The molecular
structure of the active material in the battery electrodes is composed of nickel (Ni), manganese (Mn) and oxygen (O)-- where the structure is a relatively rigid crystal lattice into which the lithium ions, as mobile charge carriers, can be inserted or extracted.
«Cyclic charge and discharge of a battery induces structural
evolution of the active materials, and such a structural evolution is attributed to the failure of the battery,» says team member Chongmin Wang at the Pacific Northwest National Laboratory in Richland, Washington.
Recently we used this principle to demonstrate rapid switching electrochromic devices with nearly 100 percent light absorption using only 15
nm of active material uniformly electrodeposted over the nanoslit array surface.5 Using the same approach we will electrodeposit PEC active materials onto Al plasmonic substrates to achieve highly efficient PEC process.
«Our work has fundamental contributions by introducing electrical bias as a way to control the
phase of an active material, and by laying the basic scientific groundwork for such novel energy and information processing devices,» Yildiz adds.
Graphite has been the default
choice of active material for anodes in lithium — ion batteries since their original launch by Sony but researchers and manufacturers have long sought a way to replace graphite with silicon, as it is an abundantly available element with ten times the gravimetric energy density of graphite.
But Duan said that the
performance of the active material in such tiny amounts is canceled out by the bulkier inactive components of an electrode, like the current collectors.
In this geometry, electrons (or holes) propagate perpendicular to the slit orientation seeing only a thin
layer of active material (tens of nanometers), while light propagates as SPPs along the slit length, effectively seeing a much thicker layer.
(b) scanning electron micrograph of nanoslit array coated with electrochromic polymer (c) plasmonic nanoslits with 15 nm
of active material absorbing / transmitting light across the visible spectrum with > 80 % contrast.5
The team used electron microscopy and other surface - and bulk - sensitive tools, located in EMSL, to probe the structural
evolution of active materials.