In collaboration with the Materials Project, JCAP's high - throughput experimentation team, led by John Gregoire (Caltech), and a theory team, led by Jeff Neaton and Kristin Persson (LBNL), now have a defined means for rapid identification of the most promising classes
of photoanodes.
«The job
of the photoanode is to absorb sunlight and then use that energy to oxidize water — essentially splitting apart the H2O molecule and rearranging the atoms to form a fuel.
Not exact matches
The combined material, called a
photoanode, showed excellent stability while reaching a current density
of 10 milliamps per square centimeter, the researchers reported.
«Without a membrane, the
photoanode and photocathode are close enough to each other to conduct electricity, and if you also have bubbles
of highly reactive hydrogen and oxygen gases being produced in the same place at the same time, that is a recipe for disaster,» Lewis says.
«After watching the
photoanodes run at record performance without any noticeable degradation for 24 hours, and then 100 hours, and then 500 hours, I knew we had done what scientists had failed to do before,» says Ke Sun, a postdoc in Lewis's lab and the first author
of the new study.
When applied to
photoanodes, the nickel oxide film far exceeded the performance
of other similar films — including one that Lewis's group created just last year.
The artificial leaf that Lewis» team is developing in part at Caltech's Joint Center for Artificial Photosynthesis (JCAP) consists
of three main components: two electrodes — a
photoanode and a photocathode — and a membrane.
The technique used to identify the
photoanodes uses a combination
of theory and practice — the scientists worked with a supercomputer and a database
of around 60,000 materials, and used quantum mechanics to predict the properties
of each material.
However, this requires a «
photoanode» — a sort
of catalyst that can set the ball rolling — and researchers have had a tough time identifying them in the past.
In fact,
photoanodes are so rare that in the last 40 years, scientists have only been able to find 16
of them.
Development
of Solar Fuels
Photoanodes through Combinatorial Integration
of Ni - La - Co-Ce and Ni - Fe - Co-Ce Oxide Catalysts on BiVO4.
Mechanistic Insights into Chemical and Photochemical Transformations
of Bismuth Vanadate
Photoanodes F. M. Toma, J. K. Cooper, V. Kunzelmann, M. T. McDowell, J. Yu, D. Larson, N. J. Borys, J. W. Beeman, F. A. Houle, K. A. Oersson, and I. D. Sharp
Joel A. Haber, «Development
of Solar Fuels
Photoanodes through Combinatorial Integration
of Ni - La - Co-Ce Oxide and Ni - Fe - Co-Ce Oxide Catalysts on BiVO4»
Development
of solar fuels
photoanodes through combinatorial integration
of Ni - La - Co-Ce oxide and Ni - Fe - Co-Ce oxide catalysts on BiVO4.
(Invited) Chemical and Photochemical Transformations
of Bismuth Vanadate and Catalyst Integration for Stable
Photoanodes.
Discovery
of Solar Fuels
Photoanode Materials by Integrating High - Throughput Theory and Experiment.
«Today, bismuth vanadate is one
of the best materials available for constructing
photoanodes,» said Sharp.
The team is also excited that the collective effort provides not only the discovery
of high - performance materials, but also the advancement in scientific understanding
of metal oxide
photoanodes.
Solar Fuels
Photoanodes Prepared by Inkjet Printing
of Copper Vanadates P. Newhouse, D. Boyd, A. Shinde, D. Guevarra, L. Zhou, E. Soedarmadji, G. Li, J. B. Neaton, and J. M. Gregoire
Our joint theory - experiment effort has successfully identified new earth - abundant copper and manganese vanadate complex oxides that meet highly demanding requirements for
photoanodes, substantially expanding the known space
of such materials.
The poor stability
of most semiconductors in the highly oxidizing environment
of a solar fuels
photoanode has been a key factor limiting the use
of many candidates light absorbers.
Employing a strategic combination
of detailed electronic structure calculations, combinatorial materials synthesis, and both traditional and high - throughout photoelectrochemistry measurements, the JCAP team identified earth - abundant copper and manganese vanadate complex oxides that meet highly demanding requirements for
photoanodes: low band gap energy, stability under highly oxidizing conditions, and valence band alignment with respect to OER.
The scientists focused on bismuth vanadate, a thin - film semiconductor that has emerged as a leading candidate for use as a
photoanode, the positively charged part
of a photoelectric cell that can absorb sunlight to split water.
«Without a membrane, the
photoanode and photocathode are close enough to each other to conduct electricity, and if you also have bubbles
of highly reactive hydrogen and oxygen gases being produced in the same place at the same time, that is a recipe for disaster,» Lewis says regarding his findings published in PNAS.
Dr. Ager's research interests include the fundamental electronic and transport characteristics
of photovoltaic materials, development
of new
photoanodes and photocathodes based on abundant elements for solar fuels production, and the development
of new oxide - and sulfide - based transparent conductors.
Bottom: Solar driven water oxidation performance
of 25 mA · cm − 2 at 1.23 V vs. RHE is among the highest reported for a Si - based
photoanode; inset shows stable operation for at least 100 hours.
At the
photoanode side, water molecules are split into oxygen gas (O2), electrons and hydrogen protons through oxidation in the presence
of sunlight and the thin film coating the team recently developed.
Development
of solar fuels
photoanodes through combinatorial integration
of Ni — La — Co — Ce oxide catalysts on BiVO4.
Stable solar - driven oxidation
of water by semiconducting
photoanodes protected by transparent catalytic nickel oxide films.
Within JCAP, Dr. Haber's research focus surrounds the application
of high - throughput methods to integrate promising lead materials into functional assemblies, such as integration
of electrocatalyst libraries with light absorbers to produce functional
photoanode and photocathode assemblies.
Effect
of Tin Doping on alpha - Fe2O3
Photoanodes for Water Splitting.
Combining high throughput experimentation with theory enabled discovery
of a unique solar fuels
photoanode with remarkable stability.