Made with metal canisters
of ammonium nitrate which can deteriorate if exposed to prolonged heat and humidity, these airbags may be literal time - bombs.
A consortium of 10 automaker clients of Takata has just determined that the root causes of the shrapnel misfires are the supplier's use
of ammonium nitrate, plus the way Takata constructed the assembly, both combined with exposure to heat and humidity, Automotive News reported Tuesday.
The West, Texas, disaster will, if anything, only accelerate the declining usage
of ammonium nitrate as a fertilizer, Ferguson said.
A carelessly tossed cigarette started a fire aboard a ship carrying about 2,300 tons (2,086,000 kilograms)
of ammonium nitrate packed in paper sacks.
The experimental plots of irrigated and tilled (disk / chisel) continuous corn have received six different rates
of ammonium nitrate fertilizer (range 0 to 200 pounds / acre) for 50 years.
To demonstrate one potential use of the nanoparticles, the research team used them as advanced catalysts for ammonia oxidation, which is a key step in the production of nitric acid (a liquid acid that is used in the production
of ammonium nitrate for fertilizers, making plastics, and in the manufacturing of dyes).
Not exact matches
The result is
ammonium nitrate and
ammonium sulfate, molecules that condense with others
of their kind, plus water, to form tiny particles in the air that absorb sunlight and block visibility — smog.
Because
of its danger and potential use by terrorists,
ammonium nitrate is subject to strict regulation in most places.
A faintsmell
of ammonium -
nitrate explosive hangs in the air during the secondelevator descent.
Plants fertilized with
ammonium grew almost twice as much as the plants fertilized with
nitrate, and their darker green leaves attested to higher levels
of protein, the team reports in the 5 February issue
of the Proceedings
of the National Academy
of Sciences.
The continuing high acidity
of the sulfate particles has limited
ammonium nitrate formation, the researchers believe.
But ammonia plants also produce anhydrous ammonia,
ammonium nitrate (the compound that caused last week's explosion in Texas),
ammonium sulfate, UAN (urea
ammonium nitrate solution) and other forms
of ammonia used in agricultural and industrial applications — none
of which use the leftover CO2.
In 2010, about one - third
of deposited nitrogen was in the form
of nitrate, with the rest being
ammonium; by contrast, in 1980,
nitrate made up just 17 %
of deposited nitrogen.
The findings, published in the journal Nature Plants, show
ammonium nitrate fertiliser used in wheat cultivation contributes almost half (43 per cent)
of the greenhouse gas emissions — dwarfing all other processes in the supply chain.
Historical cases
of fertilisers detonating include one on 16 April 1947, when a boat carrying
ammonium nitrate fertiliser in Texas accidentally exploded, killing almost 600 people.
In this case, the array
of sensors was formed
of 21 ion - selective electrodes, including some with response to cations (
ammonium, sodium), others with response to anions (
nitrate, chloride, etc.), as well as electrodes with generic (unspecified) response to the varieties considered.
His firm is supplying the plant with CO2 — a by - product
of making
ammonium nitrate.
But because
of its low price, effectiveness and relative ease
of transport,
ammonium nitrate will probably still be in use — and still pose a danger — for some time.
«I'm not aware
of any state where
ammonium nitrate is predominant source [
of inorganic fertilizer] where 30, 40 years ago it might have been,» Ferguson told TechNewsDaily.
«In many parts
of the country,
ammonium nitrate has largely disappeared from the market because
of the concern for its safety,» Ferguson told TechNewsDaily.
By number, it is typically a mix
of sulphate,
nitrate,
ammonium, and a wide spectrum
of carbonaceous (elemental and organic carbon) compounds.
Ocean acidification is also predicted to reduce microbial production
of nitrate from
ammonium (Beman et al., 2011), which could have major consequences for oceanic primary production because a significant fraction
of the
nitrate used by phytoplankton is generated by nitrification at the ocean surface (Yool et al., 2007).
Currently, fertilizer is made using natural gas (steam reforming
of methane to generate hydrogen to feed into the Haber process)-- but with the new advances (http://www.greencarcongress.com/2008/07/researchers-at.html), it should be possible to generate that hydrogen directly from water using sunlight; feed the hydrogen into the Haber process (energy expensive, true, but doable), and then you have your ammonia, convert half
of that to
nitrate, and there you have your
ammonium nitrate fertilizer, which currently accounts for about 1/2
of all agricultral fossil fuel use.
A majority
of sub-micrometer particles (< 1 µm in diameter, PM1) originated from diesel engine emissions whereas another sub-micrometer particle type originated from the combustion products
of explosives (e.g.
nitrate and
ammonium).
Ford, which also manufactures the Lincoln brand, said it was notified
of the problem by Takata and that it is not related to the Japanese company's massive ongoing recall involving non-desiccated
ammonium -
nitrate airbag inflators that are subject to propellant degradation and potential rupture in a crash.
The report went on to name FCA among a subset
of the group that still makes non-desiccated
ammonium nitrate inflators.
FCA agrees, noting that desiccated
ammonium nitrate inflators are unassociated with inflator ruptures «
of the kind attributed to certain non-desiccated
ammonium nitrate inflators.»
FCA says most
of its airbag inflators employ another propellant, while some have
ammonium nitrate inflators with desiccant, a moisture inhibitor that Takata claims mitigates the risk
of rupture.
The June 1 report said certain other automakers, including Honda, Nissan and Ford, also have new cars with Takata's
ammonium nitrate inflators, but they have desiccant, a drying agent that reduces the likelihood
of unintended airbag rupture.
The safety agency previously gave Takata until the end
of 2019 to prove that its remaining airbag inflators using
ammonium nitrate are fundamentally safe, but now all Takata airbags using that propellant without a chemical drying agent must be recalled.
Hmm... sounds vaguely familiar to a scenario that has been playing out over the past three years, but FCA points out that none
of the affected vehicles use
ammonium -
nitrate inflators — the suspected prime culprit in the massive Takata airbag recall that has affected some 41 million vehicles worldwide.
Beginning with the familiar products,
ammonium sulfate, sodium
nitrate, and cyanamid, there have followed liquid ammonia, a highly concentrated plant food used for the neutralization
of acid phosphate and in turn, for the same purpose, that product carrying in solution urea or
ammonium nitrate.
Saline combinations
of two plant foods, such as potassium
nitrate and
ammonium phosphate are already familiar commodities, while within the laboratory there remain various others awaiting their commercial development.
The product was acid phosphate containing some 16 percent P 2 0 5, to which, in the earlier days were added small quantities
of nitrogen carriers, such as guano, slaughterhouse tankage, garbage tankage, fish scrap, and lowanalysis potash salts
of foreign origin, to be replaced gradually in subsequent years by the higher grades
of nitrogen carriers,
ammonium sulfate and sodium
nitrate, for years likewise largely
of foreign origin, and the more concentrated potash salts.
The Guardian reports that the Australian Senate is conducting an inquiry into the impact
of a nearby
ammonium nitrate plant, emissions from which may be threatening the ecological conditions
of the site.
Currently, fertilizer is made using natural gas (steam reforming
of methane to generate hydrogen to feed into the Haber process)-- but with the new advances (/ / www.greencarcongress.com/2008/07/researchers-at.html), it should be possible to generate that hydrogen directly from water using sunlight; feed the hydrogen into the Haber process (energy expensive, true, but doable), and then you have your ammonia, convert half
of that to
nitrate, and there you have your
ammonium nitrate fertilizer, which currently accounts for about 1/2
of all agricultral fossil fuel use.
Nitrate (NO3 --RRB- and
ammonium (NH4 +) are both sources
of nitrogen.
A majority
of sub-micrometer particles (< 1 µm in diameter, PM1) originated from diesel engine emissions whereas another sub-micrometer particle type originated from the combustion products
of explosives (e.g.
nitrate and
ammonium).
For deep placement, nitrogen (as a 28 «N solution
of urea -
ammonium nitrate) was banded 10 to 15 cm below the soil surface using modified anhydrous ammonia applicator knives spaced 45 cm apart.
A recent Canadian study
of the nation - wide emissions
of greenhouse gases from agricultural activities used nitrous oxide emissions factors which indicated that nitrous oxide emissions from anhydrous ammonia and
ammonium phosphate were from four to five times as high as those from urea or
ammonium nitrate.
The GISP2 ∼ 3.5 yr sample resolution could potentially under - sample a
nitrate or
ammonium increase (Mayewski et al., 1997) because both compounds have atmospheric residence times
of a few years.
Their estimates, however, for the increases in
nitrate and
ammonium associated with a Younger Dryas — size comet are orders
of magnitude larger than observed in the Summit Greenland ice core records; the Younger Dryas
nitrate and
ammonium increases are at most just half
of the Tunguska increase.
Every day, 5.5 million pounds
of explosives — a mix
of diesel fuel and
ammonium nitrate — are used to blow up the mountains
of southern West Virginia and eastern Kentucky.
One
of Dave's essays that caught my attention involved the very interesting idea
of using excess wind power to make methanol, ethanol, or even
ammonium nitrate fertilizer.
Typical materials which have a high solubility in water coupled with a large endothermic heat
of solution in water are potassium
nitrate, potassium nitrite,
ammonium nitrate, and urea.
Standard measurements include mass concentrations
of organics, sulfate,
nitrate,
ammonium, and chloride.
Typical examples
of materials suitable for use in practicing this invention are urea, potassium
nitrate, potassium nitrite, and
ammonium nitrate.
In particular, we evaluate non-sea-salt sulfate (nss - SO4 =),
ammonium (NH4 +),
nitrate (NO3 --RRB-, black carbon (BC), sea - salt, dust, primary and secondary organics (POA and SOA) with a focus on the importance
of secondary organic aerosols.
Microbial communities in wetlands play a dominant role in the removal
of inorganic nitrogen (
nitrate and
ammonium)(DeBusk 1999).