(It also considered ground - level ozone, but emphasized that most
of the ozone precursors originated in the United States).
Climate change affects the sources
of ozone precursors through physical response (lightning), biological response (soils, vegetation, biomass burning) and human response (energy generation, land use, agriculture).
«I expect it will be a large source
of ozone precursors, and this would be located in an area that's already failing to meet federal health - based standards for ozone,» he said.
In more complex models that calculate atmospheric chemistry or the carbon cycle, the boundary conditions would instead be the emissions
of ozone precursors or anthropogenic CO2.
«Our work confirms that reducing emissions
of ozone precursors would have an enormous effect on the air we all breathe,» Pfister said.
Chemistry - transport model studies of the impact of recent changes
of ozone precursor emissions, both regionally and globally as outlined above, consistently show that the local response of ozone levels has been a decrease in North America and Europe and an increase in East Asia (Verstraeten et al., 2015; Zhang et al., 2016; Lin et al., 2017).
The ozone season is selected because it is the part of the year with highest temperatures and strongest solar radiation and thus the time when photochemical reactions
of ozone precursor gases are most likely to produce high ozone levels (Rice, 2014).
Not exact matches
These hydrocarbons, together with olefinic minor LPG components, furnish substantial amounts
of hydroxyl radical reactivity, a major
precursor to formation
of the
ozone component
of urban smog.
Inside the body, squalene is the
precursor of cholesterol, but the sebaceous glands in the skin churn out the stuff as is and
ozone is drawn to it like a magnet, Weschler says.
The researchers [3] quantified China's current contribution to global «radiative forcing» (the imbalance,
of human origin,
of our planet's radiation budget), by differentiating between the contributions
of long - life greenhouse gases, the
ozone and its
precursors, as well as aerosols.
Air monitoring by researchers in 2000 found levels
of volatile organic compounds — highly reactive
ozone precursors such as benzene, known as VOCs — were 10 to 100 times higher than what had previously been estimated.
The study finds that titanium dioxide coatings, seen as promising for their role in breaking down airborne pollutants on contact, are likely in real - world conditions to convert abundant ammonia to nitrogen oxide, the key
precursor of harmful
ozone pollution.
Because
ozone in the troposphere is a
precursor to OH, they deployed weather balloons equipped with measuring devices known as sondes to measure the amount
of ozone in the air from the surface to the stratosphere.
Wang, T, Xue, L, Brimblecombe, P, Lam, YF, Li, L and Zhang, L 2017
Ozone pollution in China: A review
of concentrations, meteorological influences, chemical
precursors, and effects.
This development has raised concerns regarding emissions
of greenhouse gases, air toxics, and
precursors to
ozone and fine particle formation.
From the Physical Science Basis: «Shindell et al. (2009) estimated the impact
of reactive species emissions on both gaseous and aerosol forcing species and found that
ozone precursors, including methane, had an additional substantial climate effect because they increased or decreased the rate
of oxidation
of SO2 to sulphate aerosol.
In a model that calculates atmospheric chemistry, the
ozone distribution is a function
of the emissions
of chemical
precursors, the solar UV input and the climate itself.
«While it is well understood that increases in CH4, NOx, CO and NMVOCs have driven up tropospheric
ozone, only one model has previously explored the relative contributions
of these different
precursors (Shindell et al., 2005, 2009).
Biomass burning is a big source
of black carbon and organic aerosols (warming), CO and VOCs (
ozone precursors), also SO2 (leading to sulphate aerosols)(cooling).
According to the Chinese Centre for Disease Control and Prevention, the burning
of coal is responsible for 70 percent
of the emissions
of soot that clouds out the sun in so much
of China; 85 percent
of sulfur dioxide, which causes acid rain and smog; and 67 percent
of nitrogen oxide, a
precursor to harmful ground level
ozone.
This assessment report looks into all aspects
of anthropogenic emissions
of black carbon and tropospheric
ozone precursors, such as methane.
7: Forests).18, 31,32,33,34,35 Long periods
of record high temperatures are associated with droughts that contribute to dry conditions and drive wildfires in some areas.159 Wildfire smoke contains particulate matter, carbon monoxide, nitrogen oxides, and various volatile organic compounds (which are
ozone precursors) 37and can significantly reduce air quality, both locally and in areas downwind
of fires.38, 39,40,41,42
The transportation sector produces one - third
of U.S. greenhouse gas emissions, and automobile exhaust also contains
precursors to fine particulate matter (PM2.5) and ground - level
ozone (O3), which pose threats to public health.
Heue, K. - P., Coldewey - Egbers, M., Delcloo, A., Lerot, C., Loyola, D., Valks, P., and van Roozendael, M.: Trends
of tropical tropospheric
ozone from 20 years
of European satellite measurements and perspectives for the Sentinel - 5
Precursor, Atmos.
Lee, Y., D. Shindell, G. Faluvegi, M. Wenig, Y. Lam, Z. Ning, S. Hao, and C. Lai, 2015: Increase
of ozone concentrations, its temperature sensitivity and the
precursor factor in South China.
«We use 1280 years
of control simulation, with constant preindustrial forcings including constant specified CO2, and a five - member ensemble
of historical simulations from 1850 — 2005 including prescribed historical greenhouse gas concentrations, SO2 and other aerosol -
precursor emissions, land use changes, solar irradiance changes, tropospheric and stratospheric
ozone changes, and volcanic aerosol (ALL), following the recommended CMIP5 specifications.
Factors that affect
ozone formation include heat, concentrations
of precursor chemicals, and methane emissions.
Because methane and VOCs are both
ozone precursors, and are released by many
of the same sources in the oil and gas sector, reductions will help reduce tropospheric
ozone.
The Government
of Canada has already taken action on SLCPs through implementation
of air pollutant regulations targeting
ozone precursors, and particulate matter including black carbon.
In terms
of SLCPs, the Multi-Sector Air Pollutants Regulations establish requirements for nitrogen oxide emissions (an
ozone precursor) from boilers and heaters and stationary spark - ignition engines operated in various industrial sectors, and nitrogen oxides (an
ozone precursor) and sulphur dioxide from cement manufacturing facilities.
For the runs with different emission and «climate» years, e.g. Em2000Cl1850, emissions
of aerosol and
ozone precursors are set to 2000, methane amounts for chemistry are set to 2000, but
ozone and methane at 2000 do not affect the radiation (i.e. radiation sees 1850 «climate» conditions for everything but aerosols).
Of all the pollutants, reducing black carbon and methane, a key
precursor to
ozone, fit the criteria best.»
[Response: For any projection for the future
of climate, you obviously need a projection
of emissions (greenhouse gases,
ozone and aerosol
precursors, etc.), land use change and so on.
They produce aerosols yes, but a lot
of them are black carbon (a warming influence), and they also produce NOx, CO and CH4 (
ozone precursors) as well as CO2
of course.
Unger, N., D.T. Shindell, D.M. Koch, and D.G. Streets, 2006: Cross influences
of ozone and sulfate
precursor emissions changes on air quality and climate.
Thus, we have traditionally studied the impact
of carbon dioxide separately from the impact
of sulphate aerosols and separately from the impacts
of the emissions that cause
ozone (the «
precursors»).
These results suggest that efforts to mitigate atmosphere - related environmental damages should target a broad set
of emissions including CO2, methane and aerosol /
ozone precursors.
Topics that I work on or plan to work in the future include studies
of: + missing aerosol species and sources, such as the primary oceanic aerosols and their importance on the remote marine atmosphere, the in - cloud and aerosol water aqueous formation
of organic aerosols that can lead to brown carbon formation, the primary terrestrial biological particles, and the organic nitrogen + missing aerosol parameterizations, such as the effect
of aerosol mixing on cloud condensation nuclei and aerosol absorption, the semi-volatility
of primary organic aerosols, the importance
of in - canopy processes on natural terrestrial aerosol and aerosol
precursor sources, and the mineral dust iron solubility and bioavailability + the change
of aerosol burden and its spatiotemporal distribution, especially with regard to its role and importance on gas - phase chemistry via photolysis rates changes and heterogeneous reactions in the atmosphere, as well as their effect on key gas - phase species like
ozone + the physical and optical properties
of aerosols, which affect aerosol transport, lifetime, and light scattering and absorption, with the latter being very sensitive to the vertical distribution
of absorbing aerosols + aerosol - cloud interactions, which include cloud activation, the aerosol indirect effect and the impact
of clouds on aerosol removal + changes on climate and feedbacks related with all these topics In order to understand the climate system as a whole, improve the aerosol representation in the GISS ModelE2 and contribute to future IPCC climate change assessments and CMIP activities, I am also interested in understanding the importance
of natural and anthropogenic aerosol changes in the atmosphere on the terrestrial biosphere, the ocean and climate.