By the end of this century, global ocean
surface pH could decrease by a further 0.3 — 0.5 units [1,2].
The increase in
surface pH before ca. 1985 is consistent with the trend in nitrogen inputs (Conley et al. 2009), whereas the subsequent decrease can be explained by enhanced ecosystem respiration.
Accordingly, upwelling of waters acidified by anthropogenic CO2 has led to a further decrease in
surface pH, as reported in the eastern Pacific Ocean along the west coast of North America, from central Canada to northern Mexico, where shoaling of the layer of seawater undersaturated with aragonite increased the frequency and magnitude of coastal acidification associated with upwelling events (Feely et al. 2008, 2010).
Changes in global average
surface pH and saturation state with respect to aragonite in the Southern Ocean under various SRES scenarios.
However as will be discussed, there are biological processes that do lower
surface pH to that extent, despite much lower atmospheric CO2 concentrations.
On the contrary as Gaia theory would suggest, coral reefs are actively regulating
surface pH.
Although this upwelling deceases
surface pH and provides more CO2, diatoms still rely on bicarbonate transporters and carbonic anhydrase to ensure an adequate supply of CO2 for photosynthesis.
The mechanisms that lowered
surface pH to 8.3 - 8.4 during the Last Ice Age is a matter of considerable debate, but clearly more carbon was being sequestered at depth and less carbon was being pumped to the surface.
As illustrated,
surface pH was more sensitive to the upwelling of subsurface DIC.
Then for our last 20 million years, ocean
surface pH has fluctuated within this new equilibrium between 8.4 and 8.1, as seen in Figure 1 below (Pearson and Palmer 2000).
Coastal and equatorial upwelling bring an enormous amount of DIC to the surface, with subsequent transport to the gyres of the open ocean, causing declines in open ocean
surface pH at rates that are much faster than possibly attributed to atmospheric diffusion.
Because oceans contain over 50 times as much CO2 as the atmosphere,
surface pH is more sensitive to changes in the rates of upwelling of low - pH, carbon - rich deep waters.
When photosynthesis and carbonate dissolution outweigh respiration and calcification,
surface pH can rise to 8.4 or higher as would be expected.
Although studies in the waters around Hawaii (Dore 2009) reported an increasing trend in DIC that was «indistinguishable» from what rising atmospheric CO2 predicts researchers observed, «Air - sea CO2 fluxes, while variable, did not appear to exert an influence on
surface pH variability.
For example across the tropical ocean, the ratio of net calcification to net photosynthesis for coccolithophores remained constant despite regions of widely varying
surface pH and calcite saturation levels (Maranon 2016).
Sixty million years ago proxy evidence indicates ocean
surface pH hovered around 7.4.
Furthermore when
surface pH is above 8.1, the concentration of surface CO2 is lower than atmospheric CO2, and this difference allows CO2 to diffuse into the ocean.
Furthermore if more organic molecules are formed and sequestered than subsequently respired, we would expect
surface pH to remain above 8.1.
As discussed in the article on natural cycles of ocean «acidification», and illustrated in the graph below by Martinez - Boti, over the past 15,000 years proxy data (thick lines) has determined
surface pH has rarely been in equilibrium with expectations (green line) based on models driven by atmospheric CO2.
This further complicates any attribution of trends in
surface pH. For example upwelling of stored CO2 is believed to have been the main driver of the rise in atmospheric CO2 and the fall in ocean
surface pH during the transition from the glacial maximum to our interglacial.
If
surface pH was in equilibrium with the atmosphere, then CO2 concentrations would have hovered around 2000 ppm, but there is no consensus that CO2 reached those levels.
Although it is commonly assumed atmospheric CO2 and ocean
surface pH are in equilibrium, studies examining various time frames from daily and seasonal pH fluctuations (Kline 2015) to the millennial scale transitions from the last ice age to our warm interglacial (Martinez - Boti 2015), demonstrate surface ocean pH has rarely been in chemical equilibrium with atmospheric CO2.
Although some researchers have raised concerns about possible negative effects of rising CO2 on ocean
surface pH, there are several lines of evidence demonstrating marine ecosystems are far more sensitive to fluxes of carbon dioxide from ocean depths and the biosphere's response than from invasions of atmospheric CO2.
In contrast to Bednarsek's anthropogenic hypothesis, an increase in the assimilation of CO2 and an efficient biological pump can prevent a decrease in
surface pH and calcium carbonate saturation.
To attribute her observed dissolution to anthropogenic CO2, Bednarsek argued recent invasions of anthropogenic CO2 into the surface water had lowered
its surface pH to such an extent, mixing no longer counteracted the low pH of upwelled water.
In 2095, the projected average ocean
surface pH is 7.8, and lower still in the Arctic Ocean.
Fig 2: Annual variations in atmospheric CO2, oceanic CO2, and ocean
surface pH. Strong trend lines for rising CO2 and falling pH.
As acids go, H2CO3 is relatively innocuous — we drink it all the time in Coke and other carbonated beverages — but in sufficient quantities it can change the water's pH. Already, humans have pumped enough carbon into the oceans — some hundred and twenty billion tons — to produce a.1 decline in
surface pH. Since pH, like the Richter scale, is a logarithmic measure, a.1 drop represents a rise in acidity of about thirty per cent.
For the «business - as - usual» scenario RCP8.5, the model - mean changes in 2090s (compared to 1990s) for sea surface temperature, sea
surface pH, global O2 content and integrated primary productivity amount to +2.73 °C, − 0.33 pH unit, − 3.45 % and − 8.6 %, respectively.
Average ocean
surface pH is expected to drop to about 7.8 off the West Coast by 2050, and could drop further during coastal upwelling periods.
The effect of the treatments was evaluated by determining stratum corneum integrity and cohesion, intercorneocyte cohesion, moisturization, skin -
surface pH, and erythema.
Not exact matches
In this recipe, the meat is simply coated with baking soda, which increases the
pH (or in other words, reduces acidity) and affects the way the molecules of protein at the
surface of the meat interact with each other.
According to their site, briefly soaking meat in a solution of baking soda and water raises the
pH on the meat's
surface, making it more difficult for the proteins to bond excessively, which keeps the meat tender and moist when it's cooked.
This is due to the ocean
pH decreases in depth (with a minimum value of < 7,7), which is related to the expected
pH in
surface ocean over the next 85 years).
«After years of work, we can now control not just the size of the pores, but the
pH of the
surface — how acidic or basic it is.»
Indeed, a study in 2006 suggested that Mars may have gone through an acidic phase, triggered by active volcanism, after an early period in which it had a denser atmosphere and large bodies of neutral -
pH water on its
surface.
Piercing through water solution and reflecting off the calcite's
surface like a mirror, focused X-rays changed the water's acidity level, starting a chain of reactions that lowered the
pH and caused the calcite to dissolve.
As its concentration rises in the atmosphere, carbon enters the ocean through chemical reactions, causing its
pH at the
surface to drop by 0.1 units since the preindustrial era.
On average, researchers estimate that
surface waters, where key players in the ocean food chain live, have seen a 0.1 decrease in
pH since the beginning of the Industrial Revolution; that's an extraordinarily rapid 30 % increase in acidity.
First, the
surface charge on a particle of magnetite (a form of iron oxide) depends on the
pH of the solution surrounding it: below
pH 6 it is positive, and above it is negative.
Prof Angus Gray - Weale from the Chemistry, Department of Chemistry University of Melbourne said, «The
surface tension of water affects its behavior and changes with
pH but previous research about the adsorption of various ions at the interface all ignored the presence of the hydroxide ion and its charge.»
«Areas of greatest vulnerability will likely be where deep waters, naturally low in
pH, meet acidified
surface waters,» such as areas of coastal upwelling along the West Coast and in estuary environments such Hood Canal, the new study predicts.
The tanks held seawater with a range of
pH levels reflecting current conditions as well as the lower
pH occasionally encountered in Puget Sound when deep water wells up near the
surface.
If you imagine the female egg cell (and later, the fertilized egg) as a spherical planet with its own intrinsic biological geography, then certain characteristics of that cell — the location of protein molecules or RNA messages or biochemical traits like
pH or even the internal connective structures called microtubules — will be more prominent in certain regions, like one hemisphere as opposed to the other, or near the
surface rather than near the core.
Inspired by dynamic shifts in
pH due to upwelling — the movement of nutrient - rich water toward the ocean
surface — the researchers took urchins from the Santa Barbara Channel and brought them into the lab.
The
pH in this zone is roughly 7.4, nearly 10 times higher in acidity (or a unit lower in
pH) than what is found in
surface waters, which have an average
pH of 8.2.
And at least one group of Chinese soils is approaching the
pH values at which aluminum and manganese start leaching into
surface water, with potentially toxic results.
In this study, an OSU team that included graduate students Lauren Fullmer, Sara Goberna - Ferron and Lev Zakharov overcame the need for ligands with a three - pronged strategy:
pH - driven hydrolysis by oxidative dissolution of zinc; metal nitrate concentrations 10 times higher than conventional syntheses; and azeotropic evaporation for driving simultaneous cluster assembly and crystallization at the
surface of the solution.
Because endosomes are the vehicles that deliver cargo essential for communication between brain cells, changing their
pH alters traffic to and from the cell
surface, which could affect learning and memory, Rao says.
Finally, none of the teams experienced a shift in Shannon - Wiener diversity or evenness, which would be expected in an exercise - driven community shift, since metabolically active bacteria might come to dominate the community with a change in
pH, temperature and moisture at the skin
surface.