CO2 molecules are incapable of absorbing any radiation above the 15
micron band from the earth's surface.
Not exact matches
The movies are created with data
from GOES infrared 6.7
micron band.
Spectrally, the opacity of the atmospheric column ranges
from a few tenths in the 10
micron window region to many thousands in the center of the 15
micron CO2
band.
CO2, in contrast, strongly absorbs wavelengths > 13 times longer than O2 does, as well as other
bands around 2 - 3 and 4 - 5
microns, while water vapor absorbs strongly
from around 5 - 8
microns.
Which references... «Absolute Intensities of the Discrete and Continuous Absorption
Bands of Oxygen Gas at 1.26 and 1.065 Micron» (1965, Badger et al.) https://authors.library.caltech.edu/10448/1/BADjcp65.pdf «Molecular oxygen (O2) has absorption bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).&r
Bands of Oxygen Gas at 1.26 and 1.065
Micron» (1965, Badger et al.) https://authors.library.caltech.edu/10448/1/BADjcp65.pdf «Molecular oxygen (O2) has absorption
bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).&r
bands throughout the spectrum
from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1)
from individual O2 molecules and (2)
from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).»
The shape of the CO2 absorption
band, in terms of CSD per unit CO2 concentration, can be approximated as having a peak at some frequency (designated ν0) or wavelength (about 15
microns for CO2) with, on each side of that peak, a halving of that optical thickness for each amount BW1 or BW2 that one moves away
from the center (toward lower or higher frequency, respectively)
Thus, a very thin layer near the top of the stratosphere will essentially only be heated (absent solar heating) by radiation
from below at the peak of the CO2
band near 15
microns.
(CO2 is saturated at the tropopause level in the central portion of it's dominant (for Earth)
band (centered near 15
microns), but the optical thickness per unit CO2 declines away
from the center in such a way that the width of the
band exceeding a given optical thickness tends to widen by some amount with each doubling; it is this shifting of the «edges» of the
band where adding more CO2 has an effect.)
(CO2
band is near the peak wavelength, water vapor
bands significant in stratosphere for wavelengths longer than ~ 25
microns and between ~ 5.5 and 7
microns, and ozone between ~ 9.5 and 10
microns, and CH4 and N2O between ~ 7.5 and 8
microns — Hartmann p. 44 and 48, rough est.
from graphs; signficant stratospheric transparency remains in several of those
bands except near the peak of the CO2
band, but especially water vapor
from 25 to 50
microns.)
So seen
from outer space the earth radiation spectrum should be a small (10 % area) 288K thermal spectrum, overlaid with prominent GHG
band spectra like CO2 15
micron peaks, and various water peaks, plus the Ozone 9.6
micron peak.
george e smith says: July 18, 2013 at 12:57 pm «So seen
from outer space the earth radiation spectrum should be a small (10 % area) 288K thermal spectrum, overlaid with prominent GHG
band spectra like CO2 15
micron peaks, and various water peaks, plus the Ozone 9.6
micron peak.
There are 16 thermal emissive
bands (TEBs), covering wavelengths
from 3.7 to 14.4
microns.
Thus water doesn't play any role in the 3 - 4
micron band and all energy absorbed there (as can be seen in the «total absorption and scattering» graph) is
from CO2 alone and nothing else, whatever the water content of the atmosphere.
The gases in the bottles are being heated by conduction but CO2 is also absorbing significant IR in the 2.7
micron band directly
from the radiant emissions
from the lamp as glass transmits a significant proportion of the radiation at this wavelength and significant IR
from the heated glass in the ~ 15
micron bandwidth.
The net effect on Earth Venus and Mars
from CO2 as a gas is virtually identical demonstrating the limited effect
from CO2 beacuse the 14.77
micron band gets so close to saturation by just 300ppmv with further increases like the 950,000 ppmv high pressure concentration on Venus having very little additional effect.
Nowhere
from 9 to 13
microns do we see appreciable absorption
bands of CO2.
I guess the ∆ T ~ ln C is an empirical formula
from the fact that the 15 -
micron O2
band is practically saturated at the peak, and hence the additional CO2 causes essentially slow
band broadening, which is approximated by the ∆ T ~ ln C formula.
In Earth's atmosphere, there is a «window» between the 8 and 12
micron band where there is virtually no absorption going on, and through which IR radiation passes out
from the surface to space virtually unimpeded.
If we take the total radiation
from our 1 square metre to be 100 %, what percentage of that energy is radiated in the 15
micron band?
It is apparent
from whatyou say that you are not familiar with «Wien's law of displacement» judging by your comment that the spectral
band from 12 to 18
microns includes the peak emission of the Earth's emission spectrum.
On the other hand, the single CO vibrational
band only absorbs IR at much shorter wavelengths (4.7
microns, or 2145 cm − 1), where the emission of radiant energy
from Earth's surface is at least a factor of ten lower.
But I am pretty confident there will be detectable emissions in the.5 to 50
micron range
from playing around with a.5 to 50
micron hand held detector many, many years ago, aiming it at the sky, the sun, etc and comparing the output to a detector using much narrower
bands.
The AGW hypothesis states that a doubling of atmospheric CO2 will increase the global temperature by approximately 2.78 °C but the 14.77
micron band of the Earth's thermal radiative spectrum is already so close to satureation that no more than half a degree C of warming
from a doubling of CO2 is even (remotely) physically possible.
CO2 at concentrations of just 300ppmv has a very strong effect on a narrow
band of the Earth's thermal radiation centred on 14.77
microns taking over about 10 % of the Earth's greenhouse effect
from clouds and water vapour.