The time it takes for half of any quantity
of hafnium - 182 to decay into tungsten - 182 is 9 million years.
The team of researchers from MIPT's Laboratory of Functional Materials and Devices for Nanoelectronics, with the participation of their colleagues from the University of Nebraska (USA) and the University of Lausanne (Switzerland), have for the first time experimentally demonstrated that polycrystalline alloyed films
of hafnium and zirconium oxides with a thickness of just 2.5 nm (see image below) retain their ferroelectric properties.
«Since the structures of this material are compatible with silicon technology, we can expect that new non-volatile memory devices with ferroelectric polycrystalline layers
of hafnium oxide will be able to be built directly onto silicon in the near future,» says the corresponding author of the study and head of the Laboratory of Functional Materials and Devices for Nanoelectronics, Andrei Zenkevich.
Intel's demonstration consisted
of a hafnium - based microprocessor capable of running three different computer operating systems.
The problem had been that the hafnium - tungsten dating technique depends not only on measuring the relevant isotopes in meteorites long ago blasted off Mars but also on knowing the relative proportion
of hafnium and tungsten in the deep martian mantle.
Not exact matches
To address the problem, Braun and his Illinois colleagues coated tungsten emitters in a nanolayer
of a ceramic material called
hafnium dioxide.
Hafnium bombs: In an episode reminiscent
of the Cold Fusion debacle, DARPA forked out $ 7 million in the 1990s for research into a bomb predicted to release huge gamma - ray bursts without creating any nuclear fallout.
For solid vessels, the highest melting point recorded is for tantalum
hafnium carbide, which has a potential melting point
of 4263 kelvin.
From indium touchscreens to
hafnium - equipped moonships, the nether regions
of the periodic table underpin modern technology — but supplies are getting scarce
Nuclear reactors utilize control rods made from elements such as cadmium, boron or
hafnium, all
of which are efficient neutron absorbers.
So Cola, NSF Graduate Research Fellow Erik Anderson and Research Engineer Thomas Bougher replaced the calcium with aluminum and tried a variety
of oxide materials on the carbon nanotubes before settling on a bilayer material composed
of alumina (Al2O3) and
hafnium dioxide (HfO2).
Many researchers had gauged how long Mars took to form using the steady decay
of radioactive
hafnium - 182 to tungsten - 182, but the answers were all over the place.
To shrink the uncertainty, Dauphas and Pourmand went looking in a variety
of non-martian meteorites for a stand - in for the
hafnium - tungsten ratio that would not be altered.
Their real breakthrough, however, is discovering the use
of an intermediate dielectric coating (
hafnium) to block the quenching
of the free electrons in the metal by the CNTs, allowing the nanotubes to function uninhibited.
The
hafnium coating enables the bunching
of gold nanotubes that creates a thick canopy full
of sensitive spots for detection.
During their investigations, the research team came to the surprising result that has been published in the journal Geology: 2.7 billion years ago, seawater contained an unusually high abundance
of the radioactive isotope
Hafnium 176 but a comparably low abundance
of the radioactive isotope Neodymium 143, similar to what can be observed in present day seawater.
Dr. Hoffmann: «The isotope
Hafnium 176 in contrast to its counterpart Neodymium 143 was transported by means
of weathering into the oceans and became part
of iron - rich sediments on the sea floor 2,700 million years ago.»
A Cologne working group involving Prof. Carsten Münker and Dr. Elis Hoffmann and their student Sebastian Viehmann (working with Prof. Michael Bau from the Jacobs University Bremen) have managed for the first time to determine the isotope composition
of the rare trace elements
Hafnium and Neodymium in 2.7 - billion - year - old seawater by using high purity chemical sediments from Temagami Banded Iron Formation (Canada) as an archive.
The Temagami Banded Iron Formation, which was formed 2.7 billion years ago during the Neoarchean period, can be used as an archive because the isotopic composition
of many chemical elements such as
Hafnium and Neodymium directly mirrors the composition
of Neoarchean seawater.
Hafnium - based insulators are now used in the 45 - nanometer generation
of chips made by Intel, shown here below a chip from 1993.
Producing
hafnium oxide transistors would require chipmakers to add multiple new steps to the manufacturing process — in part because the electrodes must be fashioned from metal, instead
of from a form
of silicon, to remain compatible with the
hafnium.
«It's a very, very significant event,» says electrical engineer Carlton Osburn
of North Carolina State University, member
of a research team that studied
hafnium and other advanced transistor materials.
A few years ago, DARPA, which prides itself on promoting far - out projects, proposed spending $ 30 million on a «
hafnium bomb,» a type
of nuclear weapon intended to release energy from atomic nuclei without either fission or fusion, using an approach similar to how energy is extracted from electrons in a laser.
Ma, who says he has worked with both the Intel and IBM research groups but is not privy to either's design, adds that the presence
of silicon dioxide would require chipmakers to add nitrogen to the
hafnium oxide as well.
«Scientists grow a material based on
hafnium oxide for a new type
of non-volatile memory.»
While
hafnium oxide is already used in the production
of modern silicon logic chips, a few years ago ferroelectric properties were discovered in one
of its modifications.
While the environmental implications
of the major industrial metals (e.g., iron and copper) have been extensively studied [3], the environmental burdens
of many
of the minor metals (e.g., niobium, rhenium,
hafnium) are essentially unknown, even though they are increasingly employed by industry.
Tungsten contains one isotope
of mass 182 that is created when an isotope
of the element
hafnium undergoes radioactive decay, meaning its elemental composition changes as it gives off radiation.
Because all the
hafnium - 182 decayed to tungsten - 182 during the first 50 million years
of Solar System history, these findings indicate that the mantle material that melted to form the flood basalt rocks that the team studied originally had more
hafnium than the rest
of the mantle.