For example — at what height would 90 %
of the atmospheric molecules be below you?
As demonstrated by my modest experiment (1 & 2) the presence
of the atmospheric molecules participating in the conductive, convective and latent heat movement processes renders this ideal black body radiation impossible.
We are sitting at 385 ppm of CO2, or 0.038 %
of all atmospheric molecules, 4 % of which are to be contributed to human activity.
Near Titan's surface, about 5 percent
of the atmospheric molecules are methane, the fraction decreasing with altitude.
On a global scale, the heating
of atmospheric molecules causes the lower atmosphere, or troposphere, to expand and stretch higher during the day; it then settles back down as it cools at night.
At the present time, the concentration is about 390 ppm, 0.039 percent
of all atmospheric molecules and less than 1 percent of that in our breath.
Not exact matches
With this labeling method, the intrinsically labeled Golden Rice β - carotene showed a protonated
molecule of m / z
of Mβc + H + = 536 + 1 (representing unlabeled β - carotene) and a range
of isotopomers with the most abundant showing an enrichment
of 9 deuterium at Menrich - βc = Mβc + H + + 9 mass units (Figure 4) as analyzed by using the liquid chromatography / mass spectrometry with a positive
atmospheric pressure chemical ionization interface (the total m / z was Mβc + 9 + H + = 536 + 9 + 1 = m / z 546)(23).
But James Ferris, a prebiotic chemist at Rensselaer Polytechnic Institute in Troy, N.Y., doubts that
atmospheric electricity could have been the only source
of organic
molecules.
In the midst
of an extreme Antarctic freeze,
atmospheric molecules lose roughly 20 percent
of their room - temperature velocity.
Moreover, these measurements were made at concentrations
of sulfuric acid and dimethylamine corresponding to
atmospheric levels (less than 1
molecule of sulfuric acid per 1 x 1013
molecules of air).
Franck Montmessin
of the LATMOS
atmospheric research centre in France says ozone forms when sunlight breaks up carbon dioxide
molecules on the planet's daylight side.
Tinetti says the earlier studies could be a product
of the planets» bright sides cooking to the same temperature throughout, which makes
atmospheric molecules less likely to absorb radiation from below.
A few
molecules of H2O at normal
atmospheric pressure are solid when below 32 degrees Fahrenheit, liquid between 32 °F and 212 °F, and gas when above 212 °F.
Low energy electrons are ubiquitous and are known to play important role in variety
of phenomena relevant to astrochemistry (where they participate in synthesis
of new
molecules), in radiation biology (where they cause chemical changes in living cell, plasma chemistry),
atmospheric chemistry, radioactive waste management and nanolithography — to name but a few.
This
atmospheric layer includes
molecules that absorb ultraviolet and visible light, acting as a kind
of «sunscreen» for the planet it surrounds.
Determining the structure
of these
molecules, she said, «is paving the way for future spectroscopic detection and
atmospheric chemistry modeling.»
As this light passes through the exoplanet's atmosphere, some
of it is absorbed by
atmospheric molecules.
The region contains strong fundamental vibrational transitions
of most
molecules, as well as two
atmospheric transmission windows.
IUVS also created a map
of the
atmospheric ozone on Mars by detecting the absorption
of ultraviolet sunlight by the
molecule.
Some
of these recombine into nitric oxide, and this in turn reacts with other
atmospheric chemicals, occasionally producing a
molecule made up
of three oxygen atoms — ozone, or O3.
The low
atmospheric temperature also works to slow the reaction, giving additional time for the separation
of molecules.
«It is ironic that high concentrations
of molecules with high global warming potential (GWP), the worst - case scenario for Earth's climate, is the optimal scenario for detecting an alien civilization, as GWP increases with stronger infrared absorption and longer
atmospheric lifetime,» say the authors.
It's correct that an extra methane
molecule is something like 25 times more influential than an extra CO2
molecule, although that ratio is primarily determined by the background
atmospheric concentration
of either gas, and GWP typically assumes that forcing is linear in emission pulse, which is not valid for very large perturbations.
The seasonal cycle in
atmospheric CO2 shows that the lifetime
of a CO2
molecule in the air before it is exchanged with another in the land biosphere is about 12 years.
The global warming potential (GWP) depends on both the efficiency
of the
molecule as a greenhouse gas and its
atmospheric lifetime.
Methods: In this new approach, the team began with an
atmospheric aerosol sample that contains thousands
of molecules formed in the reactions
of ozone, a common
atmospheric oxidant, with limonene, a
molecule emitted by various types
of trees, which is responsible for the citrus scent found walking among the orange trees.
Analyzing such systems, whether they are on the surface
of a catalyst, a microbial community, or
atmospheric aerosols, and understanding their impact requires tools that can accurately identify and quantify hundreds
of molecules,» said Dr. Julia Laskin, a PNNL chemist, who has been advancing the frontiers
of the Nanospray Desorption Electrospray Ionization Mass Spectrometry, nicknamed nano - DESI, for the last 3 years.
Scientists are still investigating how this
atmospheric loss occurred, but suggest that the sun might have pushed light
molecules out
of Mars» upper atmosphere that could not be held in by the planet's gravity.
The team observed signatures
of glowing water
molecules, which indicated that WASP - 121b's
atmospheric temperatures increase with altitude, Evans said.
And energy out mostly by radiation, however, as much as 20 %
of escaping energy is simply highly energized
atmospheric molecules; which furthers vertical convection all the way out to the inside
of Earth's magnetic bottle, and the Van Allen radiation belt.
In one study, Mao and colleagues subjected a mixture
of hydrogen and water to a pressure
of about 220 megapascals (2,000 times
atmospheric pressure) at room temperature (300 K or 80 °F), which formed a clathrate hydrate — a cage - like framework
of water
molecules enclosing
molecules of gas.
In August 2005, the scientists reported that they created this compound by compressing buckyballs — soccer ball - shaped
molecules each made
of 60 carbon atoms — at 2,200 degrees C and 200 times normal
atmospheric pressure, a process that could lend itself to mass production.
Briefly put, the process can be defined as a CO2
molecule absorbing a ~ 650 cm - 1 photon (equivalent to a thermal energy
of about 900 K), and losing that energy to the surrounding bath
of atmospheric gases.
It also seems that even though the selective absorption
of specific energy bands by different
molecules IS the mechanism to add energy to the air, the energy absorbed by CO2 & especially Water Vapor is extremely rapidly dispersed by molecular collisions to ALL the components
of the atmosphere, so that the N2 and O2 also heatup, and all the
atmospheric components assume a uniform temperature (ie global warming).
An parcel means that the medium is small enough to be isothermal and in local thermodynamic equilibrium (which then ensures that the population
of thermodynamic molecular energy levels will be set by molecular collisions at the local
atmospheric temperature), but the parcel is also large enough to contain a large enough sample
of molecules to represent a statistically significant mass
of air for thermodynamics to apply.
A warm parcel
of air will radiate more than a colder parcel, even at the same 390 ppm
of CO2 in the air due to the population
of the different rotational and vibrational energy states
of the GHGs from collisions with other
atmospheric molecules in the LTE limit.
The processes (absorption
of light, collisional energy transfer and emission) can be separated because the average time that an isolated CO2
molecule takes before it emits a photon is much longer that the time for collisional de-excitation (~ tens
of microseconds at
atmospheric pressure, less, higher in the atmosphere).
The study notes that «It is not physically possible for large enough volumes
of air to interact with the surface under normal
atmospheric conditions and therefore this method will not remove sufficient
molecules of NO2 to have a significant impact on ambient concentrations.»
I think I know what you mean here but in the context
of the previous Much Ado about Methane article with discussion
of the difference between
atmospheric lifetime
of a CO2
molecule vs. lifetime
of an increase in concentration, this could also be put more clearly.
So, although each
molecule of CO2 that escapes from the oceans will, on average, be back in the ocean again in five years time, if the sea surface temperature rises the increase in the
atmospheric CO2 will remain.
The fundamental point is that the total
atmospheric warming arising as a result
of the density
of the atmosphere is a once and for all netting out
of all the truly astronomic number
of radiant energy /
molecule encounters throughout the atmosphere.
I stand corrected and you are right that it is a weight adjusted 10 %
of IR resonating
atmospheric molecules.
If you look at the total cross section
of all the air
molecules in a volume 1 Meters high by 1 M ^ 2 cross section, You get figure
of.0.25 * 10 ^ 26
molecules / M ^ 3 for the number
of molecules at
atmospheric pressure.
The speed
of release is again dictated by overall
atmospheric density because greater density renders it less likely that the neighbouring
molecules are cool enough for a release
of radiant energy to occur.
The radiative absorption capability
of CO2 allows
atmospheric molecules to reach a higher temperature than that imparted to them by energy at the surface so they rise to a higher location than would be predicted from their weight and their individual gas constants.
The fundamental point is that the total
atmospheric warming arising as a result
of the density
of the atmosphere is a once and for all netting out
of all the truly astronomic number
of energy /
molecule encounters throughout the atmosphere.
«The
atmospheric greenhouse effect is a flea on the back
of an oceanic elephant and the influence
of CO2 but a microbe on the back
of the flea and the influence
of anthropogenic CO2 but a
molecule on the back
of the microbe.»
John Carter August 8, 2014 at 12:58 am chooses to state his position on the greenhouse effect in the following 134 word sentence: «But given the [1] basics
of the greenhouse effect, the fact that with just a very small percentage
of greenhouse gas
molecules in the air this effect keeps the earth about 55 - 60 degrees warmer than it would otherwise be, and the fact that through easily recognizable if [2] inadvertent growing patterns we have at this point probably at least [3] doubled the total collective amount in heat absorption and re-radiation capacity
of long lived
atmospheric greenhouse gases (nearly doubling total that
of the [4] leading one, carbon dioxide, in the modern era), to [5] levels not collectively seen on earth in several million years — levels that well predated the present ice age and extensive earth surface ice conditions — it goes [6] against basic physics and basic geologic science to not be «predisposed» to the idea that this would ultimately impact climate.»
About half
of the albedo comes from clouds, with the surface and Rayleigh scattering by
atmospheric molecules contributing the rest.
Yet models
of atmospheric absorption that only take into account the water
molecule's well - known rotational and vibration - rotational transitions don't match up with measurements
of the atmosphere's absorption spectrum [1]....