Nitrification,
the oxidation of ammonia via nitrite to nitrate, has always been considered to be a two - step process catalysed by chemolithoautotrophic microorganisms oxidising either ammonia or nitrite.
Microbiologists used to think that two distinct groups of bacteria were responsible for the stepwise
oxidation of ammonia to nitrate via nitrite.
Wang's research group designed a five - metal catalyst based on these high - entropy - alloy nanoparticles and demonstrated superior catalytic performance for selective
oxidation of ammonia to nitrogen oxide, a reaction used by the chemical industry to produce nitric acid, an important chemical in the large - scale production of fertilizers and other products.
They were able to achieve 100 percent
oxidation of ammonia and 99 percent selectivity toward desired products with the high entropy alloy nanoparticles, proving their ability as highly efficient catalysts.
Not exact matches
To demonstrate one potential use
of the nanoparticles, the research team used them as advanced catalysts for
ammonia oxidation, which is a key step in the production
of nitric acid (a liquid acid that is used in the production
of ammonium nitrate for fertilizers, making plastics, and in the manufacturing
of dyes).
They cranked them up even more — to 200 microns per second (equivalent to 100
of the nanomachine's body lengths)-- by also adding hydrazine, an
ammonia - derived chemical compound that accelerates hydrogen peroxide
oxidation.
«This study shows for the first time that the
oxidation of hydrogen sulfide and
ammonia from the bottom waters could be a major contributor to lower pH in coastal oceans and may lead to more rapid acidification in coastal waters compared to the open ocean,» said Cai, the paper's lead author and an expert in marine chemistry and carbon's movement through coastal waters.
The seasonal distribution
of marine Crenarchaeota in the oxic and
ammonia - rich surface waters off Palmer Station, Antarctica [4], as well as a correlation
of increasing crenarchaeal abundance with a nitrite (NO2 −) maximum are both consistent with the hypothesis that marine Crenarchaeota are capable
of ammonia oxidation [25].
Citation: Hallam SJ, Mincer TJ, Schleper C, Preston CM, Roberts K, Richardson PM, et al. (2006) Pathways
of Carbon Assimilation and
Ammonia Oxidation Suggested by Environmental Genomic Analyses
of Marine Crenarchaeota.
In particular,
ammonia oxidation rates in seawater have been shown to decline by 3 — 44 % as a linear function
of decreasing pH, in both in situ and experimental studies covering a range
of pH values (from 6.0 to approx. 8.10)[6 — 9].