The phrase
"nickel atoms" refers to individual particles of the chemical element nickel.
Full definition
The researchers were mixing organic nitrogen - rich compounds
with nickel atoms and water.
By scanning an electron probe over the sample, the scientists were able to visualize discrete
nickel atoms on the graphene.
To make the nickel oxide coating, the researchers used a technique which involves smashing atoms of argon into a pellet
of nickel atoms at high speed.
Based on the results from the studies at Harvard, NSLS - II, CFN, and additional institutions, the scientists discovered single
nickel atoms catalyzed the CO2 conversion reaction with a maximal of 97 percent efficiency.
«Converting CO2 into usable energy: Scientists show that
single nickel atoms are an efficient, cost - effective catalyst for converting carbon dioxide into useful chemicals.»
To get a closer look at the
individual nickel atoms within the atomically thin graphene sheet, the scientists used scanning transmission electron microscopy (STEM) at Brookhaven's Center for Functional Nanomaterials (CFN), a DOE Office of Science User Facility.
If that field interacts with itself, then, as the infant universe expanded and cooled, the field may have taken on a value or «phase,» which would be a bit like the direction in
which nickel atoms point.
Nickel atoms act like little magnets themselves, and below a certain temperature, neighboring atoms tend to point in the same direction, so that their magnetic fields reinforce one another.
High temperatures caused carbon to diffuse to the surface, where
mobile nickel atoms catalyzed graphene growth on the edges of islands.
The researchers discovered that the unique manner in which the platinum and
nickel atoms arrange themselves on the surfaces of these particles serves to optimally accelerate the chemical reaction between hydrogen and oxygen to form water.
«On the surface of nickelate, you have one
nickel atom at the center of a square of four oxygen atoms,» Cooper said.
«However, we found the
individual nickel atoms were distributed uniformly, which accounted for the excellent performance of the conversion reaction.»
Tetrahedra with
a nickel atom at their centre are somewhat elongated due to the Jahn - Teller effect (green), while the tetrahedrons with a copper atom at their centre are compressed (blue).
«Photons, or particles of light, interact with the electrons in
the nickel atoms to do two things,» Stavitski said.
In addition to the unique energetic properties of single atoms, the CO2 conversation reaction was facilitated by the interaction of
the nickel atoms with a surrounding sheet of graphene.
In essence, this provided the scientists with an image of
the nickel atoms» local structure.
The scientists could show that during fast charging, manganese and
nickel atoms are leached from the crystal structure.
The technique incorporates
some nickel atoms into the diamond's crystal structure, forming what is called an «S3 defect center.»
Oxygen from the air dissolves into the liquid and selectively etches away some of
the nickel atoms.