The researchers report in Nano Letters that by combining inorganic semiconductor
nanocrystals with organic molecules, they have succeeded in «upconverting» photons in the visible and near - infrared regions of the solar spectrum.
Using star - shaped block co-polymer structures as tiny reaction vessels, researchers have developed an improved technique for producing
nanocrystals with consistent sizes, compositions and architectures — including metallic, ferroelectric, magnetic, semiconductor and luminescent nanocrystals.
For the future, Lin envisions more complex
nanocrystals with multifunctional shells and additional shapes, including nanorods and so - called «Janus» nanoparticles that are composed of biphasic geometry of two dissimilar materials.
The research results, «Germanium - Tin / Cadmium Sulfide Core / Shell
Nanocrystals with Enhanced Near - Infrared Photoluminescence,» were published in the American Chemical Society's journal Chemistry of Materials.
The result is CdS semiconductor
nanocrystals with associated size - dependent band gap and photoluminescent properties.
Using an engineered strain of Stenotrophomonas maltophilia to control particle size, Lehigh researchers biosynthesized quantum dots using bacteria and cadmium sulfide to provide a route to low - cost, scalable and green synthesis of CdS
nanocrystals with extrinsic crystallite size control in the quantum confinement range.
In a paper published June 13 in Angewandte Chemie, the UCSC researchers reported the results of experiments using unique branched ligands to synthesize perovskite
nanocrystals with greatly improved stability and uniform particle size.
«You need several control samples — a PbS
nanocrystal with lead oxide precursor and another precursor that does not involve water during synthesis,» he says.
Not exact matches
A nanoparticle (or nanopowder or nanocluster or
nanocrystal) is a microscopic particle
with at least one dimension less than 100 nm.
Philippe Walter of the C2RMF, lead author of the report, says he has not studied what happens to hair dyed
with Grecian Formula, but he suspects
nanocrystals are also at work.
Conventional perovskite
nanocrystals capped
with ligands consisting of long straight - chain amines show poor stability in solvents such as water and alcohol.
«Novel capping strategy improves stability of perovskite
nanocrystals: Study addresses instability issues
with organometal - halide perovskites, a promising class of materials for solar cells, LEDs, and other applications.»
A City College of New York led - team has successfully demonstrated how to both enhance light emission and capture light from metamaterials embedded
with light emitting
nanocrystals.
Nanocrystals selectively infused, or «doped»,
with rare - earth ions have attracted the attention of researchers, because of their low toxicity and ability to convert low - energy laser light into violet - colored luminescence emissions — a process known as photon upconversion.
Experiments revealed that the isolated Yb «energy clusters» inside this pill - shaped
nanocrystal (see image) enabled substantially higher dopant concentrations than usual — Yb accounted for up to 98 per cent of the crystal's mass — and helped initiate multiphoton upconversion that yielded violet light
with an intensity eight times higher than previously seen.
The material was synthesized by exploiting the structural evolution of platinum - nickel (Pt - Ni) bimetallic
nanocrystals into cage - like structures
with a self - assembled Pt skin structure on the interior and exterior surfaces.
This light stimulates dyes made
with nanocrystals of rare earth elements — a family of 17 similar metals that are not scarce but are difficult to mine.
The best defence against being tagged
with nanocrystals sprayed by drones controlled by border guards, police or the army (24...
This combined
nanocrystals - nanoantenna device was able to produce a highly directional stream of single photons all flying to the same direction
with a record low divergence angle.
«The atoms are in a very specific location within the
nanocrystal core and when you apply the shell around the
nanocrystal, the atoms of the shell may not match perfectly
with the atoms of the core,» Smith said.
Semiconductor
nanocrystals, or quantum dots, are tiny, nanometer - sized particles
with the ability to absorb light and re-emit it
with well - defined colors.
The other facet of the
nanocrystal,
with both lead and sulfur exposed, was bare of ligands.
These findings have been reported in a Science paper titled «Hydroxylation of the Surface of PbS
Nanocrystals Passivated
with Oleic Acid.»
Calculated atomic structure of a 5nm diameter
nanocrystal passivated
with oleate and hydroxyl ligands.
To achieve this, he used a
nanocrystal sample produced from lead chloride instead of lead oxide, such that there was no way for water to be generated in the reaction
with oleic acid.
Small organic fluorescent dyes,
nanocrystals («quantum dots»), autofluorescent proteins, small genetic encoded tags that can be complexed
with fluorochromes, and combinations of these probes are highlighted.
Their tests
with transmission electron microscopy on the
nanocrystals, which form as ultrathin films, plates and tiny particles, reveal the desired quality and uniformity.
Together
with colleagues from Forschungszentrum Jülich, the University of Edinburgh and the University of Nottingham, Almeida has studied the magnetic vortices in magnetite
nanocrystals.
Empa researchers Gilberto Siqueira and Tanja Zimmermann from the Laboratory for Applied Wood Materials have now succeeded, together
with colleagues from Harvard University and ETH Zürich, in developing a new, environmentally friendly 3D printing ink made from cellulose
nanocrystals (CNC).
Earlier techniques for producing polymeric micelles
with linear block co-polymers have been limited by the stability of the structures and by the consistency of the
nanocrystals they produce, Lin said.
Other forms of quantum dots could be used as a sensor in place of the molecule, such as those that can be realized
with semiconductor materials: one example would be quantum dots made of
nanocrystals like those already being used in fundamental research.
«In
nanocrystals, the gap changes
with their size — the smaller the size, the larger the gap,» says physicist Victor Klimov of Los Alamos National Laboratory in New Mexico.
Nanocrystal lasers might be cheaper, more efficient and versatile compared
with today's kind, Krauss says, perhaps leading to chemical sensors or optical communications devices capable of rapidly switching between laser colors.
In the new report published in Nature Materials, the Los Alamos team demonstrates that using their «designer» quantum dots, they can achieve light amplification in a
nanocrystal solid
with direct - current electrical pumping.
The particles, which are invisible to the naked eye, contain colored stripes of
nanocrystals that glow brightly when lit up
with near - infrared light.
Recently, his group has developed a number of high - performance electrocatalysts made
with non-precious metal oxide or
nanocrystals hybridized
with carbon nanotubes.
Two papers
with among the longest titles found in the journal that year, «The role of particle morphology in interfacial energy transfer in CDSE / CDS heterostructure
nanocrystals» and «Insects betray themselves in nature to predators by rapid isomerization of green leaf volatiles,» have 68 and 67 citations, respectively.
«The direct growth of anchored MoSoy
nanocrystals on graphene sheets may enhance the formation of strongly coupled hybrid materials
with intimate, seamless electron transfer pathways, thus accelerating the electron transfer rate for the chemical desorption of hydrogen from the catalyst, further reducing the energy required for the reaction to take place,» Sasaki said.
The collaboration
with high - tech startup company ThermoAura, focusing on
nanocrystal synthesis, also contributed to the success of this work.
Researchers at the U.S. Naval Research Laboratory (NRL) Center for Computational Materials Science, working
with an international team of physicists, have revealed that
nanocrystals made of cesium lead halide perovskites (CsPbX3), is the first discovered material which the ground exciton state is «bright,» making it an attractive candidate for more efficient solid - state lasers and light emitting diodes (LEDs).
Visualization and quantitation of peroxisomes using fluorescent
nanocrystals: treatment of rats and monkeys
with fibrates and detection in the liver.
Now, Rosso and teams at PNNL, EMSL, the Environmental Molecular Sciences Laboratory, a DOE Office of Science User Facility at PNNL, and the University of Pittsburgh developed a new approach by combining an environmental transmission electron microscope, called an ETEM,
with nanocrystal force probes that allows scientists to watch crystals interact in a life - like situation.
A
nanocrystal can be doped
with 5,000 to 10,000 impurities so it emits a certain color in the near - infrared
with a very narrow spectral peak.
They discovered that by coating blue LEDs
with a layer of
nanocrystals specially engineered to turn the blue light into warm white, they could produce light at efficiency of over 300 lumens of visible light per watt.