The growth of graphene on metal surfaces can be catalyzed by mobile
surface metal atoms.
Not exact matches
It consists of a tiny
metal finger with a tip only a few
atoms wide that moves back and forth just above the
surface of a sample.
Only with this experimental set - up is it possible to measure the tiny forces between microscope tip and noble gas
atom, as a pure
metal surface would allow the noble gas
atoms to slide around.
«Working catalysts are not simple
surfaces, but it's now possible to use molecular beam technology to place well - characterised clusters of
metal atoms onto a
surface», says Prest.
But on an atomic scale, it has remarkable properties: on magnetite, single
metal atoms are held in place, or they can be made to move across the
surface.
In recent years, the have presented important new findings about the structure of
metal oxides, about the mobility of
atoms on their
surface and their chemical properties.
The formation of 2D atomically thin metallic layers over other
surfaces has previously been demonstrated, however in this case the
metal atoms interact with the underlying substrate.
That rope, it turns out, is not unlike an indirect interaction that takes place between distant
atoms dropped onto a
metal surface.
Shortly after, using a low - temperature scanning tunneling microscope, Eigler began to investigate the properties of individual
atoms deposited on a
metal surface.
«Our approach provides
atom - by -
atom control of the size and electron - by - electron control of the charge state of
metal clusters on
surfaces,» said Dr. Grant Johnson, a physical chemist involved in the study and former Linus Pauling Fellow who recently joined the Laboratory as a full - time scientist.
«The
surface of a
metal has one energy potential — it is uniform,» explains co-author Klaus Attenkofer, «whereas on a single
atom, every place on the
surface has a different kind of energy.»
«Nature of the chemical bond between
metal atoms and oxide
surfaces: new evidence from spin density studies of K
atoms on alkaline earth oxides» Journal of the American Chemical Society 2005, 127, 16935 - 16944.
«Single
atoms prefer to produce CO, rather than performing the competing HER, because the
surface of a bulk
metal is very different from individual
atoms,» says Stavitski.
Faults (contrary to very popular theory needs) are always lubricated to some degree by a combination of, pore space water under pressure, phyllosilicate clay slurry (lots of it), lubricant
metals like molybdenum (some - usually emplaced in hydrothermal processes of transport and
atom precipitation with changes in pressure) and especially by copious amounts of «massive» (i.e. solid) graphite, that's almost always is present in fault
surface,