Sentences with phrase «with phenyl»
In addition, gold clusters with the phenyl - containing ligand fragmented through a wide range of dissociation channels involving the loss of gold atoms as well as activation of the phosphorus - carbon bonds of the ligands.
https://www.pnnl.gov/ Not exact matches
They are loaded with powerful anti-cancer nutrients such as phenyl isothiocyanates, sulfuraphane and indole -3-carbonyl.
Frontier electron density at the ether oxygen position and superdelocalizability at the ortho position show good parallelism with biological activity — that is, the stimulant activity of phenyl ether choline molecules.
They then monitored how these potatoes fared compared with those treated with a commercial sprout inhibitor based on chloroisopropyl phenyl carbamate.
Using reference samples of TPCO 5,5» - bis (4 -(trimethylsilyl) phenyl)-2,2» - bithiophene (TMS - PTTP - TMS) crystals doped with a longer TPCO 5,5»» - bis (4 -(trimethylsilyl) phenyl)-2,2»: 5», 2»: 5», 2»» - quaterthiophene (TMS - PTTTTP - TMS) and assuming, that the absorption is linearly dependent on the impurity concentration, we can estimate the impurity concentration in other similar samples.
On the other hand, in order to reduce the basicity of the amine, addition of electron withdrawing groups on the phenyl ring, such as F (e.g. 132) and CF3 (e.g. 133), led to compounds with high absorption potentials, but, with a concomitant loss of antiviral activity.
Furthermore, theoretical calculations on diphosphine capped gold clusters often involve the substitution of simpler hydrogen atoms in the place of computationally demanding substituents such as phenyl groups with the assumption that the substitution does not alter the stability of the cluster.
Methods: Diphenylphosphine ligands, which consist of two phenyl (C6H5) substituted phosphorus centers separated by a carbon chain of variable length, produce gold clusters with extremely narrow distributions in size; that is, the synthesis route produces a large quantity of clusters with the same number of gold atoms as well as a small number of clusters with similar numbers of atoms.
It is noteworthy that the compounds with the lowest calculated binding free energies exhibit a high structural similarity between them [MolPort -016-359-762 (labeled as RIPK2 inhibitor 1 in subsequent figures, 3 - benzamido -4-methyl-N -[3 -(1 - methyl - 1H - imidazol - 2yl) phenyl] benzamide), MolPort -015-752-252, MolPort -015-604-588, and MolPort -016-412-727) and a high correlation with pharmacophoric points of ponatinib.
They are loaded with powerful anti-cancer nutrients such as phenyl isothiocyanates, sulfuraphane and indole -3-carbonyl.
The natural products studied, along with vitamin C, were silibinin — derived from milk thistle seeds — and caffeic acid phenyl ester — or CAPE — derived from honeybee propolis.