Several
of the absorption bands seem not to be saturated.
Reversion of the Q82E mutation (v0) revealed it has a role in brightness and expansion
of the absorption band in the eukaryotic model that would not have been revealed in the prokaryotic model (Figure 2b, 4a).
Atmospheric CO2 does not act like a selective capture machine, waiting for photons at the middle
of an absorption band and rejecting others.
Some of the absorption bands that can be safely ignored would start to play a significant role.
Another, in regards to modern calculations, is that atmospheric measurements are usually restricted to a small number
of absorption bands, owing to the limits of technology.
I guess that calculations of the total atmosphere relies on a great many individual studies of small groups
of absorption bands.
Also, I would very much like someone knowledgeable to tackle Norm Kalmanovitch's posts from around 2.30 pm — in particular his assertions regarding saturation
of the absorption band and measurements of OLR.
In addition,
some of the absorption bands overlap.
Going further with the point made in that section: What is happening is that the sides
of the absorption band (the «wings») are getting blocked, which were hardly affected before.
Second, robotic probes have measured Venus» atmosphere to be about 97 % CO2, and we can see from the image above (click for a larger version) that the absorption spectrum for CO2 (at Earth temperature and pressure — Venusian temperature and pressure increases the width
of the absorption bands, making CO2 a stronger absorber in Venus» atmosphere than in Earth's) strongly overlaps the peak emission spectrum of Venus» surface.
Note that this book was written before the 1950s, which is when the importance of the wings
of the absorption band and of where in the atmosphere the absorption is significant was first widely understood.
The basic points, in a nutshell, is that one has to go beyond the first absorption and subsequent emission to consider the full problem of multiple absorptions and emissions and one has to consider the «wings»
of the absorption band rather than it just being a binary problem of absorption or no absorption at a given wavelength.
That is, with more carbon dioxide there are additional frequencies along the skirts
of the absorption band for which the atmosphere becomes opaque.
1) The «edges»
of the absorption bands do not absorb so well (dropping to zero over some finite range of wavelengths.
Not exact matches
«Its
absorption range covers a broad
band from 0.7 to 1.9 gigahertz below -10 decibel, and the total thickness
of the absorber is only 7.8 millimeters, which is one
of the thinnest microwave absorbers reported.»
They found
absorption bands characteristic
of the iron in volcanic glass, a shiny substance similar to obsidian that forms when magma cools too fast for its minerals to crystallise (Geology, DOI: 10.1130 / G32755.1).
This conduction
band state is therefore sensitive to a modulation
of the distance Q between Lithium nucleus and Borohydride group and as a result the x-ray
absorption process is sensitive to such a modulation (cf. Figs. 2 (b) and 3 (d) in the main article).
But others, such as the
band gap and shape
of the optical
absorption changed dramatically, so the properties
of the material become qualitatively different.
The color coding shows the strength
of the organics
absorption band, with warmer colors indicating the highest concentrations.
At Princeton, he made balloon observations
of cool stars in the infrared, which showed their huge water
absorption bands.
Some important work can be done in the 1 - 2.5 µm region - mainly on
absorption spectra
of combination
bands, which are weaker than fundamental
bands by large factors (typically 100 or more).
Just to expand on that a little — the distribution
of population among the quantum states
of the greenhouse gas molecules is actually set in two ways; by collisons with air molecules (ie both greenhouse gas molecules and non-greenhouse gas molecules) and by excitation as a result
of absorption in that greenhouse gases»
bands.
This makes it crucial to constrain the environment
of H2O ice to enable correct assignments
of other species contributing to the interstellar 6 um
absorption band.
Doppler RV is measured through monitoring interference fringe shifts
of stellar
absorption lines over a broad
band.
She seems to have beaten John Tyndall to the discovery
of the infrared
absorption bands of greenhouse gasses by a few years:
Those most similar to class M stars have strong ZrO
absorption bands analogous to the TiO
bands of class M stars, whereas those most similar to carbon stars have strong sodium D lines and weak C2
bands.
The CO2 climate forcing does not increase as rapidly as the CO2 amount because
of partial saturation
of CO2
absorption bands [75].
We tentatively detected radius variations with wavelength for both planets, in particular in the case
of WASP - 45 b we found a slightly larger
absorption in the redder
bands than in the bluer ones.
(Pressure does broaden the
absorption bands of GHGs.)
In escaping Fate, Justin attaches himself to a
band of quirky characters who will help him move beyond his self -
absorption into the fold
of family and friends.
Just to expand on that a little — the distribution
of population among the quantum states
of the greenhouse gas molecules is actually set in two ways; by collisons with air molecules (ie both greenhouse gas molecules and non-greenhouse gas molecules) and by excitation as a result
of absorption in that greenhouse gases»
bands.
It's more useful to think
of the stratosphere and above as being radiatively heated / cooled in specific
bands (as opposed to a more general
absorption / emission in the troposphere — mainly due to water vapour).
A simple example is the radiation code — instead
of using a line - by - line code which would resolve the
absorption at over 10,000 individual wavelengths, a GCM generally uses a broad -
band approximation (with 30 to 50
bands) which gives very close to the same results as a full calculation.
As the radiation in that particular wavelength
band is used up, the amount left for
absorption by more
of the gas is reduced.
The reason for this is as follows: Carbon dioxide has three
absorption bands at wavelengths
of 4.26, 7.52, and 14.99 micrometers (microns).13 The Earth's emission spectrum, treated as a black body (no atmospheric
absorption), peaks at between 15 and 20 microns, and falls off rapidly with decreasing wavelength.
The CO2 doesn't alter climate by affecting thermal mass; it affects climate by retarding the efficiency
of infrared radiation, and it has important IR
absorption bands in places where water is ineffective.
As a result, the carbon dioxide
absorption bands at 4.26 and 7.52 microns contribute little to the
absorption of thermal radiation compared to the
band at 14.99 microns.
``... The MSUs are cross-track scanners with measurements
of microwave radiance in four channels ranging from 50.3 to 57.95 GHz on the lower shoulder
of the Oxygen
absorption band.
It is really hard to understand how anybody could avoid the idea that the
absorption bands of every gas have been cataloged and re-measured about a jillion times.
CO2 absorbs most all
of the surface radiation in its
absorption bands within tens
of meters from the surface.
I don't know how
absorption probabilities go with pressure off the top
of my head, but for sure they decrease with decreasing pressure; focusing on
band structure while excluding the huge drop in number density with altitude is obfuscatory.
It also seems that even though the selective
absorption of specific energy
bands by different molecules IS the mechanism to add energy to the air, the energy absorbed by CO2 & especially Water Vapor is extremely rapidly dispersed by molecular collisions to ALL the components
of the atmosphere, so that the N2 and O2 also heatup, and all the atmospheric components assume a uniform temperature (ie global warming).
Examples
of magnetic dipole radiation are the well - known atmospheric
absorption bands of oxygen in the red... and the new infrared atmospheric
absorption band of O2, at 1.27 microns.»
Which references... «Absolute Intensities
of the Discrete and Continuous
Absorption Bands of Oxygen Gas at 1.26 and 1.065 Micron» (1965, Badger et al.) https://authors.library.caltech.edu/10448/1/BADjcp65.pdf «Molecular oxygen (O2) has absorption bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N
Absorption Bands of Oxygen Gas at 1.26 and 1.065 Micron» (1965, Badger et al.) https://authors.library.caltech.edu/10448/1/BADjcp65.pdf «Molecular oxygen (O2) has absorption bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).&r
Bands of Oxygen Gas at 1.26 and 1.065 Micron» (1965, Badger et al.) https://authors.library.caltech.edu/10448/1/BADjcp65.pdf «Molecular oxygen (O2) has
absorption bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N
absorption bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen absorptions at 1.06 and 1.27 um may be attributed to two types of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).&r
bands throughout the spectrum from the infrared (IR) to the ultraviolet... The oxygen
absorptions at 1.06 and 1.27 um may be attributed to two types
of absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N
absorption (1) from individual O2 molecules and (2) from O2 molecules that are involved in some interaction through collisions or transient pairings with other molecules (in this case either O2 or N2).»
Thus, there are no strong infrared
absorption bands due to dipole transitions as in the case
of the major greenhouse gases.
Well, if we add atmospheric
absorption to wavelengths just outside the first
band, there could be initial cooling
of lower levels and warming
of upper levels as explained in 1b, which will be enhanced if this is added at shorter wavelengths (reduced if addeed at longer wavelengths) relative to where the initial atmopsheric
absorption was (see 438).
Thus, adding
absorption to some new
band will initially tend to warm the colder upper atmosphere and radiatively cool the lower atmosphere and warm the surface (The forcing at any level will be positive, so the surface + troposphere will warm; if some
of the increased flux escaping in parts
of the spectrum where the abover layers have sufficiently small optical thickness, some
of the upper - level cooling will persist.
The line broadenning takes some optical thickness from the line centers and puts it into gaps between closely - spaced lines, so that there can be significant
absorption over a contiuous
band of wavelengths.
The magnitude
of the radiative forcing per doubling is equal to the effect
of band widenning, which is (BW1 + BW2) * depth
of valley or height
of hill, plus some additional effect in the center
of the
band, which is on the order
of 1/2 * (BW1 + BW2) * increase in height or depth
of hill or valley; the central contribution could be more or less than that, but it will be less than double (because the shape
of the
absorption spectrum won't allow a square shape in the graph
of the spectral flux).
The shape
of the CO2
absorption band, in terms
of CSD per unit CO2 concentration, can be approximated as having a peak at some frequency (designated ν0) or wavelength (about 15 microns for CO2) with, on each side
of that peak, a halving
of that optical thickness for each amount BW1 or BW2 that one moves away from the center (toward lower or higher frequency, respectively)