It is my understanding that radiative gases provide an additional radiative route for energy loss to space that
non radiative gases fail to provide.
There have been many «heated» discussions on various blogs as to the hypothetical structure of the atmosphere composed of no greenhouse gases, only
non radiative gases.
N2 and O2 are generally called
non radiative gases in climate science, but they do absorb and emit IR.
Not exact matches
3) Under the assumption of
radiative equilibrium, it can be shown that the surface temperature of a planet would slightly and
non linearily increase with the concentration of IR active
gases (primarily H2O) if and only if radiation was the only mean for energy transfer.
Without the
radiative forcing supplied by CO2 and the other
non condensing greenhouse
gases, the terrestrial greenhouse would collapse, plunging the global climate into an icebound Earth state.»
A
non radiative atmosphere should not be considered a «bizarre case» but rather the base line for all modelling of levels of
radiative gases in the atmosphere.
«in an isotropic
non GHG world, the net would be zero, as the mean conduction flux would equalize, but in our earth it is still nearly zero» if the atmosphere were isothermal at the same temperature as the surface then exactly the downwelling radiation absorbed by the surface would be equal to the radiation of th surface absorbed by the air (or rather by its trace
gases) and both numbers would be (1 - 2E3 (t (nu)-RRB--RRB- pi B (nu, T) where t (nu) is the optical thickness, B the Planck function, nu the optical frequency and T the temperature; as the flow from the air absorbed by the surface is equal to the flow from the surface absorbed by the air, the
radiative heat transfer is zero between surface and air.
You had to elaborate your answer by saying that
gases with
non polar molecule symmetry do not absorb or emit energy within the temperature parameters with any application in engineering, e.g. O2, N2, H2..., while
gases with polar molecule symmetries are significant absorbers and emitters of
radiative energy, e.g. H2O, CO2, SO3... for engineering applications, depending of their density, temperature and pressure in a given environment.