iron
atom within a porphyrin ring (for more information on porphyrin chemistry see this site at Washburn University), but Dr. Datta - Gupta and his laboratory technician attempted to chemically add different
metals such as copper, magnesium, or manganese to porphyrins using column chromatography.
POMs are molecular transition
metal - oxygen clusters
in which the
metal atoms are bridged by oxygen
atoms to form a three - dimensional network.
In recent years, the have presented important new findings about the structure of
metal oxides, about the mobility of
atoms on their surface and their chemical properties.
Nevalaita and Koskinen created three periodic tables that chart the properties of 2 - D
metals with
atoms in triangular, square or honeycomb configurations.
Aside from the demonstration that
metal atoms can form freestanding 2D membranes there is significant interest
in the potential of such 2D
metal materials as they are expected to have exotic properties.
In these structures ligands, which are organic or inorganic molecules of variable independent stability, bind to one or more transition
metal atoms.
For instance,
atoms of any given
metal arranged
in a triangular lattice typically had about 70 percent the bond strength of
atoms in the 3 - D version of that
metal.
The formation of 2D atomically thin metallic layers over other surfaces has previously been demonstrated, however
in this case the
metal atoms interact with the underlying substrate.
The term is generally reserved for complexes
in which the
metal ion is bound to two or more
atoms of the chelating agent, although the bonds may be any combination of coordination or ionic bonds.
Artistic impression of the squeezed light (plasmon)
in between the
metal and graphene, separated by a one -
atom thick dielectric.
Nevalaita and Koskinen also compared the stability of 2 - D
metals whose
atoms were arranged
in the three different configurations.
But whereas those materials were made up of covalent bonds —
in which pairs of
atoms share electrons — these 2 - D
metals are composed of metallic bonds, where electrons flow more freely among
atoms.
«We might be able to open up a new kind of chemistry where elements could be simulated with
metals —
in this case aluminum — of different numbers of
atoms.»
ULTRATHIN FILMS Computer simulations reveal the properties of a little - studied group of synthetic materials: 2 - D arrays of
metal atoms arranged
in honeycombs (illustrated), triangles or squares.
To understand how they work, we can take a look at nature itself: while natural elements acquire their physical properties from the
atoms that form them and the way
in which they are ordered, metamaterials use natural means, like small
metal fragments that fit together like parts of a Meccano model to artificially synthesise properties that are impossible to find otherwise.
Meyer, a chemist at University of North Carolina at Chapel Hill and director of its Energy Frontier Research Center
in Solar Fuels, noticed that two separate groups of researchers working on two separate parts of the photosynthetic reaction happened to be using the same class of catalyst — ones with an
atom of the
metal ruthenium surrounded by organic molecules.
«
In essence,» said co-author Darren W. Johnson, a professor of chemistry, «we can prepare one type of nanoscale cluster compound, and then step - by - step substitute out the individual
metal atoms to make new clusters that can not be made by direct methods.
The process described
in the paper represents a new approach to transmetalation,
in which individual
atoms of one
metal complex — a cluster
in this case — are individually substituted
in water.
Melanie Sanford, a chemist the University of Michigan, Ann Arbor, who focuses on using
metal - based agents, primarily palladium, to catalyze reactions that substitute hydrogen
in carbon - hydrogen bonds with other
atoms or functional groups.
The Kondo effect, first described last century by the Japanese physicist Jun Kondo, is observed when magnetic impurities, i.e., very few
atoms (even only 1
in 1000) of magnetic material such as iron are added to
metals like gold or copper.
Specifically, a
metal - organic framework compound, copper [1,3 - benzenedicarboxylate] with a unique arrangement of copper
atoms in a crystal, has been shown to exhibit this novel behavior.
He knew he needed to find
metals that were deft at breaking the carbon - hydrogen bonds that are at the heart of methane, ethane, and propane, short hydrocarbons known as alkanes, and then add
in oxygen
atoms that would transform the alkanes into alcohols.
Inside its three - story
metal sphere researchers can interpret and interact with their data
in new and intriguing ways, including watching electrons spin from inside an
atom or «flying» through an MRI scan of a patient's brain as blood density levels play as music.
In metals, for instance, electrons freely flow around and between
atoms.
«We were excited to find that the platinum
metal dissolved
in copper, just like sugar
in hot coffee, all the way down to single
atoms.
In the early 2000s, Maria's group had pioneered the single -
atom approach for
metals anchored on oxide supports as the exclusive active sites for the water - gas shift reaction to upgrade hydrogen streams for fuel cell use.
After decades of eluding researchers because of chemical instability, key
metal - oxide clusters have been isolated
in water, a significant advance for growing the clusters with the impeccable control over
atoms that's required to manufacture small features
in electronic circuits.