Temperature is a measure
of the kinetic energy of the molecules.
I insisted several times now that the height * dependence *
of the kinetic energy of each molecule is a * premise * of our (Maxwell's, FOMD's) argument.
It means that energy transfer is dominated by collision and the distribution
of kinetic energy of the molecules follows the Maxwell - Boltzmann distribution.
Not exact matches
The remaining
molecules of lower
kinetic energy are counted.
In both cases
kinetic energy flows through matter without permanently displacing the
molecules in the matter itself — instead, it puts the matter through phases
of compression (where the
molecules get pushed together) and rarefaction (where the
molecules spread apart).
By using as sources supersonic jets
of hydrogen or helium containing small concentrations
of heavier
molecules we have been able to obtain molecular beams with
kinetic energies of the heavy
molecules well into the range above I electron volt.
Then they used the speed
of sound measurement to calculate the average speed
of the argon
molecules and hence the average amount
of kinetic energy that they had — from this they were able to calculate the Boltzmann constant with an extremely high accuracy.
The suggested method is to use the Boltzmann constant, which is a measure
of the relationship between the
kinetic energy of molecules and temperature.
Also, as the faster - moving
molecules escape, the remaining
molecules have lower average
kinetic energy, and the temperature
of the liquid thus decreases.
«With soft - landing techniques, chemists can control — very precisely — the location, the makeup, and the
kinetic energy of the
molecules that we deposit,» said Laskin, the PNNL physical chemist who led the writing
of the review article.
When neutron particles collide with hydrogen and oxygen particles, some
of the
kinetic energy from the neutron is transferred to the water
molecule, much like a cue ball hitting another billiard ball
of the same size.
When an icy impact occurred, the impactor's
kinetic energy became heat
energy, instantly melted some ice, gouged out a crater, and kicked up into Mars» thin atmosphere large amounts
of debris mixed with water (liquid, ice crystals, and vapor)-- and complex organic
molecules that obviously came recently from life.127 Then, the dirt and salt - water mixture settled back to the surface in vast layers
of thin sheets — strata — especially around the crater.
«Only large groups
of colliding
molecules have a temperature — which is proportional to their mean
kinetic energy.
Once this mixture
of fuel droplets, and air is inside the cylinder, and a spark occurs do the air
molecules gain
kinetic energy, then collide into the atomised fuel, and the individual fuel
molecules break apart thus turning fuel from a liquid to a gas (vaporisation), then those fuel
molecules combines with the air
molecule, then combustion occurs?
(The temperature
of air depends on the average
kinetic energy of its
molecules.)
This
kinetic energy is made up
of not only the vibrational
energy, but also the rotational
energy and the classical
kinetic energy of moving
molecules.
Collison
of an excited greenhouse gas
molecule will normally result in the deactivation
of the greenhouse gas
molecule and an increase in the
kinetic energy of the non-greenhouse gas
molecule.
Almost immediately (nanoseconds) they relax from their excited state by either 1) emitting that
energy as a new photon, some
of which will continue up towards space, some
of which will go back downward to be reabsorbed, thus keeping the
energy in the atmosphere longer, or 2) by colliding with another gas
molecule, most likely an O2 (oxygen) or N2 (nitrogen)
molecule since they make up over 98 %
of the atmosphere, thereby converting the extra vibrational
energy into
kinetic energy by transferring it to the other gas
molecule, which will then collide with other
molecules, and so on, making the air warmer.
i.e. every
molecule in a gas is capable
of radiating, if and only if, it has aquired sufficient
kinetic energy, (Maxwell - Boltzmann distribution), and those
molecules are evenly distributed through the volume
of the gas.
The
energy content
of such an atmosphere would be skewed towards the top with the
molecules at the boundary
of space containing both a full load
of kinetic energy AND a similar amount
of potential
energy whereas those at the bottom would have
kinetic energy only.
This is the direct and powerful thermal infrared, longwave infrared, actually capable
of doing the cooking,
of making the whole
molecules of matter vibrate which is also heat,
kinetic energy.
Since reducing pressure with height around a sphere allows more space between
molecules and between the
molecules and the ground the
molecules cool due to conversion
of kinetic energy to potential
energy.
The bulk
of collisions change the
kinetic energy of the
molecules.
As I understand the Ideal Gas Law, the temperature one measures depends on the density
of the gas as less density means less collisions
of individual
molecules with the measuring apparatus, or IOW, less
kinetic energy per volume unit
of gas.
It can transfer
kinetic energy to another
molecule though, and through random collisions a small number
of the
molecules will reach the necessary
energy to radiate.
The water vapor evaporated from the surface taking with it latent heat
of evaporation (the
molecules»
kinetic energy) when those water vapor
molecules reach the condensation level they change state — and release
energy — then again when they freeze they release
energy.
Unlike Miskolczi's misapplication
of the virial theorem to air
molecules, the Moon undergoes no significantly orbit - altering collisions, whence the Moon's
kinetic energy decreases by exactly half the potential
energy increase, easily confirmed by other ways
of computing the same thing.
I would equally interested fo people who believe «global warming» affirming clearly that they don't believe that an excited CO2
molecule increases the
kinetic energy of atmospheric gases in any significant degree.
@Web: The problem with your argument is that it presumes that there is not a statistical distribution
of kinetic energies among the top-most water
molecules, such that a certain percentage
of them are within a single photon's
energy of the heat
of vaporization.
(3) Isothermal conditions would require creation
of energy every time a
molecule moved upwards, supposedly retaining
kinetic energy whilst gaining potential
energy.
I think Geoff Wood's argument is that the
molecules have
energy which consists
of kinetic energy and potential
energy.
It takes the power
of real heat to heat matter, to move the
molecules of matter into vibration,
kinetic energy which is heat.
The net flow
of energy is from a region
of high mean
kinetic energy to a region
of low
kinetic energy, but a population or region
of molecules radiates in all directions.
In the real world it takes heat from the Sun to raise the temperature
of matter, to heat it, to move the
molecules of matter into vibration, which is heat,
kinetic energy.
And this
energy stored by the
kinetic energy of the gas
molecules of the atmosphere.
Within a volume
of the atmosphere, none
of the
molecules are exactly at the mean
kinetic energy, all are below or above average by at least a small amount, and some are above or below average by large amounts.
Then, the temperature is determined by the
kinetic energy of the
molecules.
It can be studied by semi-classical statistical mechanics and the result is that the velocities
of molecules (translational
kinetic energy) within a volume
of gas in equilibrium are distributed according to the Maxwell - Boltzmann distribution.
Perhaps such collisions can only cause
kinetic energy exchanges and perhaps trigger or assist in the release or absorption
of photons characteristic
of the
molecules involved in the collision.
The
kinetic energy of molecules — heat — is transferred to other
molecules in the atmosphere heating the atmosphere.
These Photons have a separate existence to the
molecules about them & don't present any indication
of the
Kinetic Energy (KE)
of those surrounding
molecules, whose KE is presented as the VELOCITY
of the molecular unit and is measured in style as «Temperature» (or as Pressure also).
A collision where the
kinetic energy is split between two (or more)
molecules, leading to a decay in number
of molecules at N2 (+) or near N2 (+)
kinetic energy levels.
The «temperature»
of a gas (if you must use a compound term) is a measure
of the total
kinetic energy of the
molecules in the volume
of gas being measured.
That case nonetheless remains relevant, because it illustrates by exaggeration something that remains true independently
of how large the number
of molecules gets: the mean molecular translational
kinetic energy decreases with height, and it does so at a rate that is finite and non-zero, albeit negligible for most purposes.
But a point you raised gnawed at me, and I tentatively reached a result that is an argument for your point
of view: if you start with our atmospheric pressure at ground level, the difference in
kinetic energy Velasco et al. specify for an altitude difference
of, say, 10 km would not be measurable with a time uncertainty less than a second even in principle unless the gas - column width is less than something on the order
of 100 nitrogen -
molecule diameters across.
The problem you are struggling to understand is that there is a Bolztman distribution
of kinetic energy such that you can not obtain a reliable temperature for an ensemble by measuring one individual
molecule's temperature.
The
kinetic energy of the in the the
molecules at the top
of the box and the
molecules at the bottom
of the box are different, in the additive fashion
of kinetic energy plus potential
energy equals a constant total
energy.
Over a sufficiently long period
of time, it follows from the equipartition theorem and other principles
of statistical mechanics that every
molecule in a gas will have the same average
kinetic energy, the same average potential
energy, and the same total
energy, as any other
molecule.
Visible light is not thermal
energy on the move, it can not heat water as thermal infrared can heat water, water is a transparent medium for it, it works on electronic transition level
of effect on meeting matter, AND not vibrational resonance, i.e. moving the whole
molecule,
kinetic energy, which is the process
of thermal infrared, etc. «Climate» science mangles all
of these by giving the properties
of one to another and then claiming visible light can do what it isn't physically possible for it to do.
As implausible as it might seem at first, the average
kinetic energy of the
molecules that make it 17 km will be the same as the average KE
of the
molecules at the bottom.