Materials Research Society 2000 Fall Meeting Symposium on Structure - Property Relationships
of Oxide Surfaces and Internal Interfaces
His current research programs address numerous aspects of the physical and chemical properties
of oxide surfaces.
These include fundamental experimental studies of the geometric and electronic structure
of oxide surfaces, as well as more applied studies that are developing oxides as catalytic materials.
The latter act as coordinatively unsaturated sites — a hypothesis introduced long ago to account for the catalytic activity
of oxide surfaces — onto which carbon monoxide can chemisorb and from where it can react with neighboring lattice - oxygen to carbon dioxide.
The other strategy is based on different elements, including niobium, that propel hydrogen out
of the oxide surface and protect the underlying zirconium alloy.
Not exact matches
KALONGWE ORE Kalongwe hosts a near -
surface resource
of 302 000 t copper and 42 000 t cobalt as predominantly
oxide ore
with the possibility
of oxide mineralization to be found closer to
surface than the original intercept.
By: Robyn Wilkinson 4th November 2016 There is an increasing investment trend involving near -
surface, easily mined base metal
oxide deposits in Africa that can generate early cash flow amid current commodity prices to fund further exploration
of the deposit at a later stage, advances specialist consultant to the mining industry The... →
SHORT - TERM FOCUS Oxidised near -
surface deposits, such as high - grade secondary copper mineralisation in the
oxide zone
of Zambian copper deposits, are drawing investor interest
«That's due to the amount
of oxide produced — a small amount lowers the
surface tension, but too much forms a crust over the metal and stops it spreading.
Since the reaction produces nitrous
oxide with a specific isotopic signature, Joye says: «This could be an easy way to «sniff» around the
surface of Mars looking for pockets
of subsurface brine that might be hotspots for extreme microbial life.»
The dissociation
of nitric
oxide on a ruthenium (0001)
surface was studied by scanning tunneling microscopy.
«This work suggests that not only does the formation
of the
oxide lower the
surface tension
of the liquid metal, but that it also creates compressive stresses — the opposite
of tension — that help the metal spread out and form fractals,» Dickey says.
«Applying voltage to EGaIn forms a thin layer
of oxide on the
surface of the metal, which effectively lowers the
surface tension,» Dickey says.
«Because neutron spectroscopy could «see» hydrogen due to its large neutron scattering cross-section, it succeeded where optical spectroscopy techniques failed and enabled the first direct observations
of cerium hydrides both on the
surface and in the bulk
of a cerium
oxide catalyst,» Wu said.
Shirley Meng, a professor at UC San Diego's Department
of NanoEngineering, added, «This beautiful study combines several complementary tools that probe both the bulk and
surface of the NMC layered
oxide — one
of the most promising cathode materials for high - voltage operation that enables higher energy density in lithium - ion batteries.
«Breaking down metal
oxide into tiny particles increases its
surface area and exposes lots
of ultra-small, interconnected grain boundaries that become active sites for the water - splitting catalytic reaction,» Cui said.
One
of the unexpected consequences
of the October 28 flare was a fivefold increase in ozone - destroying nitric
oxide at 70 miles above Earth's
surface.
We've always called Mars the Red Planet, but Curiosity showed us, for the first time, that it's not red — there's just a layer
of reddish iron
oxide on its
surface.
Using samples
of first zinc
oxide and later calcium carbonate, Fischer made maps that showed every dip and rise on the
surface of crystal to a resolution
of 1 nanometer or one - billionth
of a meter.
The scientists also found that the discontinuous nature
of the nano - islands along with the interfacial
oxide modified the electronic properties
of the silicon
surface and improved its solar performance.
The work also explains how the electric charges that accumulate on the
surface of liquid metal droplets, together with their
oxide skin, can be manipulated and used.
Their first trick is to roughen the
surface of the cartridge by dipping it in a solution
of aluminium
oxide and urea.
«One
of the developments that makes our fabrication process innovative is that we deposited yttrium
oxide (Y2O3) insulator directly onto the
surface of the diamond [to form the gate],» said Liu.
«We added the yttrium
oxide to the diamond with a technique known as electron beam evaporation, which involves using a beam
of electrons to transform molecules
of yttrium
oxide from the solid state to the gaseous state so that they can be made to cover a
surface and solidify on it.»
Monico also used high - powered X-rays to analyse microscopic samples from the painting and found that some
of the lead chromate at the painting's
surface had turned into greenish chromium
oxide, which combined with the underlying yellow to produce a darker and browner hue than van Gogh may have intended.
Here we report an iridium
oxide / strontium iridium
oxide (IrOx / SrIrO3) catalyst formed during electrochemical testing by strontium leaching from
surface layers
of thin films
of SrIrO3.
This catalyst has demonstrated specific activity at 10 milliamps per square centimeter
of oxide catalyst (OER current normalized to catalyst
surface area), with only 270 to 290 millivolts
of overpotential for 30 hours
of continuous testing in acidic electrolyte.
Meanwhile, Aharon Kapitulnik and colleagues at Stanford University in Palo Alto, California, used a scanning tunneling microscope to study the crystal
surface of bismuth strontium calcium copper
oxide.
In their approach, they discovered that germanium nanowires are grown by the reduction
of germanium
oxide particles and subsequent self - catalytic growth during the thermal decomposition
of natural gas, and simultaneously, carbon sheath layers are uniformly coated on the nanowire
surface.
For years he has been studying the behaviour
of tiny particles on metal -
oxide surfaces together with Professor Ulrike Diebold (both TU Vienna).
In recent years, the have presented important new findings about the structure
of metal
oxides, about the mobility
of atoms on their
surface and their chemical properties.
Matula says this sudden illumination happens because during the first bout
of sonoluminescence, temperatures in the bubble, which can be as high as several hundred thousand degrees — hotter than the sun's
surface — do something to nitrogen and oxygen to make them form compounds such as nitrous
oxide that dissolve in the surrounding water.
At the Vienna University
of Technology, it has now been possible to selectively switch individual oxygen molecules sitting on a titanium
oxide surface between a non-reactive to a reactive state using a special force microscope.
In the experiments, oxygen molecules were studied on the
surface of a titanium
oxide crystal at extremely low temperatures.
In all
of these applications, particle size is critical to the utility and function
of oxide nanoparticles — decreased particles size results in increased
surface area, which can significantly improve the performance
of the
oxide nanoparticle.
The same process also happens when the
surface of the titanium
oxide is irradiated with light — electrons are liberated inside the material, and can come to the
surface to activate one
of the oxygen molecules.
The work builds on research, published in Science last year, in which the Wang and Datye groups found a novel way to trap and stabilize individual platinum atoms on the
surface of cerium
oxide, a commonly used component in emissions control catalysts.
Kepler - 13Ab's strong
surface gravity — six times greater than Jupiter's — then pulls the titanium
oxide snow out
of the upper atmosphere and traps it in the lower atmosphere on the nighttime side
of the planet.
Yamaguchi believes that deuterium ions migrate towards the palladium
oxide surface of the plate because
of differences in temperature and density.
First, the
surface charge on a particle
of magnetite (a form
of iron
oxide) depends on the pH
of the solution surrounding it: below pH 6 it is positive, and above it is negative.
Starting with a substrate
of indium tin
oxide, the researchers used light - activated chemistry to pinpoint specific locations on the
surface for polymer growth.
A microlayer
of oxides then formed on the two
surfaces, gluing them together.
Researchers at Umeå University, together with researchers at Uppsala University and Stockholm University, show in a new study how nitrogen doped graphene can be rolled into perfect Archimedean nano scrolls by adhering magnetic iron
oxide nanoparticles on the
surface of the graphene sheets.
For example, oxygen can react with iron on the
surface of a planet to make iron
oxides; this is what gives most red rocks their color.
The researchers opted for aluminum
oxide (Al2O3) since it can form immediately on any kind
of surface.
Natterer and colleagues created the minuscule magnetic bits using atoms
of holmium deposited on a
surface of magnesium
oxide.
The nano - catalyst filter uses a technology that decomposes elements
of cigarette smoke using oxygen radical, which is generated by decomposing ozone in the air on the
surface of the manganese -
oxide - based nano - catalyst filter.
«Scrutinizing the tip
of molecular probes: Nature
of interaction
of probe molecules on the
surface of oxide particles elucidated.»
The authors used data from infrared spectroscopy and thermogravimetry to identify the strength
of the interaction between the probe and the
oxide surface, which also helped them determine the type
of bonding to the
surface.